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公开(公告)号：US20180051121A1
公开(公告)日：2018-02-22
申请号：US15557518
申请日：2016-03-02
Applicant: Dow Global Technologies LLC
Inventor： Davide Micheletti , Rossella Riccio , Jean-Paul Masy , Vanni Parenti
CPC classification number: C08G18/482 , C08G18/163 , C08G18/4825 , C08G18/4829 , C08G18/4879 , C08G18/5033 , C08G18/7664 , C08G2101/0025
Abstract: A storage stable isocyanate-reactive composition includes a reactive component including (a) 5 wt % to 30 wt % of at least one Novolac-type polyoxypropylene polyether polyol having a hydroxyl functionality from 2 to 5 and a hydroxyl number from 130 to 450 mg KOH/g, (b) 20 wt % to 60 wt % of at least one high functional polyether polyol having a hydroxyl functionality from 6 to 8 and a hydroxyl number from 300 to 700 mg KOH/g, (c) 2 wt % to 30 wt % of at least one low functional polyether polyol having a hydroxyl functionality from 2 to 5 and a hydroxyl number from 50 to 400 mg KOH/g, (d) 2 wt % to 30 wt % of at least one amine initiated polyol having a hydroxyl number from 250 to 600 mg KOH/g, and (e) 1 wt % to 25 wt % of one or more additives; and a hydrocarbon physical blowing agent component in an amount of at least 10 parts by weight for each 100 parts by weight of the reactive component.
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公开(公告)号：US09896542B2
公开(公告)日：2018-02-20
申请号：US15504368
申请日：2015-10-19
Applicant: Dow Global Technologies LLC
Inventor： Arjun Raghuraman , Matthias Schaefer , Jean-Paul Masy , David S. Laitar
IPC: C08G65/26
CPC classification number: C08G65/269 , B01J23/75 , B01J27/26 , C08G65/2654 , C08G65/266 , C08G65/2663 , C08G65/2696
Abstract: A method of producing a high primary hydroxyl group content and a high number average molecular weight polyol includes preparing a mixture that includes a double metal cyanide catalyst and a low molecular weight polyether polyol having a number average molecular weight of less than 1,000 g/mol, the polyether polyol is derived from propylene oxide, ethylene oxide, or butylene oxide, setting the mixture to having a first temperature, adding at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the mixture at the first temperature, allowing the mixture to react to form a reacted mixture, adding a Lewis acid catalyst to the reacted mixture, setting the reaction mixture including the second catalyst to have a second temperature that is less than the first temperature, and adding additional at least one selected from propylene oxide, ethylene oxide, and butylene oxide to the reacted mixture at the second temperature such that a resultant polyol having a primary hydroxyl group content of at least 60% and a number average molecular weight greater than 2,500 g/mol is formed.
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公开(公告)号：US09708448B2
公开(公告)日：2017-07-18
申请号：US15024096
申请日：2014-08-16
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Jean-Paul Masy , Myriam Linke , David A. Babb , John W. Weston
CPC classification number: C08G65/12 , C08G65/2606 , C08G65/2609 , C08G65/2663 , C08G65/2696
Abstract: 1,2-butylene oxide is homopolymerized or randomly copolymerized in the presence of a double metal cyanide catalyst such as a zinc hexacyanocobaltate catalyst complex. The polymers unexpectedly contain significant amounts of monofunctional impurities, which can be partially controlled through selection of polymerization conditions.
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公开(公告)号：US20150004389A1
公开(公告)日：2015-01-01
申请号：US14344343
申请日：2012-09-20
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Elisa Corinti , Andrea Benvenuti , Alessio Sabadini , Jean-Paul Masy , Francois M. Casati , Brian Dickie
CPC classification number: C08G18/7657 , C08G18/14 , C08G18/1833 , C08G18/3206 , C08G18/4072 , C08G18/4812 , C08G18/4825 , C08G18/4829 , C08G18/4833 , C08G18/4841 , C08G18/4845 , C08G18/632 , C08G18/7671 , C08G2101/0008 , C08G2101/0033 , C08G2101/0083 , C08J9/0042 , C08J2375/08
Abstract: Embodiments of the invention provide for viscoelastic polyurethane foams. The foams are made from reaction system which includes (a) an isocyanate reactive component, (b) a isocyanate component, (c) one or more blowing agents, (d) a catalyst component, and (e) a silicone based surfactant. The isocyanate reactive component includes at least (i) from 25 to 80% by weight of at least one polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol having a combined number average equivalent weight from 1300 to 1700, a polyoxyethylene percentage of between 75% and 95% by weight of the combined amounts of polyoxypropylene and polyoxyethylene, and a primary OH percentage of between 80 and 95% of the total number of OH groups of the polyoxyethylene capped polyoxypropylene/polyoxyethylene polyol, and (ii) from 5 to 30% by weight of the isocyanate reactive component of at least one low functionality polyol having a functionality of between 1.5 and 2.5, a combined number average equivalent weight from 500 to 1500 and an OH number of 40 to 70.
Abstract translation: 本发明的实施方案提供了粘弹性聚氨酯泡沫。 泡沫由反应体系制成，其包括（a）异氰酸酯反应性组分，（b）异氰酸酯组分，（c）一种或多种发泡剂，（d）催化剂组分和（e）硅氧烷基表面活性剂。 异氰酸酯反应性组分包括至少（i）25至80重量％的至少一种聚均数当量为1300至1700的聚氧乙烯封端的聚氧丙烯/聚氧乙烯多元醇，聚氧乙烯百分比为75-95％ 聚氧丙烯和聚氧乙烯的组合量的重量，聚氧乙烯封端的聚氧丙烯/聚氧乙烯多元醇的OH基总数的80-95％的主要OH百分比，和（ii）5-30重量％ 至少一种官能度为1.5至2.5的低官能度多元醇的异氰酸酯反应性组分，组合的数均当量为500至1500，OH数为40至70。
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公开(公告)号：US12024587B2
公开(公告)日：2024-07-02
申请号：US16642436
申请日：2018-08-21
Applicant: Dow Global Technologies LLC
Inventor： Jean-Paul Masy , David A. Babb
IPC: C08G65/12 , C08G18/16 , C08G18/18 , C08G18/20 , C08G18/24 , C08G18/48 , C08G18/76 , C08G65/02 , C08G65/26
CPC classification number: C08G65/12 , C08G18/165 , C08G18/1833 , C08G18/2063 , C08G18/244 , C08G18/4816 , C08G18/4829 , C08G18/4837 , C08G18/7664 , C08G65/02 , C08G65/26 , C08G65/2663 , C08G65/269 , C08G65/2696 , C08G2110/0016 , C08G2110/0058 , C08G2110/0083
Abstract: An alkylene oxide mixture containing greater than 50% by weight ethylene oxide is continuously polymerized in the presence of a double metal cyanide polymerization catalyst and an alkoxylated initiator having a hydroxyl equivalent weight of up to 200. The catalyst remains active, producing a polyol having an equivalent weight of up to 700 with a high oxyethylene content continuously at fast reaction rates.
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Patent Agency Ranking
公开(公告)号：US11149117B2
公开(公告)日：2021-10-19
申请号：US16354114
申请日：2019-03-14
Applicant: Dow Global Technologies LLC
Inventor： David S. Laitar , David A. Babb , Carlos M. Villa , Richard Keaton , Jean-Paul Masy
Abstract: Alkylene oxide polymerizations are performed in the presence of a double metal cyanide polymerization catalyst and certain magnesium, Group 3-Group 15 metal or lanthanide series metal compounds. The presence of the magnesium, Group 3-Group 15 metal or lanthanide series metal compound provides several benefits including more rapid catalyst activation, faster polymerization rates and the reduction in the amount of ultra high molecular weight polymers that are formed. The catalyst mixture is unexpectedly useful in making polyethers having low equivalent weights.
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公开(公告)号：US10815331B2
公开(公告)日：2020-10-27
申请号：US16309566
申请日：2017-06-07
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Michael T. Malanga , Sabrina Fregni , George J. Frycek , Stephen W. King , Jean-Paul Masy , Sadeka Onam
Abstract: The present invention discloses a polymeric polyol composition useful for making polyurethane polymers, especially polyurethane foams. Said polyurethane polymer foams demonstrate a good balance of mechanical properties, physical properties, and low emissions. The polymeric polyol composition is the reaction product(s) of (i) a polyamine initiator composition comprising the polymerization product(s) of aminoethylpiperazine with (ii) at least one epoxide compound, at least one glycidyl ether compound, or mixtures thereof.
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公开(公告)号：US20190330406A1
公开(公告)日：2019-10-31
申请号：US16475119
申请日：2017-12-19
Applicant: Dow Global Technologies LLC
Inventor： Hamideh Ahmadloo , Paul Cookson , Ricco B. Borella , Jean-Paul Masy , Lucie Porcelli , Francois Casati
Abstract: A polyol composition is made by polymerizing a mixture of ethylene oxide and propylene oxide onto a mixture of at least one diol initiator and at least one triol initiator, followed by polymerizing 100% propylene oxide or a mixture of at least 90 weight percent propylene oxide and at most 10 weight percent ethylene oxide. The resulting polyol composition has a hydroxyl equivalent weight of 200 to 400 and an average nominal functionality of 2.05 to 2.95 hydroxyl groups/molecule. 5 to 30 percent of the hydroxyl groups of the coinitiated polyether polyol are primary hydroxyl groups and polymerized ethylene oxide constitutes 40 to 63 percent of the total weight of the coinitiated polyether polyol.
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公开(公告)号：US10160830B2
公开(公告)日：2018-12-25
申请号：US15579595
申请日：2016-06-15
Applicant: Dow Global Technologies LLC
Inventor： David A. Babb , Jean-Paul Masy , Mattias Schaefer , William A. Koonce , Donald Cameron
IPC: C08G65/26
Abstract: An alkylene oxide mixture containing greater than 50% by weight ethylene oxide is continuously polymerized in the presence of a double metal cyanide polymerization catalyst and certain magnesium, Group 3-Group 15 metal or lanthanide series metal compounds. The presence of the magnesium, Group 3-Group 15 metal or lanthanide series metal compound permits the polymerization to be performed continuously without premature deactivation of the double metal cyanide catalyst.
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公开(公告)号：US09994701B2
公开(公告)日：2018-06-12
申请号：US14429154
申请日：2013-09-23
Applicant: DOW GLOBAL TECHNOLOGIES LLC
Inventor： Ricco B. Borella , Sven Claessens , Jean-Paul Masy , Stijn De Loos
CPC classification number: C08L25/12 , C08G18/4072 , C08G18/632 , C08G18/636 , C08G2101/0008 , C08G2101/005 , C08G2101/0083 , C08G2650/58 , C08J9/0061 , C08J9/12 , C08J2375/08 , C08J2425/12
Abstract: Polymer polyols are made by polymerizing an ethylenically unsaturated monomer in a continuous polyol phase. The polymerization is stabilized with a macromer or a pre-formed polymer made by polymerizing or copolymerizing the macromer. The macromer is a random polymer of propylene oxide and ethylene oxide in defined ratios, which also contains polymerization carbon-carbon double or triple bond. Polymer polyols made in the process exhibit little viscosity rise when blended with water. Flexible polyurethane foam made from the polymer polyol exhibits excellent hardness, have good surface characteristics and, when pigmented, exhibit good, uniform coloration.
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