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公开(公告)号：US08197670B2
公开(公告)日：2012-06-12
申请号：US12711124
申请日：2010-02-23
申请人： Lin Li , Hua-Min Huang , Zunqing He
发明人： Lin Li , Hua-Min Huang , Zunqing He
IPC分类号： C10G17/00
CPC分类号： C10G31/08 , C10G2300/1033 , C10G2300/1074 , C10G2300/1077 , C10G2300/308 , C10G2300/805
摘要： A process is disclosed using a dispersion of supercritical fluid and oil to upgrade a hydrocarbon feedstock such as a heavy oil into an upgraded hydrocarbon product or synthetic crude with highly desirable properties such as low sulfur content, low metals content, lower density (higher API), lower viscosity, lower residuum content, etc. The process utilizes a capillary mixer to form the dispersion. The process does not require external supply of hydrogen nor does it use externally supplied catalysts.
摘要翻译： 公开了一种使用超临界流体和油的分散体将烃原料如重油升级成升级的烃产物或合成粗品的方法，其具有高度期望的性能，例如低硫含量，低金属含量，较低密度（较高的API） ，较低的粘度，较低的渣油含量等。该方法利用毛细管混合器形成分散体。 该方法不需要外部氢气供应，也不需要使用外部供应的催化剂。
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公开(公告)号：US20120103871A1
公开(公告)日：2012-05-03
申请号：US12914275
申请日：2010-10-28
申请人： Zunqing He , Zhen Zhou , Lin Li
发明人： Zunqing He , Zhen Zhou , Lin Li
CPC分类号： C10G27/02 , C10G27/06 , C10G33/00 , C10G2300/1033 , C10G2300/202 , C10G2400/08
摘要： A method for reducing mercaptan concentration in a liquid hydrocarbon, comprising: contacting a mercaptan-rich liquid hydrocarbon having a first concentration of mercaptan sulfur with a composition comprising an oxidizing agent and water wherein the molar ratio of the oxidizing agent to mercaptan sulfur in the mercaptan-rich liquid hydrocarbon is from 3:1 to 10:1; and separating the water from the liquid hydrocarbon to yield a mercaptan-depleted liquid hydrocarbon having a second concentration of mercaptan sulfur, the second concentration being less than the first concentration; wherein a major amount of mercaptan compounds in the mercaptan-rich liquid hydrocarbon are converted to at least one sulfur oxoacid or salt thereof, having the formula: [RSOx]nY wherein R is a hydrocarbyl group; x is an integer from 1 to 3; n is 1 or 2; and Y is hydrogen, an alkaline metal, or alkaline earth metal.
摘要翻译： 一种用于降低液体烃中硫醇浓度的方法，包括：使具有第一浓度的硫醇硫的富硫醇液体烃与包含氧化剂和水的组合物接触，其中硫醇中的氧化剂与硫醇的摩尔比 富液体烃为3：1至10：1; 并从液态烃中分离出水，得到具有第二浓度的硫醇硫的硫醇贫化液态烃，第二浓度小于第一浓度; 其中所述富硫醇溶液中的主要量的硫醇化合物被转化成至少一种具有下式的硫代酸或其盐：其中R是烃基的[RSO x] n Y; x是1至3的整数; n为1或2; Y是氢，碱金属或碱土金属。
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公开(公告)号：US20120024756A1
公开(公告)日：2012-02-02
申请号：US13180629
申请日：2011-07-12
申请人： Akshay Verma , Bi-Zeng Zhan , Zunqing He , Zhen Zhou , Marcus Dutra e Mellon , Sheila Yeh
发明人： Akshay Verma , Bi-Zeng Zhan , Zunqing He , Zhen Zhou , Marcus Dutra e Mellon , Sheila Yeh
CPC分类号： C10G25/003 , C10G25/12 , C10G45/58 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2400/10
摘要： A method is disclosed for removing impurities such as nitrogen and/or sulfur compounds from a hydrocarbon feed, in which the feed is contacted with an adsorbent including a nitrogen-containing organic heterocyclic salt deposited on a porous support, e.g., a supported ionic liquid. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including a supported ionic liquid. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including a supported ionic liquid. In one embodiment, the adsorbent is regenerated to restore its treatment capacity.
摘要翻译： 公开了一种用于从烃进料中除去诸如氮和/或硫化合物的杂质的方法，其中进料与包含沉积在多孔载体上的含氮有机杂环盐例如负载型离子液体的吸附剂接触。 另外，公开了一种加氢处理烃进料的方法，其包括加氢处理步骤，其中在加氢处理之前，将进料与包含负载离子液体的吸附剂接触。 另外，公开了一种含有基油馏分的异构化脱蜡的润滑油的制造方法，其中在异构化脱蜡工序之前，将基油馏分与含负载离子液体的吸附剂接触。 在一个实施方案中，吸附剂被再生以恢复其处理能力。
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公开(公告)号：US09296956B2
公开(公告)日：2016-03-29
申请号：US13281114
申请日：2011-10-25
申请人： Lin Li , Zunqing He , Zhen Zhou , King T. Ng , Paul E. Hajdu
发明人： Lin Li , Zunqing He , Zhen Zhou , King T. Ng , Paul E. Hajdu
CPC分类号： C10G17/07 , C10G19/02 , C10G53/10 , C10G53/12 , C10G2300/1033 , C10G2300/202
摘要： A method for reducing mercaptan concentration in a crude oil is disclosed. The method comprises contacting the crude with a treating solution comprising a hypochlorite solution, whereby the mercaptan sulfur is oxidized and converted to at least one sulfur oxoacid or salt thereof, yielding a treated crude oil having less than 50 ppm mercaptan sulfur and residual organic chloride. The treated crude oil containing residual organic chloride is brought in contact with a caustic solution at a molar ratio of caustic to chloride of 0.1:1 to 50:1, generating an upgraded crude oil with less than 10 ppm organic chloride. In one embodiment, the spent treating solution is recycled to form a regenerated hypochlorite stream for use in the treatment solution.
摘要翻译： 公开了一种降低原油中硫醇浓度的方法。 该方法包括使粗品与包含次氯酸盐溶液的处理溶液接触，由此硫醇硫被氧化并转化成至少一种含硫的含硫酸或其盐，产生具有小于50ppm硫醇硫和残余的有机氯化物的经处理的原油。 含有残余有机氯化物的处理过的原油与苛性碱溶液以0.1:1至50:1的苛性碱与氯化物的摩尔比接触，产生具有小于10ppm有机氯化物的升级原油。 在一个实施方案中，废处理溶液被再循环以形成用于处理溶液的再生次氯酸盐流。
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公开(公告)号：US08888993B2
公开(公告)日：2014-11-18
申请号：US13180629
申请日：2011-07-12
申请人： Akshay Verma , Bi Zeng Zhan , Zunqing He , Zhen Zhou , Marcus Dutra e Mellon , Sheila Yeh
发明人： Akshay Verma , Bi Zeng Zhan , Zunqing He , Zhen Zhou , Marcus Dutra e Mellon , Sheila Yeh
CPC分类号： C10G25/003 , C10G25/12 , C10G45/58 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2400/10
摘要： A method is disclosed for removing impurities such as nitrogen and/or sulfur compounds from a hydrocarbon feed, in which the feed is contacted with an adsorbent including a nitrogen-containing organic heterocyclic salt deposited on a porous support, e.g., a supported ionic liquid. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including a supported ionic liquid. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including a supported ionic liquid. In one embodiment, the adsorbent is regenerated to restore its treatment capacity.
摘要翻译： 公开了一种用于从烃进料中除去诸如氮和/或硫化合物的杂质的方法，其中进料与包含沉积在多孔载体上的含氮有机杂环盐例如负载型离子液体的吸附剂接触。 另外，公开了一种加氢处理烃进料的方法，其包括加氢处理步骤，其中在加氢处理之前，将进料与包含负载离子液体的吸附剂接触。 另外，公开了一种含有基油馏分的异构化脱蜡的润滑油的制造方法，其中在异构化脱蜡工序之前，将基油馏分与含负载离子液体的吸附剂接触。 在一个实施方案中，吸附剂被再生以恢复其处理能力。
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公开(公告)号：US20120074042A1
公开(公告)日：2012-03-29
申请号：US12889715
申请日：2010-09-24
申请人： Shabbir Husain , Lin Li , Zhen Zhou , Alexander E. Kuperman , Zunqing He , Huping Luo
发明人： Shabbir Husain , Lin Li , Zhen Zhou , Alexander E. Kuperman , Zunqing He , Huping Luo
IPC分类号： C10G29/04
CPC分类号： C10G29/00 , C10G29/04 , C10G29/06 , C10G2300/1011 , C10G2300/1033 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/203 , C10G2300/4018 , Y02P30/20
摘要： Disclosed are embodiments relating to a process for reducing the total acid number of a hydrocarbon feed by contacting the feed with a metal titanate catalyst having an MTiO3 structure wherein M is a metal having a valence of 2+, resulting in a hydrocarbon product having a final total acid number lower than the initial total acid number of the feed. The process is useful for pretreating high acid crudes prior to further processing thus avoiding corrosion of equipment used in refining operations. The process can be integrated into conventional refining operations in order to treat various refinery streams. In one embodiment, a process is provided for refining a low acid crude oil and a high acid crude oil by separately introducing a relatively low acid crude oil feed and a relatively high acid crude oil feed to an atmospheric distillation column, wherein the relatively high acid crude oil feed is contacted with a metal titanate catalyst prior to introduction to the atmospheric distillation column.
摘要翻译： 公开了通过使进料与具有MTiO 3结构的金属钛酸酯催化剂接触来降低烃进料的总酸值的方法的实施方案，其中M是具有2+价数的金属，导致烃产物具有最终的 总酸值低于进料的初始总酸值。 该方法可用于在进一步加工之前预处理高酸性原油，从而避免在精炼操作中使用的设备的腐蚀。 该方法可以集成到常规的精炼操作中，以便处理各种炼油流。 在一个实施方案中，提供了通过将相对低的酸性原油进料和相对高的酸性原油进料单独引入常压蒸馏塔来提炼低酸原油和高酸性原油的方法，其中相对高的酸 原油进料在引入常压蒸馏塔之前与钛酸金属催化剂接触。
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公开(公告)号：US20120024751A1
公开(公告)日：2012-02-02
申请号：US12847107
申请日：2010-07-30
申请人： Zunqing He , Akshay Verma , Bi-Zeng Zhan , Zhen Zhou
发明人： Zunqing He , Akshay Verma , Bi-Zeng Zhan , Zhen Zhou
CPC分类号： C10G25/003 , C10G67/06 , C10G2300/1037 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/202 , C10G2400/10
摘要： A denitrification method is disclosed for removing nitrogen compounds from a hydrocarbon feed in which the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a porous support. Additionally, a method for hydrotreating a hydrocarbon feed which includes a hydroprocessing step is disclosed, wherein prior to hydroprocessing, the feed is contacted with an adsorbent including an organic heterocyclic salt deposited on a support. Additionally, a method for producing a lube oil which includes isomerization dewaxing of a base oil fraction is disclosed, wherein prior to the isomerization dewaxing step, the base oil fraction is contacted with an adsorbent including an organic heterocyclic salt deposited on a support.
摘要翻译： 公开了一种用于从烃进料中除去氮化合物的脱氮方法，其中进料与包含沉积在多孔载体上的有机杂环盐的吸附剂接触。 另外，公开了一种加氢处理烃进料的方法，其包括加氢处理步骤，其中在加氢处理之前，将进料与包含沉积在载体上的有机杂环盐的吸附剂接触。 另外，公开了一种包含基油馏分的异构化脱蜡的润滑油的制造方法，其中在异构化脱蜡工序之前，使基油馏分与沉积在载体上的有机杂环盐的吸附剂接触。
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公开(公告)号：US20110203973A1
公开(公告)日：2011-08-25
申请号：US12711124
申请日：2010-02-23
申请人： Lin Li , Hua-Min Huang , Zunqing He
发明人： Lin Li , Hua-Min Huang , Zunqing He
CPC分类号： C10G31/08 , C10G2300/1033 , C10G2300/1074 , C10G2300/1077 , C10G2300/308 , C10G2300/805
摘要： A process is disclosed using a dispersion of supercritical fluid and oil to upgrade a hydrocarbon feedstock such as a heavy oil into an upgraded hydrocarbon product or synthetic crude with highly desirable properties such as low sulfur content, low metals content, lower density (higher API), lower viscosity, lower residuum content, etc. The process utilizes a capillary mixer to form the dispersion. The process does not require external supply of hydrogen nor does it use externally supplied catalysts.
摘要翻译： 公开了一种使用超临界流体和油的分散体将烃原料如重油升级成升级的烃产物或合成粗品的方法，其具有高度期望的性能，例如低硫含量，低金属含量，较低密度（较高的API） ，较低的粘度，较低的渣油含量等。该方法利用毛细管混合器形成分散体。 该方法不需要外部氢气供应，也不需要使用外部供应的催化剂。
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