摘要:
The invention relates to a process for preparing polymers for coating applications by polymerizing esters of acrylic acid or of methacrylic acid or vinyl aromatics or other free-radically polymerizable vinyl compounds or monomer mixtures composed predominantly of such monomers by means of a continuous polymerization process. In particular, the invention relates to a solvent-free preparation process for polymers, through which the binder can be prepared for coating applications with superior processing properties, very good thermal stability, improved pigment wetting and a higher gloss.
摘要:
Process for telomerizing noncyclic olefins having at least two conjugated double bonds with at least one nucleophile using a catalyst containing a metal of group 8, 9 or 10 of the Periodic Table of the Elements, wherein the overall telomerization process has a process step of catalyst recycling, in which hydrogen is added via a hydrogen source to the mixture present in this process step.
摘要:
The present invention relates to polyester acrylate graft copolymers comprising poly(meth)acrylates as graft substrate, the graft substrate having internal and/or terminal functional groups and polyester side chains as graft branches and/or having polyester blocks attached to at least one chain end of the graft substrate. The present invention further relates to processes for preparing the polyester acrylate graft copolymers and also to their use.
摘要:
Process for telomerizing noncyclic olefins having at least two conjugated double bonds with at least one nucleophile using a catalyst containing a metal of group 8, 9 or 10 of the Periodic Table of the Elements, wherein the overall telomerization process has a process step of catalyst recycling, in which hydrogen is added via a hydrogen source to the mixture present in this process step.
摘要:
Process for separating a metal complex catalyst from a reaction mixture obtained from a telomerization reaction, wherein the metal complex catalyst is separated off at least one membrane which is more permeable to the telomerization product than to the metal complex catalyst.
摘要:
The invention relates to a method for producing polymers for paint applications by polymerizing esters of acrylic acid or of methacrylic acid or vinyl aromatic compounds or other radically polymerizable vinyl compounds or monomer mixtures that consist predominantly of such monomers by means of a continuous polymerization method. The invention relates in particular to a solvent-free, continuous method of producing polymers, whereby it is possible to produce binders for paint applications having an adjustable granule size. The polymer granulates produced according to the invention are characterized by superior processing properties without fine fractions.
摘要:
Process for telomerizing noncyclic olefins having at least two conjugated double bonds with at least one nucleophile using a catalyst containing a metal of group 8, 9 or 10 of the Periodic Table of the Elements, wherein hydrogen is added via a hydrogen source to the process in at least one process step in the overall telomerization process.
摘要:
The present invention relates to a (meth)acrylate polymer for preparing a coating composition, where the (meth)acrylate polymer has a weight-average molecular weight in the range from 10 000 to 60 000 g/mol and the (meth)acrylate polymer comprises 0.5 to 40% by weight of units derived from (meth)acrylic monomers which in the alkyl radical have at least one double bond and 8 to 40 carbon atoms, 0.1 to 10% by weight of units derived from monomers containing acid groups, and 50 to 99.4% by weight of units derived from (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical that have no double bonds or heteroatoms in the alkyl radical, and these (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical are selected such that a polymer composed of these (meth)acrylates having 1 to 12 carbon atoms in the alkyl radical has a glass transition temperature of at least 40° C., based in each case on the weight of the (meth)acrylate polymer.The present invention further relates to a coating material comprising the stated polymer, and to a method of producing a coating. The present invention additionally describes a coated article comprising a coating obtainable by the method.