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51 条记录 (耗时 0.021 秒)

    Polycarbonates with end groups containing double bonds which can be crosslinked by UV light
    21.
    发明授权
    Polycarbonates with end groups containing double bonds which can be crosslinked by UV light 失效
    具有端基的聚碳酸酯含有双键，其可以通过UV光交联

    公开(公告)号：US4221645A

    公开(公告)日：1980-09-09

    申请号：US50899

    申请日：1979-06-21

    申请人： Siegfried Adelmann ,  Dieter Margotte ,  Hans J. Rosenkranz ,  Hugo Vernaleken ,  Werner Nouvertne ,  Dieter Freitag

    发明人： Siegfried Adelmann ,  Dieter Margotte ,  Hans J. Rosenkranz ,  Hugo Vernaleken ,  Werner Nouvertne ,  Dieter Freitag

    IPC分类号： C08F299/00 ,  C08F290/00 ,  C08F299/02 ,  C08F299/04 ,  C08G63/00 ,  C08G64/00 ,  C08G64/04 ,  C08G64/14 ,  C08G64/40 ,  C08J3/28 ,  C08F8/00

    CPC分类号： C08J3/28 ,  C08G64/045 ,  C08J2369/00

    摘要： High molecular weight aromatic polycarbonates having molecular weights M.sub.w (weight average) of between about 10,000 and 200,000, which are based on diphenols and monofunctional chain stoppers, which correspond to the general formula ##STR1## in which Z denotes the radical of a diphenol,n denotes an integer from 20 to 400,E denotes ##STR2## m is 0 or 1 and R denotes a hydrogen atom or a C.sub.1 to C.sub.3 alkyl group, and in which between about 0.5 and 5 mol % of Z are radicals of aromatic dihydroxyketones. These polycarbonates share mechanical and thermal properties with known polycarbonates but in addition are suitable for crosslinking, for example in the presence of photoinitiators and optionally photo-reducing agents and under irradiation with UV light. When crosslinked they are resistant to organic solvents and insensitive to stress-cracking, and have particularly good flame-repellent properties when additionally incorporating flameproofing agents.

    摘要翻译： 分子量Mw（重均分子量）在10,000和200,000之间的高分子量芳族聚碳酸酯，它们基于二酚和单官能链终止剂，其对应于通式（I），其中Z表示 二苯酚，n表示20〜400的整数，E表示m为0或1，R表示氢原子或C1〜C3烷基，其中约0.5〜5摩尔％的Z为 芳族二羟基酮。 这些聚碳酸酯与已知的聚碳酸酯共享机械和热性能，但另外适用于交联，例如在光引发剂和任选的光还原剂的存在下，并且在用UV光照射下。 当交联时，它们对有机溶剂具有耐受性并且对应力开裂不敏感，并且当额外加入防火剂时具有特别好的阻燃性能。

    Polymers containing 8-hydroxyquinoline groups
    24.
    发明授权
    Polymers containing 8-hydroxyquinoline groups 失效
    含有8-羟基喹啉基团的聚合物

    公开(公告)号：US4012362A

    公开(公告)日：1977-03-15

    申请号：US573837

    申请日：1975-05-02

    申请人： Gunther Reiff ,  Dieter Margotte ,  Karstel Idel ,  Hugo Vernaleken ,  Dieter Freitag

    发明人： Gunther Reiff ,  Dieter Margotte ,  Karstel Idel ,  Hugo Vernaleken ,  Dieter Freitag

    IPC分类号： C07D215/26 ,  C08F20/34 ,  C08F20/60 ,  C08F22/22 ,  C08F22/36 ,  C08F26/06 ,  C08F120/60

    CPC分类号： C08F22/36 ,  C07D215/26 ,  C08F20/34 ,  C08F20/60 ,  C08F22/22 ,  C08F26/06 ,  Y10S423/14

    摘要： Homo- and copolymers of monomers obtained by acylation of 2-[4-hydroxy(or amino)phenyl]-2-[5-(8-hydroxyquinolyl)]-propane with .alpha.,.beta.-monoolefinically unsaturated carboxylic acid halides or - anhydrides. As comonomers can be employed compounds containing one or more .alpha.,.beta.-olefinically unsaturated groups such as olefines, diolefines, acrylic acid derivatives, vinyl monomers. The polymers having molecular weights between 5000 - 500,000 can be prepared by radical or ionic chain mechanisms, in continuous or discontinuous processes. They may be used for removing metal ions from their solution, for complexing of interfering metallic impurities in thermoplastic or thermosetting resins or in form of their metal complexes as stabilizers for plastics.

    摘要翻译： 通过将2- [4-羟基（或氨基）苯基] -2- [5-（8-羟基喹啉基）] - 丙烷与α，β-单烯烃不饱和羧酸卤化物或 - 酸酐酰化获得的单体的均聚物和共聚物。 作为共聚单体，可以使用含有一个或多个α，β-烯属不饱和基团的化合物，例如烯烃，二烯，丙烯酸衍生物，乙烯基单体。 分子量在5000-500,000之间的聚合物可以通过自由基或离子链机制在连续或不连续过程中制备。 它们可用于从其溶液中除去金属离子，用于将干涉金属杂质与热塑性树脂或热固性树脂或其金属络合物的形式络合作为塑料稳定剂。

    Process for preparing esters of ethylenically unsaturated carboxylic acids
    25.
    发明授权
    Process for preparing esters of ethylenically unsaturated carboxylic acids 有权
    制备烯属不饱和羧酸酯的方法

    公开(公告)号：US6153788A

    公开(公告)日：2000-11-28

    申请号：US131026

    申请日：1998-08-07

    申请人： Wolfgang Fischer ,  Dieter Margotte ,  Jurgen Meixner

    发明人： Wolfgang Fischer ,  Dieter Margotte ,  Jurgen Meixner

    IPC分类号： C07C67/26 ,  C07C67/60 ,  C07C69/54 ,  C08G63/47 ,  C07C69/52

    CPC分类号： C07C67/60

    摘要： The present invention relates to a process for preparing unsaturated esters by azeo-tropically esterifyinga) monohydric or polyhydric alcohols orb) polyesters which contain at least two hydroxyl groups per molecule and are the reaction product of polyhydric alcohols with mono- or dibasis, saturated or aromatically unsaturated carboxylic acids,with ethylenically unsaturated carboxylic acids in the presence of an acid catalyst and subsequently reacting the acid catalyst and any unesterified carboxylic acid groups with ethylenically unsaturated monoepoxy compounds.

    摘要翻译： 本发明涉及一种通过将a）一元或多元醇或b）每分子含有至少两个羟基的聚酯并且是多元醇与单 - 或二 - 二饱和的多元醇的反应产物 - 或芳族不饱和羧酸与烯键式不饱和羧酸在酸催化剂的存在下反应，随后使酸催化剂和任何未酯化的羧酸基团与烯属不饱和单环氧化合物反应。

    Polyurethane coating compositions containing polyether polyols as additives
    26.
    发明授权
    Polyurethane coating compositions containing polyether polyols as additives 失效
    含聚醚多元醇作为添加剂的聚氨酯涂料组合物

    公开(公告)号：US5308912A

    公开(公告)日：1994-05-03

    申请号：US971449

    申请日：1992-11-04

    申请人： Dieter Margotte ,  Werner Kubitza

    发明人： Dieter Margotte ,  Werner Kubitza

    IPC分类号： C08G18/08 ,  C08G18/40 ,  C08G18/70 ,  C09D175/04 ,  C09D175/08 ,  C08L75/06

    CPC分类号： C08G18/706 ,  C08G18/0819 ,  C08G18/4063 ,  C09D175/04

    摘要： The present invention relates to an aqueous coating composition containinga) an aqueous solution or dispersion of a polyol component containing at least one water-dilutable polyacrylate resin having hydroxyl groups and a molecular weight (M.sub.n) above 500,b) a polyisocyanate component which has a viscosity of 50 to 10,000 mPa.s at 23.degree. C. and is emulsified in component a), andc) 0.5 to 6% by weight, based on the weight of component a), of a water-soluble polyether polyol having a molecular weight of 300 to 1000,wherein the coating composition has an NCO/OH equivalent ratio of 0.5:1 to 5:1, based on the isocyanate groups of component b) and the alcoholic hydroxyl groups of components a) and c).

    摘要翻译： 本发明涉及一种水性涂料组合物，其含有a）多元醇组分的水溶液或分散体，其含有至少一种具有羟基并且分子量（Mn）在500以上的水可稀释的聚丙烯酸酯树脂，b）多异氰酸酯组分，其具有 在23℃下的粘度为50至10,000mPa.s，并在组分a）中乳化，c）基于组分a）的重量计为0.5至6重量％的水溶性聚醚多元醇，其具有 分子量为300〜1000，其中涂料组合物的NCO / OH当量比为0.5:1至5:1，基于组分b）的异氰酸酯基和组分a）和c）的醇羟基。

    Solutions of isocyanurate polyisocyanates in coatings solvents and a process for their production
    27.
    发明授权
    Solutions of isocyanurate polyisocyanates in coatings solvents and a process for their production 失效
    异氰脲酸酯多异氰酸酯在涂料溶剂中的溶液及其制备方法

    公开(公告)号：US5064960A

    公开(公告)日：1991-11-12

    申请号：US571465

    申请日：1990-08-22

    申请人： Josef Pedain ,  Dieter Margotte

    发明人： Josef Pedain ,  Dieter Margotte

    IPC分类号： C08G18/02 ,  C07D251/34 ,  C08G18/79 ,  C08G18/80 ,  C09D175/00

    CPC分类号： C08G18/794 ,  C07D251/34 ,  C08G18/8064

    摘要： The present invention relates to a process for the preparation of a composition containing an isocyanurate polyisocyanate dissolved in a solvent inert to isocyanate groups bya) reacting 2.5 to 7% of the isocyanate groups of a starting diisocyanate based on 2,4-diisocyanatotoluene or a mixture of 2,4-diisocyanatotoluene and 2,6-diisocyanatotoluene with a monohydric alcohol corresponding to the formula ##STR1## wherein R.sub.1 is an aliphatic or cycloaliphatic C.sub.6-18 hydrocarbon radical which may be olefinically unsaturated,R.sub.2 is hydrogen or a methyl group, andn is 0 or an integer from 1 to 3,b) adding a sufficient amount of an organic solvent which is inert to isocyanate groups to form a 30 to 70% solution of the urethanized diisocyanate either before, during or after step a),c) subsequently partially trimerizing the remaining isocyanate groups of said urethanized diisocyanate in the presence of a catalyst which accelerates the trimerization of isocyanate groups andd) terminating the trimerization reaction when the content of unreacted diisocyanotoluene is less than 0.5% by weight by the addition of a catalyst poison.The present invention also relates to the solutions of isocyanurate polyisocyanates obtained by this process.

    摘要翻译： 本发明涉及一种制备含有异氰脲酸酯多异氰酸酯的组合物的方法，所述组合物溶解在对异氰酸酯基团惰性的溶剂中，通过以下步骤：a）使2.5至7％的起始二异氰酸酯基于2,4-二异氰酸根合甲苯或 2,4-二异氰酸根合甲苯和2,6-二异氰酸基甲苯与一种对应于式R 1的一元醇的混合物，其中R 1是可以是烯属不饱和的脂族或脂环族C 6-18烃基，R 2是氢或甲基 ，n为0或1〜3的整数，b）在步骤a）之前，期间或之后，加入足够量的异氰酸酯基惰性的有机溶剂，形成氨基甲酸酯化二异氰酸酯的30〜70％ c）随后在催化剂存在下将所述氨基甲酸酯化二异氰酸酯的剩余异氰酸酯基部分三聚化，催化剂加速异氰酸酯基团的三聚化，和d）终止 当未反应的二异氰酰甲苯的含量通过加入催化剂毒物小于0.5重量％时，三聚反应。 本发明还涉及通过该方法获得的异氰脲酸酯多异氰酸酯的溶液。

    Process for the preparation of (meth)acrylic acid esters and their use
    28.
    发明授权
    Process for the preparation of (meth)acrylic acid esters and their use 失效
    制备（甲基）丙烯酸酯的方法及其用途

    公开(公告)号：US4748269A

    公开(公告)日：1988-05-31

    申请号：US851742

    申请日：1986-04-14

    申请人： Jurgen Meixner ,  Josef Pedain ,  Peter Hohlein ,  Dieter Margotte

    发明人： Jurgen Meixner ,  Josef Pedain ,  Peter Hohlein ,  Dieter Margotte

    IPC分类号： C07C69/54 ,  C08F2/46 ,  C08F220/36 ,  C07C69/52

    CPC分类号： C07C69/54 ,  C07C67/08 ,  C07C67/60

    摘要： (Meth)acrylic acid esters can be prepared by acid-catalyzed reaction of (meth)acrylic acid with alcohols in a water-immiscible solvent. After the esterification, the reaction mixture is washed with aqueous solutions having an alkaline reaction and then reacted at elevated temperature with carbodiimides. Acid numbers below 0.5 (mg of KOH/g of substance) are obtained in this way. (Meth)acrylic acid esters are used, for example, as reactive diluents or as comonomers.

    摘要翻译： （甲基）丙烯酸酯可以通过（甲基）丙烯酸与醇在水不混溶溶剂中的酸催化反应来制备。 酯化后，反应混合物用碱性反应的水溶液洗涤，然后在高温下与碳二亚胺反应。 以这种方式获得酸值低于0.5（KOH / g的物质）。 （甲基）丙烯酸酯用作例如作为反应性稀释剂或共聚单体。