公开(公告)号：US20110256615A1

公开(公告)日：2011-10-20

申请号：US13057968

申请日：2009-12-22

申请人： Michael Brady ,  Dennis Stamires ,  Paul O'Connor

发明人： Michael Brady ,  Dennis Stamires ,  Paul O'Connor

IPC分类号： C12P1/00 ,  C10L5/00

CPC分类号： D21C1/02 ,  C12P2201/00 ,  D21C3/00 ,  D21C11/0007 ,  Y02E50/16

摘要： A process is disclosed for preparing biomass particles for thermolytic or enzymatic conversion whereby the biomass particles baying a moisture content of at least 20% are subjected to flash heating. The flash heating may be preceded by one or more adsorption/desorption cycles with water or steam. A swelling aid may be added during the adsorption part of an adsorption/desorption cycle.

摘要翻译： 公开了一种用于制备用于热分解或酶促转化的生物质颗粒的方法，其中使水分含量至少为20％的生物质颗粒经受闪蒸加热。 闪蒸加热之前可以用水或蒸汽进行一次或多次吸附/解吸循环。 在吸附/解吸循环的吸附部分可以加入溶胀助剂。

公开(公告)号：US20110114765A1

公开(公告)日：2011-05-19

申请号：US12934006

申请日：2009-11-30

申请人： Michael Brady ,  Robert Bartek ,  Dennis Stamires ,  Paul O'Connor

发明人： Michael Brady ,  Robert Bartek ,  Dennis Stamires ,  Paul O'Connor

IPC分类号： B02C19/18 ,  B02C19/00

CPC分类号： D21B1/02 ,  D21B1/021 ,  Y02E50/14

摘要： A method is disclosed for reducing the mechanical strength of solid biomass material, in particular ligno-cellulosic biomass. The method comprises heating the solid biomass material to a temperature in the range of 105° C. to 200° C. The heat treatment, which is referred to as “toasting”, significantly reduces the mechanical energy required for reducing the particle size of the solid biomass material.The method is particularly suitable as a pretreatment step to a conversion reaction of the solid biomass material.

摘要翻译： 公开了一种降低固体生物质材料，特别是木质纤维素生物质的机械强度的方法。 该方法包括将固体生物质材料加热至105℃至200℃的温度。被称为“烘烤”的热处理显着降低了降低颗粒尺寸所需的机械能 固体生物质材料。 该方法特别适用于固体生物质材料的转化反应的预处理步骤。

公开(公告)号：US20070272594A1

公开(公告)日：2007-11-29

申请号：US10582593

申请日：2004-12-06

申请人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

发明人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

IPC分类号： B01J23/02

CPC分类号： B01J23/10 ,  B01J23/02 ,  B01J29/06 ,  B01J29/088 ,  B01J37/03 ,  B01J37/04 ,  B01J2229/20 ,  B01J2229/42 ,  C10G11/04 ,  C10G11/05

摘要： The invention relates to an oxidic catalyst composition comprising 5-60 wt % of a divalent metal, 5-60 wt % of a trivalent metal, and 35-60 wt % of a rare earth metal, calculated as oxide and based on the total weight of the oxidic catalyst composition. The invention also relates to a process for preparing such an oxidic catalyst composition. This composition is suitable as metal trap in FCC processes.

摘要翻译： 本发明涉及氧化催化剂组合物，其包含5-60重量％的二价金属，5-60重量％的三价金属和35-60重量％的稀土金属，以氧化物计，基于总重量 的氧化催化剂组合物。 本发明还涉及制备这种氧化催化剂组合物的方法。 该组合物适用于FCC工艺中的金属捕集剂。

公开(公告)号：US08288600B2

公开(公告)日：2012-10-16

申请号：US12917988

申请日：2010-11-02

申请人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus Cornelius Rasser

发明人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus Cornelius Rasser

IPC分类号： C10L1/00

CPC分类号： C10G11/18 ,  C10G1/002 ,  C10G1/06 ,  C10G1/08 ,  C10G3/42 ,  C10G3/50 ,  C10G3/56 ,  C10G3/57 ,  C10G3/62 ,  C10G45/02 ,  C10G47/00 ,  C10G47/02 ,  C10G47/30 ,  C10G47/34 ,  C10G49/007 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  Y02P30/20

摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.

摘要翻译： 本文公开了一种从生物质生产燃料的方法。 该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。 将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。 将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质 的悬浮液转化为燃料。

公开(公告)号：US08168840B2

公开(公告)日：2012-05-01

申请号：US12921343

申请日：2009-06-25

申请人： Michael Brady ,  Paul O'Connor ,  Dennis Stamires

发明人： Michael Brady ,  Paul O'Connor ,  Dennis Stamires

IPC分类号： C10G1/00

CPC分类号： C10L1/04 ,  C08L97/00 ,  C10G1/00 ,  C10G1/083 ,  C10G2300/1014 ,  C10G2300/44 ,  C10G2300/80 ,  C12P2201/00 ,  C13K1/02 ,  D21C1/04 ,  D21C1/06 ,  D21C11/0007 ,  Y02E50/16 ,  Y02P30/20

摘要： A process is described for pretreating lignocellulosic biomass. The process comprises swelling the lignocellulosic biomass with an aqueous liquid. The pretreated lignocellulosic biomass may be used as a feedstock for the enzymatic conversion to ethanol, or in a thermal conversion. process to produce bio-oil. The pretreatment results in a greater yield and, in the case of a thermal conversion process, a better quality of the bio-oil. The pretreatment process may be used to adjust the composition and amount of inorganic material present in the lignocellulosic biomass material.

摘要翻译： 描述了一种用于预处理木质纤维素生物质的方法。 该方法包括用含水液体使木质纤维素生物质膨胀。 预处理的木质纤维素生物质可以用作酶转化成乙醇或热转化的原料。 生产生物油的过程。 预处理导致更高的产量，并且在热转化过程的情况下，生物油的质量更好。 预处理方法可用于调节木质纤维素生物质材料中存在的无机材料的组成和量。

公开(公告)号：US10457873B2

公开(公告)日：2019-10-29

申请号：US13259233

申请日：2010-03-24

申请人： Dennis Stamires ,  Michael Brady ,  Paul O'Connor ,  Jacobus Cornelis Rasser

发明人： Dennis Stamires ,  Michael Brady ,  Paul O'Connor ,  Jacobus Cornelis Rasser

IPC分类号： C10B47/00 ,  C10B53/02 ,  C10B49/16 ,  C10B57/08 ,  C10C5/00 ,  C10L1/02 ,  C10L9/02 ,  C10G1/00 ,  C10G1/02

摘要： A process is disclosed for converting a particulate solid biomass material to a high quality bio-oil in high yield. The process comprises a pretreatment step and a pyrolysis step. The pretreatment comprises a step of at least partially demineralizing the solid biomass, and improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass. In a preferred embodiment the liquid pyrolysis product is separated into the bio-oil and an aqueous phase, and the aqueous phase is used as a solvent in the demineralization step and/or in the step of improving the accessibility of the solid biomass by opening the texture of the particles of the solid biomass.

公开(公告)号：US08876925B2

公开(公告)日：2014-11-04

申请号：US13139954

申请日：2009-12-22

申请人： Michael Brady ,  Dennis Stamires ,  Paul O'Connor

发明人： Michael Brady ,  Dennis Stamires ,  Paul O'Connor

IPC分类号： C10L5/00 ,  C10G31/09 ,  C10G1/06 ,  C10G3/00 ,  C10G21/00 ,  C10G31/10

CPC分类号： C10G3/00 ,  C10G1/06 ,  C10G21/00 ,  C10G31/09 ,  C10G31/10 ,  C10G2300/1014 ,  C10G2300/205 ,  Y02P30/20

摘要： A process is disclosed for converting a biomass material to a stabilized bio-oil. The process comprises converting the biomass to a pyrolytic oil having suspended therein particles of metal compounds, and removing at least part of the suspended metal compounds to obtain a stabilized bio-oil.

摘要翻译： 公开了将生物质材料转化为稳定的生物油的方法。 该方法包括将生物质转化为具有悬浮在其中的金属化合物颗粒的热解油，并除去至少部分悬浮的金属化合物以获得稳定的生物油。

公开(公告)号：US20110154720A1

公开(公告)日：2011-06-30

申请号：US12917988

申请日：2010-11-02

申请人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus C. Rasser

发明人： Robert Bartek ,  Michael Brady ,  Dennis Stamires ,  Steve Yanik ,  Paul O'Connor ,  Jacobus C. Rasser

IPC分类号： C10L1/00 ,  B01J8/00

CPC分类号： C10G11/18 ,  C10G1/002 ,  C10G1/06 ,  C10G1/08 ,  C10G3/42 ,  C10G3/50 ,  C10G3/56 ,  C10G3/57 ,  C10G3/62 ,  C10G45/02 ,  C10G47/00 ,  C10G47/02 ,  C10G47/30 ,  C10G47/34 ,  C10G49/007 ,  C10G2300/1011 ,  C10G2300/1014 ,  C10G2300/107 ,  C10G2300/1074 ,  C10G2300/1077 ,  Y02P30/20

摘要： A process for producing fuel from biomass is disclosed herein. The process includes torrefying biomass material at a temperature between 80° C. to 400° C. to form particulated biomass having a mean average particle size between 1 μm and 1000 μm. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes from 1 weight percent to 40 weight percent particulated biomass. The suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit, and then at least a portion of the particulated biomass of the suspension is converted into fuel.

摘要翻译： 本文公开了一种从生物质生产燃料的方法。 该方法包括在80℃至400℃的温度下焙烧生物质材料，以形成平均粒度为1μm至1000μm的颗粒状生物质。 将颗粒状生物质与液体烃混合以形成悬浮液，其中悬浮液包括1重量％至40重量％的颗粒生物质。 将悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置中的单元中，然后将至少一部分颗粒生物质 的悬浮液转化为燃料。

公开(公告)号：US20090048097A1

公开(公告)日：2009-02-19

申请号：US10582601

申请日：2004-12-06

申请人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

发明人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

IPC分类号： B01J27/232 ,  B01J27/14 ,  B01J23/00 ,  B01J27/24 ,  B01J23/34 ,  B01J23/745 ,  B01J23/75 ,  B01J23/72 ,  B01J23/06 ,  B01J23/02 ,  B01J21/02 ,  B01J23/26 ,  B01J23/22 ,  B01J23/28 ,  B01J23/30 ,  B01J23/10

CPC分类号： B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/22 ,  B01J23/24 ,  B01J23/78 ,  B01J23/83 ,  B01J23/868 ,  B01J23/8892 ,  B01J27/18 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/03 ,  B01J37/04 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  C10G11/04 ,  C10G11/18 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3706

摘要： Process for the preparation of an oxidic catalyst composition consisting of one or more trivalent metals preferably aluminum, one or more divalent metals preferably magnesium and more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the steps of preparing a precursor mixture consisting of (i) or more trivalent metal compounds, (ii) one or more divalent metal compounds, (iii) one or more compounds selected from the group consisting of rare earth metal compounds, and transition metal compounds, and (iv) optionally water, which precursor mixture is not a solution. The resulting oxidic catalyst composition is suitable as a metal trap and SOx sorbent FCC processes.

摘要翻译： 制备由一种或多种三价金属组成的氧化催化剂组合物的方法，优选铝，一种或多种二价金属，优选镁和大于18wt％的一种或多种选自稀土金属化合物，磷化合物 和过渡金属化合物，该方法包括制备由（i）或更多种三价金属化合物组成的前体混合物，（ii）一种或多种二价金属化合物，（iii）一种或多种选自以下的化合物的步骤： 稀土金属化合物和过渡金属化合物，和（iv）任选的水，该前体混合物不是溶液。 所得到的氧化催化剂组合物适合作为金属捕集剂和SOx吸附剂FCC方法。

公开(公告)号：US20070287626A1

公开(公告)日：2007-12-13

申请号：US10582305

申请日：2004-12-06

申请人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

发明人： William Jones ,  Dennis Stamires ,  Paul O'Connor ,  Michael Brady

IPC分类号： B01J23/10 ,  B01J29/06 ,  B01J35/00 ,  B01J37/03 ,  C10G11/04 ,  C10G11/05 ,  C10G45/04

CPC分类号： B01J23/002 ,  B01J23/02 ,  B01J23/06 ,  B01J23/10 ,  B01J23/22 ,  B01J23/24 ,  B01J23/78 ,  B01J23/83 ,  B01J23/868 ,  B01J23/8892 ,  B01J27/18 ,  B01J29/06 ,  B01J35/0006 ,  B01J35/002 ,  B01J37/03 ,  B01J37/04 ,  B01J2229/20 ,  B01J2229/42 ,  B01J2523/00 ,  C10G11/04 ,  C10G11/18 ,  B01J2523/22 ,  B01J2523/31 ,  B01J2523/3706

摘要： Process for the preparation of an oxidic composition comprising a trivalent metal, a divalent metal and—calculated as oxide and based on the total composition—more than 18 wt % of one or more compounds selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, which process comprises the following steps: (a) preparing a precursor mixture comprising (i) a compound 1 being a trivalent metal compound, (ii) a compound 2 being a divalent metal compound, and (iii) a compound 3 being different from compounds 1 and 2 and being selected from the group consisting of rare earth metal compounds, phosphorus compounds, and transition metal compounds, (b) optionally aging the mixture, without anionic clay being formed, (c) drying the mixture, and (d) calcining the product of step c). The resulting oxidic composition is suitable as a metal trap and SOx sorbent FCC processes.

摘要翻译： 用于制备包含三价金属，二价金属和以氧化物计算并基于总组合物的氧化组合物的方法 - 大于18重量％的一种或多种选自稀土金属化合物，磷 化合物和过渡金属化合物，该方法包括以下步骤：（a）制备前体混合物，其包含（i）化合物1为三价金属化合物，（ii）化合物2为二价金属化合物，和（iii） 化合物3不同于化合物1和2，并且选自稀土金属化合物，磷化合物和过渡金属化合物，（b）任选地老化该混合物，而不形成阴离子粘土，（c）干燥 混合物，和（d）煅烧步骤c）的产物。 所得的氧化物组合物适合用作金属捕集剂和SO x x吸附剂FCC方法。