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    Process for the production of organosilicon compounds
    22.
    发明授权
    Process for the production of organosilicon compounds 失效
    生产有机硅化合物的方法

    公开(公告)号：US5068382A

    公开(公告)日：1991-11-26

    申请号：US491775

    申请日：1990-03-12

    申请人： Hartwig Rauleder ,  Hans-Joachim Kotzch

    发明人： Hartwig Rauleder ,  Hans-Joachim Kotzch

    IPC分类号： C07F7/18

    CPC分类号： C07F7/188 ,  C07F7/182

    摘要： Organosilicon compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently straight or branched alkyl of 1 to 4 carbon atoms or --OR.sup.3,R.sup.3 is R.sup.4 --(OR.sup.5).sub.m --,R.sup.6 is straight or branched alkyl of 1 to 4 carbon atoms,m is an integer from 0 to 6, inclusive,R.sup.5 is straight or branched alkylene of 2 to 4 carbon atoms, which may be identical or different when m is an integer from 2 to 6, andR.sup.6 is straight or branched alkylene of 2 to 6 carbon atoms,are prepared by reacting hydrogensilanes of the formula ##STR2## wherein R.sup.7 are identical or different groups R.sup.4 or the group OR.sup.4, and R.sup.4 has the previously indicated meaning,with terminally unsaturated ethers of the formulaR.sup.4 --(OR.sup.5).sub.m --OR.sup.8whereinm, R.sup.4 and R.sup.5 have the previously indicated meanings, andR.sup.8 is terminally unsaturated straight or branched alkenyl or 2 to 6 carbon atoms,in the presence of a catalyst at controlled temperatures to form addition products of the formula ##STR3## wherein m and R.sup.4, R.sup.5, R.sup.6 and R.sup.7 have the previously indicated meanings, and the R.sup.4 's are identical or differentwhich are converted into the desired end products by thermal and/or catalytic transesterification with monofunctional hydroxy compounds of the formulaR.sup.4 --(OR.sup.5).sub.m OHwhereinm, R.sup.4 and R.sup.5 have the previously indicated meanings.

    摘要翻译： 其中R 1和R 2各自独立地为具有1至4个碳原子的直链或支链烷基或-OR 3，R 3为R 4 - （OR 5）m - ，R 6为具有1至4个碳原子的直链或支链烷基的有机硅化合物 原子，m为0〜6的整数，包括0和6的整数，R 5为2〜4个碳原子的直链或支链亚烷基，当m为2〜6的整数时，可以相同或不同，R6为直链或支链的亚烷基 2至6个碳原子的化合物通过使下式的化合物：其中R 7为相同或不同的基团R 4或基团OR 4，且R 4具有前述含义的氢化山西与式R4-（OR5）的末端不饱和醚反应制备， m-OR 8，其中m，R 4和R 5具有前述含义，并且R 8是在受控温度下在催化剂存在下的末端不饱和的直链或支链烯基或2-6个碳原子，以形成下式的加成产物： 其中m和R4，R5，R6和R7具有之前的 并且R4相同或不同，其通过用式R 4 - （OR 5）m OH的单官能羟基化合物的热和/或催化酯交换转化为所需的最终产物，其中m，R 4和R 5具有前面所述的含义。

    Process for the coupled preparation of trisilylamine and polysilazanes having a molar mass of up to 500 g/mol
    23.
    发明授权
    Process for the coupled preparation of trisilylamine and polysilazanes having a molar mass of up to 500 g/mol 有权
    具有摩尔质量高达500g / mol的三甲胺和聚硅氮烷的偶联制备方法

    公开(公告)号：US09446954B2

    公开(公告)日：2016-09-20

    申请号：US14345587

    申请日：2013-06-05

    申请人： Carl-Friedrich Hoppe ,  Christian Goetz ,  Goswin Uehlenbruck ,  Hartwig Rauleder

    发明人： Carl-Friedrich Hoppe ,  Christian Goetz ,  Goswin Uehlenbruck ,  Hartwig Rauleder

    IPC分类号： C01B21/087 ,  B01D3/14 ,  C08G77/62 ,  B01J19/24

    CPC分类号： C01B21/087 ,  B01D3/143 ,  B01J19/24 ,  B01J2219/24 ,  C08G77/62

    摘要： The invention relates to a process for preparing trisilylamine and polysilazanes in the liquid phase, in which ammonia is introduced in a superstoichiometric amount relative to 5 monochlorosilane which is present in an inert solvent. Here, a reaction in which trisilylamine and polysilazanes are formed proceeds. TSA is subsequently separated off in gaseous form from the product mixture. The TSA obtained is purified by filtration and distillation and obtained in high or very high purity. The bottom product mixture is conveyed from the reactor through a filter unit in which solid ammonium chloride is separated off to give a liquid mixture of polysilazanes and solvent. This is fed to a further distillation to recover solvent. As a result of the NH3 being introduced in a superstoichiometric amount relative to monochlorosilane, monochlorosilane is completely reacted in the reactor. This completely prevents the reaction of monochlorosilane with additional disilylamine formed in small amounts to form solid ammonium chloride in the downstream plant parts for purification of the TSA. The solutions filtered downstream of the reactor are accordingly completely free of solids.

    摘要翻译： 本发明涉及一种在液相中制备三甲胺和聚硅氮烷的方法，其中相对于存在于惰性溶剂中的5个一氯硅烷，以超化学计量的量引入氨。 这里，形成三甲基胺和聚硅氮烷的反应。 TSA随后从产物混合物中分离出气态。 通过过滤和蒸馏纯化获得的TSA，得到高纯度或非常高的纯度。 底部产物混合物从反应器通过过滤器单元输送，其中分离固体氯化铵以得到聚硅氮烷和溶剂的液体混合物。 将其进料进一步蒸馏以回收溶剂。 作为相对于一氯硅烷以超化学计量量引入NH 3的结果，一氯硅烷在反应器中完全反应。 这完全防止一氯甲硅烷与少量形成的另外的二甲硅烷的反应在下游的植物部分中形成固体氯化铵，用于纯化TSA。 因此，在反应器下游过滤的溶液完全不含固体。

    Method for producing hydridosilanes
    26.
    发明授权
    Method for producing hydridosilanes 有权
    生产氢硅烷的方法

    公开(公告)号：US09017630B2

    公开(公告)日：2015-04-28

    申请号：US13504331

    申请日：2010-11-08

    申请人： Stephan Wieber ,  Matthias Patz ,  Martin Trocha ,  Hartwig Rauleder ,  Ekkehard Mueh ,  Harald Stueger ,  Christoph Walkner

    发明人： Stephan Wieber ,  Matthias Patz ,  Martin Trocha ,  Hartwig Rauleder ,  Ekkehard Mueh ,  Harald Stueger ,  Christoph Walkner

    IPC分类号： C01B33/04 ,  C01B33/107

    CPC分类号： C01B33/04 ,  C01B33/043 ,  C01B33/10773 ,  Y10T428/31663

    摘要： The invention relates to a method for producing hydridosilanes from halosilanes by a) reacting i) at least one halosilane of the generic formula SinX2n+2 (with n≧3 and X═F, Cl, Br and/or I) with ii) at least one catalyst of the generic formula NRR'aR″bYc with a=0 or 1, b=0 or 1, and c=0 or 1, and formula (I), wherein aa) R, R′ and/or R″ are —C1-C12 alkyl, —C1-C12 aryl, —C1-C12 aralkyl, —C1-C12 aminoalkyl, —C1-C12 aminoaryl, —C1-C12 aminoaralkyl, and/or two or three groups R, R′ and R″ (if c=0) together form a cyclic or bicyclic, heteroaliphatic or heteroaromatic system including N, with the proviso that at least one group R, R′ or R″ is unequal —CH3 and/or wherein bb) R and R′ and/or R″' (if c=1) are —C1-C12 alkylene, —C1-C12 arylene, —C1-C12 aralkylene, —C1-C12 heteroalkylene, —C1-C12 heteroarylene, —C1-C12 heteroaralkylene and/or —N═, or cc) (if a=b=c=0) R═≡C-R′″ (with R′″═—C1-C10 alkyl, —C1-C10 aryl and/or —C1-C10 aralkyl), while forming a mixture comprising at least one halosilane of the generic formula SimX2m+2 (with m>n and X═F, Cl, Br and/or I) and SiX4 (with X═F, Cl, Br and/or I), and b) hydrogenating the at least one halosilane of the generic formula SimH2m+2 while forming a hydridosilane of the generic formula SimH2m+2. The invention also relates to the hydridosilanes producible according to said method and to their use.

    摘要翻译： 本发明涉及一种由卤代硅烷生产氢硅烷的方法，其通过以下步骤：a）使i）至少一种通式为SinX2n + 2（n≥3，X = F，Cl，Br和/或I）的卤代硅烷与ii） a = 0或1，b = 0或1，c = 0或1和式（I）的通式NRR'aR“bYc的至少一种催化剂，其中aa）R，R'和/或R” 是-C 1 -C 12烷基，-C 1 -C 12芳基，-C 1 -C 12芳烷基，-C 1 -C 12氨基烷基，-C 1 -C 12氨基芳基，-C 1 -C 12氨基烷基和/或两个或三个基团R，R'和R “（如果c = 0）一起形成包括N的环状或双环，杂脂族或杂芳族体系，条件是至少一个基团R，R'或R”不等于-CH 3和/或其中bb）R和R' 和/或R“'（如果c = 1）是-C 1 -C 12亚烷基，-C 1 -C 12亚芳基，-C 1 -C 12亚芳基，-C 1 -C 12杂亚烷基，-C 1 -C 12亚杂芳基，-C 1 -C 12杂亚烷基和/ 或-N =或cc）（如果a = b = c = 0）R≡≡CR'“（其中R'”= C 1 -C 10烷基，-C 1 -C 10芳基和/或-C 1 -C 10芳烷基），同时形成包含通式SimX2m + 2（具有m> n和X = F，Cl，Br和/或I）的至少一种卤代硅烷和SiX 4（具有X = F，Cl，Br和 /或I），和b）在形成通式SimH 2 m + 2的氢硅烷的同时使通式SimH 2 m + 2的至少一种卤代硅烷氢化。 本发明还涉及根据所述方法可生产的氢硅石及其用途。

    METHOD FOR PRODUCING HYDRIDOSILANES
    28.
    发明申请
    METHOD FOR PRODUCING HYDRIDOSILANES 有权
    生产水合物的方法

    公开(公告)号：US20120214005A1

    公开(公告)日：2012-08-23

    申请号：US13504331

    申请日：2010-11-08

    申请人： Stephan Wieber ,  Matthias Patz ,  Martin Trocha ,  Hartwig Rauleder ,  Ekkehard Mueh ,  Harald Stueger ,  Christoph Walkner

    发明人： Stephan Wieber ,  Matthias Patz ,  Martin Trocha ,  Hartwig Rauleder ,  Ekkehard Mueh ,  Harald Stueger ,  Christoph Walkner

    IPC分类号： B32B9/04 ,  C01B33/04

    CPC分类号： C01B33/04 ,  C01B33/043 ,  C01B33/10773 ,  Y10T428/31663

    摘要： The invention relates to a method for producing hydridosilanes from halosilanes by a) reacting i) at least one halosilane of the generic formula SinX2n+2 (with n≧3 and X═F, Cl, Br and/or I) with ii) at least one catalyst of the generic formula NRR'aR″bYc with a=0 or 1, b=0 or 1, and c=0 or 1, and formula (I), wherein aa) R, R′ and/or R″ are —C1-C12 alkyl, —C1-C12 aryl, —C1-C12 aralkyl, —C1-C12 aminoalkyl, —C1-C12 aminoaryl, —C1-C12 aminoaralkyl, and/or two or three groups R, R′ and R″ (if c=0) together form a cyclic or bicyclic, heteroaliphatic or heteroaromatic system including N, with the proviso that at least one group R, R′ or R″ is unequal —CH3 and/or wherein bb) R and R′ and/or R″' (if c=1) are —C1-C12 alkylene, —C1-C12 arylene, —C1-C12 aralkylene, —C1-C12 heteroalkylene, —C1-C12 heteroarylene, —C1-C12 heteroaralkylene and/or —N═, or cc) (if a=b=c=0) R═≡C-R′″ (with R′″═—C1-C10 alkyl, —C1-C10 aryl and/or —C1-C10 aralkyl), while forming a mixture comprising at least one halosilane of the generic formula SimX2m+2 (with m>n and X═F, Cl, Br and/or I) and SiX4 (with X═F, Cl, Br and/or I), and b) hydrogenating the at least one halosilane of the generic formula SimH2m+2 while forming a hydridosilane of the generic formula SimH2m+2. The invention also relates to the hydridosilanes producible according to said method and to their use

    摘要翻译： 本发明涉及一种由卤代硅烷生产氢硅烷的方法，其通过以下步骤：a）使i）至少一种通式为SinX2n + 2（n≥3，X = F，Cl，Br和/或I）的卤代硅烷与ii） a = 0或1，b = 0或1，c = 0或1和式（I）的通式NRR'aR“bYc的至少一种催化剂，其中aa）R，R'和/或R” 是-C 1 -C 12烷基，-C 1 -C 12芳基，-C 1 -C 12芳烷基，-C 1 -C 12氨基烷基，-C 1 -C 12氨基芳基，-C 1 -C 12氨基烷基和/或两个或三个基团R，R'和R “（如果c = 0）一起形成包括N的环状或双环，杂脂族或杂芳族体系，条件是至少一个基团R，R'或R”不等于-CH 3和/或其中bb）R和R' 和/或R“'（如果c = 1）是-C 1 -C 12亚烷基，-C 1 -C 12亚芳基，-C 1 -C 12亚芳基，-C 1 -C 12杂亚烷基，-C 1 -C 12亚杂芳基，-C 1 -C 12杂亚烷基和/ 或-N =或cc）（如果a = b = c = 0）R≡≡CR'“（其中R'”= C 1 -C 10烷基，-C 1 -C 10芳基和/或-C 1 -C 10芳烷基），同时形成包含通式SimX2m + 2（具有m> n和X = F，Cl，Br和/或I）的至少一种卤代硅烷和SiX 4（具有X = F，Cl，Br和 /或I），和b）在形成通式SimH 2 m + 2的氢硅烷的同时使通式SimH 2 m + 2的至少一种卤代硅烷氢化。 本发明还涉及根据所述方法可生产的氢硅石及其用途

    REMOVAL OF EXTRANEOUS METALS FROM SILICON COMPOUNDS BY ADSORPTION AND/OR FILTRATION
    30.
    发明申请
    REMOVAL OF EXTRANEOUS METALS FROM SILICON COMPOUNDS BY ADSORPTION AND/OR FILTRATION 有权
    通过吸附和/或过滤从硅化合物中去除非常金属

    公开(公告)号：US20110184205A1

    公开(公告)日：2011-07-28

    申请号：US13121702

    申请日：2009-10-13

    申请人： Hartwig Rauleder ,  Ekkehard Mueh

    发明人： Hartwig Rauleder ,  Ekkehard Mueh

    IPC分类号： C07F7/02

    CPC分类号： C07F7/20

    摘要： The invention relates to a process for treating a composition containing silicon compounds, especially organosilanes and/or inorganic silanes, and at least one extraneous metal and/or a compound containing extraneous metal, wherein the composition is contacted with at least one adsorbent and/or a first filter and then a composition in which the content of the extraneous metal and/or of the compound containing extraneous metal has been reduced is obtained. The invention further relates to the use of organic resins, activated carbon, silicates and/or zeolites and/or else of at least one filter with small pore sizes to reduce the level of the compounds mentioned.

    摘要翻译： 本发明涉及一种处理包含硅化合物，特别是有机硅烷和/或无机硅烷的组合物和至少一种外来金属和/或含有外来金属的化合物的方法，其中所述组合物与至少一种吸附剂和/或 然后获得第一过滤器，然后获得其中外来金属和/或含有外来金属的化合物的含量已经被还原的组合物。 本发明还涉及使用有机树脂，活性炭，硅酸盐和/或沸石和/或至少一种具有小孔径的过滤器以降低所述化合物的含量。