公开(公告)号：US5068382A

公开(公告)日：1991-11-26

申请号：US491775

申请日：1990-03-12

申请人： Hartwig Rauleder ,  Hans-Joachim Kotzch

发明人： Hartwig Rauleder ,  Hans-Joachim Kotzch

IPC分类号： C07F7/18

CPC分类号： C07F7/188 ,  C07F7/182

摘要： Organosilicon compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently straight or branched alkyl of 1 to 4 carbon atoms or --OR.sup.3,R.sup.3 is R.sup.4 --(OR.sup.5).sub.m --,R.sup.6 is straight or branched alkyl of 1 to 4 carbon atoms,m is an integer from 0 to 6, inclusive,R.sup.5 is straight or branched alkylene of 2 to 4 carbon atoms, which may be identical or different when m is an integer from 2 to 6, andR.sup.6 is straight or branched alkylene of 2 to 6 carbon atoms,are prepared by reacting hydrogensilanes of the formula ##STR2## wherein R.sup.7 are identical or different groups R.sup.4 or the group OR.sup.4, and R.sup.4 has the previously indicated meaning,with terminally unsaturated ethers of the formulaR.sup.4 --(OR.sup.5).sub.m --OR.sup.8whereinm, R.sup.4 and R.sup.5 have the previously indicated meanings, andR.sup.8 is terminally unsaturated straight or branched alkenyl or 2 to 6 carbon atoms,in the presence of a catalyst at controlled temperatures to form addition products of the formula ##STR3## wherein m and R.sup.4, R.sup.5, R.sup.6 and R.sup.7 have the previously indicated meanings, and the R.sup.4 's are identical or differentwhich are converted into the desired end products by thermal and/or catalytic transesterification with monofunctional hydroxy compounds of the formulaR.sup.4 --(OR.sup.5).sub.m OHwhereinm, R.sup.4 and R.sup.5 have the previously indicated meanings.

摘要翻译： 其中R 1和R 2各自独立地为具有1至4个碳原子的直链或支链烷基或-OR 3，R 3为R 4 - （OR 5）m - ，R 6为具有1至4个碳原子的直链或支链烷基的有机硅化合物 原子，m为0〜6的整数，包括0和6的整数，R 5为2〜4个碳原子的直链或支链亚烷基，当m为2〜6的整数时，可以相同或不同，R6为直链或支链的亚烷基 2至6个碳原子的化合物通过使下式的化合物：其中R 7为相同或不同的基团R 4或基团OR 4，且R 4具有前述含义的氢化山西与式R4-（OR5）的末端不饱和醚反应制备， m-OR 8，其中m，R 4和R 5具有前述含义，并且R 8是在受控温度下在催化剂存在下的末端不饱和的直链或支链烯基或2-6个碳原子，以形成下式的加成产物： 其中m和R4，R5，R6和R7具有之前的 并且R4相同或不同，其通过用式R 4 - （OR 5）m OH的单官能羟基化合物的热和/或催化酯交换转化为所需的最终产物，其中m，R 4和R 5具有前面所述的含义。

公开(公告)号：US09908781B2

公开(公告)日：2018-03-06

申请号：US13383681

申请日：2010-05-18

申请人： Ekkehard Mueh ,  Hartwig Rauleder ,  Jaroslaw Monkiewicz ,  Reinhold Schork

发明人： Ekkehard Mueh ,  Hartwig Rauleder ,  Jaroslaw Monkiewicz ,  Reinhold Schork

IPC分类号： C01B33/107

CPC分类号： C01B33/107 ,  C01B33/10773 ,  C01B33/10784 ,  C01P2006/80

摘要： The invention relates to a process for dismutating at least one halosilane and reducing the content of extraneous metal and/or a compound containing extraneous metal in the at least one halosilane and in the at least one silane obtained, by contacting at least one halosilane of the general formula I, HnSiClm (I), where n and m are integers and n=1, 2 or 3 and m=1, 2 or 3 and n+m=4, with a particulate, organic, amino-functional resin to obtain at least one silane of the general formula II, HaSiClb (II), where a and b are integers and a=0, 2, 3 or 4 and b=0, 1, 2 or 4 where a+b=4, in one step, in which the content of extraneous metal and/or compounds containing extraneous metal has been reduced compared to the halosilane of the formula I. The invention further provides for the use of this resin for dismutating halosilanes and as an absorbent of extraneous metals or compounds containing extraneous metal in a process for preparing monosilane.

公开(公告)号：US09618466B2

公开(公告)日：2017-04-11

申请号：US13580843

申请日：2010-12-28

申请人： Ekkehard Mueh ,  Hartwig Rauleder ,  Rainer Amend ,  Martin Hajduk

发明人： Ekkehard Mueh ,  Hartwig Rauleder ,  Rainer Amend ,  Martin Hajduk

IPC分类号： C23C16/00 ,  G01N27/04 ,  G01N33/00

CPC分类号： G01N27/04 ,  G01N2033/0095

摘要： The invention relates to a method for indirectly determining the purity of silanes and germanes using a device for measuring specific resistance. The invention further relates to a system for industrially producing and/or filling containers with silanes or germanes, including a quality control in which a device is used for measuring specific resistance.

公开(公告)号：US09593021B2

公开(公告)日：2017-03-14

申请号：US14649353

申请日：2013-11-21

申请人： Janaina Marinas Perez ,  Ekkehard Mueh ,  Hartwig Rauleder ,  Frank Kropfgans

发明人： Janaina Marinas Perez ,  Ekkehard Mueh ,  Hartwig Rauleder ,  Frank Kropfgans

IPC分类号： C01B33/107 ,  C01B33/00 ,  C08K11/00

CPC分类号： C01B33/00 ,  C01B33/107 ,  C01B33/10742 ,  C08K11/005

摘要： The invention provides a method for the processing of finely divided solids during the production of chlorosilanes, which is characterized in that the finely divided solids are hydraulically pressed to give bodies of increased density. Moreover, also provided is the compact obtained by the process according to the invention which is characterized by a filling factor of the finely divided solids to be hydraulically pressed of 3.9 to 4.5.

摘要翻译： 本发明提供了在制备氯代硅烷期间处理细碎固体的方法，其特征在于将细碎的固体液压地挤压以提供增加密度的体。 此外，还提供了通过根据本发明的方法获得的压块，其特征在于待液压压制的细碎固体的填充因子为3.9至4.5。

公开(公告)号：US09481580B2

公开(公告)日：2016-11-01

申请号：US13884473

申请日：2011-10-24

申请人： Ekkehard Mueh ,  Hartwig Rauleder

发明人： Ekkehard Mueh ,  Hartwig Rauleder

IPC分类号： C01B33/107 ,  C01B33/04 ,  C01B33/08 ,  B01J37/06 ,  B01J21/08 ,  B01J37/02

CPC分类号： C01B33/10742 ,  B01J21/08 ,  B01J37/0215 ,  B01J37/06 ,  C01B33/043 ,  C01B33/08 ,  C01B33/107 ,  C01B33/1071 ,  C01B33/10773

摘要： The invention relates to a process for preparing monomeric and/or dimeric halogen- and/or hydrogen-containing silicon compounds from oligomeric inorganic silanes having three or more directly covalently interconnected silicon atoms substituted by substituents selected from halogen, hydrogen and/or oxygen by reacting the oligomeric silane over a nitrogen-containing catalyst in the presence of hydrogen halide.

摘要翻译： 本发明涉及一种由低聚无机硅烷制备单体和/或二聚的卤素和/或含氢硅化合物的方法，其具有三个或更多个直接共价连接的硅原子，其被选自卤素，氢和/或氧的取代基取代， 在卤化氢存在下，在含氮催化剂上的低聚硅烷。

公开(公告)号：US20150102070A1

公开(公告)日：2015-04-16

申请号：US14383757

申请日：2013-02-11

申请人： Ekkehard Mueh ,  Hartwig Rauleder ,  Bernd Nowitzki ,  Harald Klein

发明人： Ekkehard Mueh ,  Hartwig Rauleder ,  Bernd Nowitzki ,  Harald Klein

IPC分类号： B67D7/02 ,  B65B3/00 ,  B67D7/84

CPC分类号： B67D7/0294 ,  B65B3/00 ,  B67D7/025 ,  B67D7/0261 ,  B67D7/0272 ,  B67D7/0283 ,  B67D7/84

摘要： The invention relates to an empty container (1) for accommodating high-purity and ultra-high-purity, air- and/or moisture-sensitive liquid or condensable compounds, comprising a cylindrical jacket (3), a bottom (4a) and an upper end piece (4b, 4b′) at the two ends of the cylindrical jacket, an associated connection unit (2) including shut-off/multiple-way and rinsing system (5), and an associated immersion pipe (7), characterized in that the lower end of the immersion pipe (7a) protrudes into a recess (4c) (depression), which is introduced in the bottom (4a) and which is the lowest point of the bottom, and/or the lower end of the immersion pipe (7a) is tapered and is brought close to the lowest point of the bottom (4a) to within less than 2 mm by means of the tip of the tapered immersion pipe (7b) or touches the lowest point of the bottom with the tip of the tapered immersion pipe (7b). The invention further relates to the use of empty containers according to the invention for storing, handling, and/or transporting such high-purity and ultra-high-purity compounds.

摘要翻译： 本发明涉及一种用于容纳高纯度和超高纯度空气和/或湿度敏感性液体或可冷凝化合物的空容器（1），其包括圆柱形护套（3），底部（4a）和 包括关闭/多路和冲洗系统（5）的关联连接单元（2）和相关联的浸入式管道（7），其特征在于，所述圆柱形套管两端的上端件（4b，4b'） 浸入管（7a）的下端突出到凹入部（4c）（凹陷部）（凹部），该凹部被引入到底部（4a）中，并且是底部的最低点，和/ 浸入管（7a）是锥形的，并且通过锥形浸入管（7b）的尖端使其靠近底部（4a）的最低点到小于2mm内，或者接触底部的最低点 锥形浸入管（7b）的尖端。 本发明还涉及根据本发明的用于储存，处理和/或运输这种高纯度和超高纯度化合物的空容器的用途。

公开(公告)号：US08722913B2

公开(公告)日：2014-05-13

申请号：US12524371

申请日：2007-12-20

申请人： Juergen Erwin Lang ,  Hartwig Rauleder ,  Ekkehard Mueh

发明人： Juergen Erwin Lang ,  Hartwig Rauleder ,  Ekkehard Mueh

IPC分类号： C07F7/12

CPC分类号： B01J19/088 ,  B01J2219/0803 ,  B01J2219/0894 ,  C01B21/068 ,  C01B21/0823 ,  C01B32/907 ,  C01B33/04 ,  C01B33/107 ,  C01B33/12 ,  C01B33/36 ,  C01G17/00 ,  C01P2002/86 ,  C07F7/083 ,  C07F7/30

摘要： The invention relates to a method for producing dimeric and/or trimeric silicon compounds, in particular silicon halogen compounds. The claimed method is also suitable for producing corresponding germanium compounds. The invention also relates to a device for carrying out said method to the use of the produced silicon compounds.

摘要翻译： 本发明涉及二聚和/或三聚硅化合物，特别是硅卤素化合物的制备方法。 所要求保护的方法也适用于生产相应的锗化合物。 本发明还涉及用于实施所述方法来使用所生产的硅化合物的装置。

公开(公告)号：US20140072803A1

公开(公告)日：2014-03-13

申请号：US14000954

申请日：2012-02-10

申请人： Christian Panz ,  Guido Titz ,  Sven Müller ,  Markus Ruf ,  Bodo Frings ,  Hartwig Rauleder ,  Jürgen Behnisch

发明人： Christian Panz ,  Guido Titz ,  Sven Müller ,  Markus Ruf ,  Bodo Frings ,  Hartwig Rauleder ,  Jürgen Behnisch

IPC分类号： C01B33/12 ,  C03C14/00

CPC分类号： C01B33/193 ,  C01B33/124 ,  C01B33/126 ,  C01B33/128 ,  C01P2004/60 ,  C01P2006/14 ,  C01P2006/17 ,  C01P2006/80 ,  C03B19/1065 ,  C03B19/1095 ,  C03C1/022 ,  C03C14/008 ,  Y10T428/2982

摘要： It has been found that conventional cheap waterglass qualities in a strongly acidic medium react to give high-purity silica grades, the treatment of which with a base leads to products which can be processed further to give glass bodies with low silanol group contents.

摘要翻译： 已经发现，在强酸性介质中常规的廉价水玻璃质量反应以得到高纯度二氧化硅等级，用碱处理可以进一步处理可以进一步提供具有低硅烷醇基含量的玻璃体的产品。

公开(公告)号：US08221593B2

公开(公告)日：2012-07-17

申请号：US12065126

申请日：2006-06-06

申请人： Juergen Erwin Lang ,  Rainer Nicolai ,  Hartwig Rauleder

发明人： Juergen Erwin Lang ,  Rainer Nicolai ,  Hartwig Rauleder

IPC分类号： H05F3/04

CPC分类号： C01B33/10778 ,  B01J19/0093 ,  B01J19/088 ,  B01J2219/0002 ,  B01J2219/00033 ,  B01J2219/00788 ,  B01J2219/00822 ,  B01J2219/00853 ,  B01J2219/00867 ,  B01J2219/00869 ,  B01J2219/00871 ,  B01J2219/00873 ,  B01J2219/0093 ,  B01J2219/0807 ,  B01J2219/0828 ,  B01J2219/083 ,  B01J2219/0841 ,  B01J2219/0871 ,  B01J2219/0875 ,  B01J2219/0896 ,  C01G17/04 ,  C01P2006/80

摘要： A reactor, a plant, and a continuous, industrial process carried out therein for preparing high-purity silicon tetrachloride or high-purity germanium tetrachloride by treating the silicon tetrachloride or germanium tetrachloride to be purified, which is contaminated by at least one hydrogen-containing compound, by a cold plasma and isolating purified high-purity silicon tetrachloride or germanium tetrachloride from the resulting treated phase by fractional distillation. The treatment is carried out in a plasma reactor in which longitudinal axes of a dielectric, of a high-voltage electrode, and of a grounded, metallic heat exchanger are oriented parallel to one another and at the same time parallel to the force vector of gravity.

摘要翻译： 在其中进行的反应器，工厂和连续的工业方法，用于通过处理待纯化的四氯化硅或四氯化锗来制备高纯度四氯化硅或高纯度四氯化锗，其被至少一种含氢的 化合物，通过冷等离子体，并通过分馏从所得处理相中分离纯化的高纯度四氯化硅或四氯化锗。 处理在等离子体反应器中进行，其中电介质的高压电极和接地的金属热交换器的纵向轴线彼此平行取向并且同时平行于重力的力矢量 。

公开(公告)号：US20110262339A1

公开(公告)日：2011-10-27

申请号：US13121759

申请日：2009-09-28

申请人： Hartwig Rauleder ,  Ekkehard Müh ,  Mustafa Siray ,  Peter Nagler ,  Bodo Frings ,  Ingrid Lunt-Rieg ,  Alfons Karl ,  Christian Panz ,  Thomas Groth ,  Guido Stochniol ,  Matthias Rochnia ,  Jürgen Erwin Lang ,  Oliver Wolf ,  Rudolf Schmitz ,  Bernd Nowitzki ,  Dietmar Wewers

发明人： Hartwig Rauleder ,  Ekkehard Müh ,  Mustafa Siray ,  Peter Nagler ,  Bodo Frings ,  Ingrid Lunt-Rieg ,  Alfons Karl ,  Christian Panz ,  Thomas Groth ,  Guido Stochniol ,  Matthias Rochnia ,  Jürgen Erwin Lang ,  Oliver Wolf ,  Rudolf Schmitz ,  Bernd Nowitzki ,  Dietmar Wewers

IPC分类号： C01B33/025

CPC分类号： C01B33/025 ,  C01B32/05 ,  C01B33/148

摘要： The invention relates to a complete method for producing pure silicon that is suitable for use as solar-grade silicon, comprising the reduction of a purified silicon oxide using one or more pure carbon sources, the purified silicon oxide, which was purified as silicon oxide dissolved in an aqueous phase, having a content of other polyvalent metals or metal oxides, in relation to the silicon oxide, of less than or equal to 300 ppm, preferably less than 100 ppm, especially preferably less than 50 ppm and according to the invention less than 10 ppm of the other metals and being obtained advantageously by gel formation in alkaline conditions. The invention also relates to a formulation containing an activator and to the use of purified silicon oxide together with an activator for producing silicon.

摘要翻译： 本发明涉及一种适用于太阳能级硅的纯硅生产的完整方法，其中包括使用一种或多种纯碳源还原纯化的氧化硅，纯化的氧化硅被溶解为氧化硅 在水相中，具有相对于氧化硅的其它多价金属或金属氧化物的含量小于或等于300ppm，优选小于100ppm，特别优选小于50ppm，并且根据本发明，较少 超过10ppm的其他金属，并且有利地通过在碱性条件下的凝胶形成获得。 本发明还涉及含有活化剂的配方和使用纯化的氧化硅以及用于生产硅的活化剂。