Addition polymerizable aromatic sulfonium salts and polymers thereof
    22.
    发明授权
    Addition polymerizable aromatic sulfonium salts and polymers thereof 失效
    加成可聚合芳族锍盐及其聚合物

    公开(公告)号:US4477640A

    公开(公告)日:1984-10-16

    申请号:US422775

    申请日:1982-09-24

    CPC分类号: C08F2/28 C08F12/32

    摘要: Novel polymers having high activity as cationic surface-active agents are prepared by the addition polymerization of ethylenically unsaturated aromatic sulfonium salts, e.g., ##STR1## When such polymers are heated and/or dried, they are irreversibly converted to inert, nonionic residues without the elimination of odorous by-products. The novel sulfonium salt polymers having relatively low molecular weight and low charge density are particularly useful as surfactants or emulsifiers in the emulsion polymerization of ethylenically unsaturated monomers such as styrene, butadiene, alkyl acrylates and the like. The polymers having high molecular weight and high charge density are useful as thickeners and flocculants.

    摘要翻译: 通过烯键式不饱和芳族锍盐的加成聚合制备具有高活性的阳离子表面活性剂的新型聚合物,例如,当加热和/或干燥这些聚合物时,它们不可逆地转化为惰性的非离子残余物, 消除恶臭副产品。 具有相对低分子量和低电荷密度的新型锍盐聚合物在烯属不饱和单体如苯乙烯,丁二烯,丙烯酸烷基酯等的乳液聚合中特别可用作表面活性剂或乳化剂。 具有高分子量和高电荷密度的聚合物可用作增稠剂和絮凝剂。

    Quick-set film-forming compositions
    26.
    发明授权
    Quick-set film-forming compositions 有权
    快速成膜组合物

    公开(公告)号:US06359110B1

    公开(公告)日:2002-03-19

    申请号:US09596772

    申请日:2000-06-19

    IPC分类号: C08G610

    CPC分类号: C08J3/07 C09D201/02

    摘要: The present invention relates to a quick set composition and a method for preparing the composition. The composition comprises an aqueous sol of a polymer having a backbone that contains pendant cationic groups and pendant acid groups. The sol is prepared by forming a solution of a polymer that contains pendant cationic groups and pendant acid groups in an aqueous-based solvent that contains water and a suitable organic solvent and removing a sufficient amount of the organic solvent from the solution to form a composition characterized by being reversibly dissolvable and reconstitutable by addition and removal of a suitable organic solvent. The composition of the present invention provides quick-set films that can be prepared in the absence additional surface active agents and with a substantial absence of organic solvents.

    摘要翻译: 本发明涉及快速固化组合物及其制备方法。 组合物包含具有主链的聚合物的水性溶胶,所述主链含有阳离子侧基和侧基酸基。 通过在含有水和合适的有机溶剂的水性溶剂中形成含有阳离子侧基和侧基的基团的聚合物溶液来制备溶胶,并从溶液中除去足够量的有机溶剂以形成组合物 其特征在于通过添加和除去合适的有机溶剂是可逆地溶解和重新构成的。 本发明的组合物提供可在不存在另外的表面活性剂和基本上不存在有机溶剂的情况下制备的快速凝固膜。

    Quick-set film-forming compositions
    27.
    发明授权
    Quick-set film-forming compositions 有权
    快速成膜组合物

    公开(公告)号:US06191211B1

    公开(公告)日:2001-02-20

    申请号:US09151933

    申请日:1998-09-11

    IPC分类号: C08L3900

    CPC分类号: C08J3/07 C09D201/02

    摘要: The present invention relates to a quick set composition and a method for preparing the composition. The composition comprises an aqueous sol of a polymer having a backbone that contains pendant cationic groups and pendant acid groups. The sol is prepared by forming a solution of a polymer that contains pendant cationic groups and pendant acid groups in an aqueous-based solvent that contains water and a suitable organic solvent and removing a sufficient amount of the organic solvent from the solution to form a composition characterized by being reversibly dissolvable and reconstitutable by addition and removal of a suitable organic solvent. The composition of the present invention provides quick-set films that can be prepared in the absence additional surface active agents and with a substantial absence of organic solvents.

    摘要翻译: 本发明涉及快速固化组合物及其制备方法。 组合物包含具有主链的聚合物的水性溶胶,所述主链含有阳离子侧基和侧基酸基。 通过在含有水和合适的有机溶剂的水性溶剂中形成含有阳离子侧基和侧基的基团的聚合物溶液来制备溶胶,并从溶液中除去足够量的有机溶剂以形成组合物 其特征在于通过添加和除去合适的有机溶剂是可逆地溶解和重新构成的。 本发明的组合物提供可在不存在另外的表面活性剂和基本上不存在有机溶剂的情况下制备的快速凝固膜。