-
公开(公告)号:US4526704A
公开(公告)日:1985-07-02
申请号:US512846
申请日:1983-07-11
申请人: Martin Petrzilka , Martin Schadt , Alois Villiger
发明人: Martin Petrzilka , Martin Schadt , Alois Villiger
CPC分类号: C09K19/2007 , C09K19/3068 , C09K19/44
摘要: Compounds of the formula ##STR1## wherein n is 0 or 1; one of X.sup.1 and X.sup.2 is --COO-- or --OOC-- and the other is a single covalent bond or --CH.sub.2 CH.sub.2 --; X.sup.3 and X.sup.4 individually are a single covalent bond or --CH.sub.2 CH.sub.2 --, with the proviso that at most one of X.sup.1, X.sup.2, X.sup.3 and X.sup.4 is --CH.sub.2 CH.sub.2 --; rings A.sup.1 and A.sup.5 individually are a group of the formula ##STR2## or trans-1,4-cyclohexylene; rings A.sup.2, A.sup.3 and A.sup.4 individually are a group of formula II or, when ring A.sup.2, A.sup.3 or A.sup.4 is not linked with at least one of the other two of these rings by a single covalent bond then such ring also can be trans-1,4-cyclohexylene, with the proviso that at least one of rings A.sup.1 through A.sup.5 is a group of formula II; Y is hydrogen, or when Y is attached to a ring of formula II which is not linked with another ring via a single covalent bond, Y also can be fluorine, chlorine or methyl; and R.sup.1 and R.sup.2 individually are straight-chain alkyl of 1-7 carbon atoms, or when R.sup.1 or R.sup.2 is attached to a ring of formula II such R.sup.1 or R.sup.2 also can be straight-chain alkoxy of 1 to 7 carbon atoms;their manufacture and use for electro-optical and chromatographical purposes and liquid crystalline mixtures containing these compounds are described.
摘要翻译: 式(Ⅰ)化合物其中n为0或1; X1和X2之一是-COO-或-OOC-,另一个是单个共价键或-CH 2 CH 2 - ; X 3和X 4分别是单个共价键或-CH 2 CH 2 - ,条件是X 1,X 2,X 3和X 4中至多一个是-CH 2 CH 2 - ; 环A1和A5分别是式II或反式-1,4-亚环己基的基团; 环A2,A3和A4分别是式II的基团,或者当环A2,A3或A4不与单个共价键中的至少一个这些环中的至少一个连接时,该环也可以是反式-1 ,4-环己烯基,条件是环A1至A5中的至少一个是式II的基团; Y是氢,或当Y连接到通过单个共价键不与另一个环连接的式II的环时,Y也可以是氟,氯或甲基; R1和R2分别为1-7个碳原子的直链烷基,或当R1或R2连接到式II的环上时,R 1或R 2也可以是1至7个碳原子的直链烷氧基; 描述了其用于电光学和色谱目的的制造和用途以及含有这些化合物的液晶混合物。
-
公开(公告)号:US4432885A
公开(公告)日:1984-02-21
申请号:US328979
申请日:1981-12-09
申请人: Martin Petrzilka , Kuno Schleich
发明人: Martin Petrzilka , Kuno Schleich
IPC分类号: C07C1/22 , C07C1/32 , C07C13/28 , C07C13/50 , C07C17/12 , C07C25/02 , C07C25/22 , C07C29/14 , C07C29/143 , C07C29/19 , C07C37/055 , C07C43/115 , C07C43/172 , C07C43/18 , C07C43/21 , C07C45/29 , C07C45/44 , C07C45/46 , C07C45/51 , C07C45/62 , C07C45/68 , C07C49/313 , C07C49/317 , C07C49/792 , C07C63/00 , C07C63/49 , C07C69/157 , C07C69/24 , C07C69/75 , C07C69/76 , C07C255/45 , C07C255/49 , C07C255/50 , C09K19/00 , C09K19/32 , C07C13/47 , C07C49/30 , C07C103/22 , C07C121/64 , C09K3/34
CPC分类号: C07C17/12 , C07C1/22 , C07C1/322 , C07C13/50 , C07C25/22 , C07C255/00 , C07C29/14 , C07C29/143 , C07C29/19 , C07C37/0555 , C07C43/18 , C07C43/21 , C07C45/292 , C07C45/44 , C07C45/46 , C07C45/513 , C07C45/62 , C07C45/68 , C07C49/313 , C07C49/792 , C07C63/49 , C09K19/322 , C07B2200/07 , C07C2101/14 , C07C2102/28 , C09K2019/326
摘要: Decalins of the formula ##STR1## wherein ring A is aromatic or a trans-1,4-disubstituted cyclohexane ring; R.sup.2 is methyl, --CH.sub.2 R', --OR', --CO--R', --CN, --COOH, --CO--OR', --CO--SR' or --O--CO--R'; R.sup.1 is hydrogen, methyl, --CH.sub.2 R, --OR or --CH.sub.2 OR, or when R.sup.2 is methyl, --CH.sub.2 R', --OR' or --CO--R', R.sup.1 also can be --CN, --COOH, --CO--OR, --CO--SR or --O--CO--R; R and R' each are alkyl; and R.sup.1 and R.sup.2 each have up to 12 carbon atoms and together have at most 14 carbon atoms,their racemates and optically active antipodes, are described. Liquid crystalline mixtures comprising Compound I as well as their use in electro-optical devices also are disclosed.
摘要翻译: 其中环A是芳族或反式-1,4-二取代的环己烷环; R 2是甲基,-CH 2 R',-OR',-CO-R',-CN,-COOH,-CO-OR',-CO-SR'或-O-CO-R' R1是氢,甲基,-CH2R,-OR或-CH2OR,或当R2是甲基时,-CH2R',-OR'或-CO-R',R1也可以是-CN,-COOH,-CO-OR, -CO-SR或-O-CO-R; R和R'各自为烷基; 并且R1和R2各自具有至多12个碳原子并且共有至多14个碳原子,它们的外消旋体和光学活性对映体。 还公开了包含化合物I的液晶混合物以及它们在电光器件中的用途。
-
公开(公告)号:US5635471A
公开(公告)日:1997-06-03
申请号:US398726
申请日:1995-03-06
申请人: Georg Frater , Urs Muller , Martin Petrzilka
发明人: Georg Frater , Urs Muller , Martin Petrzilka
IPC分类号: C07D311/78 , A61K8/49 , A61Q13/00 , C07C33/34 , C07D311/94 , C11B9/00 , A61K7/46
CPC分类号: C07D311/94 , C07C33/34 , C11B9/008 , C07C2102/08
摘要: The invention is concerned with the 7R/7S-diastereoisomer mixture of the formula ##STR1## in pure form, essentially free of the corresponding (4R)-isomers. The invention also concerns the 2R/2S-diastereoisomer mixture of the formula ##STR2## in pure form which is useful as an intermediate for producing I. In addition, the invention concerns a process for obtaining I by subjecting II to isochromane ring closure. Odorant compositions containing I and the use of I as an odorant are also described.
摘要翻译: 本发明涉及纯的形式的基本上不含相应的(4R) - 异构体的式I的7R / 7S-非对映异构体混合物。 本发明还涉及纯形式的2R / 2S-非对映异构体混合物,其可用作生产I的中间体。此外,本发明涉及通过使II进行异苯并二氢吡喃环闭合来获得I的方法。 还描述了含有I的气味组合物和I作为气味剂的用途。
-
公开(公告)号:US4621901A
公开(公告)日:1986-11-11
申请号:US749163
申请日:1985-06-26
申请人: Martin Petrzilka , Martin Schadt
发明人: Martin Petrzilka , Martin Schadt
IPC分类号: C07C1/00 , C07C2/86 , C07C13/28 , C07C15/12 , C07C17/00 , C07C17/26 , C07C25/18 , C07C41/00 , C07C43/184 , C07C43/205 , C07C67/00 , C07C69/74 , C07C69/76 , C07C253/00 , C07C255/46 , C07C255/50 , C07C255/55 , C07C255/57 , C07C325/00 , C07C331/26 , C07C331/28 , C07D239/34 , C07D319/06 , C08L25/18 , C09K19/12 , C09K19/14 , C09K19/20 , C09K19/30 , C09K19/34 , C09K19/42 , C09K19/46 , G02F1/13 , G09F9/35 , C09K3/34
CPC分类号: C07C255/00 , C07C13/28 , C07C331/28 , C09K19/12 , C09K19/14 , C09K19/2007 , C09K19/3001 , C09K19/3402 , C09K19/3469 , C09K19/42 , C09K2019/3422
摘要: Liquid crystalline mixtures containing compounds of the formula ##STR1## wherein n stands for the number 0 or 1; X.sup.1 and X.sup.2 denote single covalent bonds or one of the symbols X.sup.1 and X.sup.2 also denotes --COO--, --OOC-- or --CH.sub.2 CH.sub.2 --; the rings A.sup.1, A.sup.2, and A.sup.3 represent 1,4-phenylene, 2-fluoro-1,4-phenylene or trans-1,4-cyclohexylene or one of these rings also represents a 2,5-disubstituted pyrimidine ring or a trans-2,5-disubstituted m-dioxane ring; R.sup.1 signifies 4-alkenyl or on a cyclohexyl ring also 2Z-alkenyl; and R.sup.2 denotes alkyl, alkoxy, --CN or --NCS,as well as the manufacture of these compounds and the use for electro-optical purposes are described.
摘要翻译: 含有下式化合物的液晶混合物其中n代表数字0或1; X1和X2表示单个共价键,或者X1和X2之一也表示-COO-,-OOC-或-CH2CH2-; 环A1,A2和A3表示1,4-亚苯基,2-氟-1,4-亚苯基或反式-1,4-亚环己基,或这些环中的一个也表示2,5-二取代的嘧啶环或反式 -2,5-二取代的m-二恶烷环; R1表示4-链烯基或环己基环,也表示2Z-烯基; 并且R2表示烷基,烷氧基,-CN或-NCS,以及这些化合物的制造和电光目的的用途。
-
25.
公开(公告)号:US4595521A
公开(公告)日:1986-06-17
申请号:US551655
申请日:1983-11-14
申请人: Martin Petrzilka , Georg Trickes
发明人: Martin Petrzilka , Georg Trickes
IPC分类号: C07D237/08 , C07D237/12 , C07D237/14 , C09K19/34 , C07D237/02 , G02F1/13
CPC分类号: C07D237/08 , C07D237/12 , C07D237/14 , C09K19/3455
摘要: Compounds of the formula ##STR1## wherein B is --C.tbd.C-- or --CH.sub.2 CH.sub.2 --, R.sup.1 is straight-chain C.sub.1 -C.sub.12 -alkyl and R.sup.2 is straight-chain C.sub.1 -C.sub.12 -alkyl or straight-chain C.sub.1 -C.sub.12 -alkoxy, their manufacture and use in liquid crystalline mixtures are described.
摘要翻译: 式Ⅰ的化合物,其中B是-C 3或C 2 -C 2-,R 1是直链C 1 -C 12 - 烷基,R 2是直链C 1 -C 12 - 烷基或直链C 1 -C 12 - 描述了它们在液晶混合物中的制备和用途。
-
公开(公告)号:US4565425A
公开(公告)日:1986-01-21
申请号:US586487
申请日:1984-03-05
申请人: Martin Petrzilka , Martin Schadt
发明人: Martin Petrzilka , Martin Schadt
IPC分类号: C07C13/28 , C07C43/162 , C07C43/215 , C07C45/00 , C07C45/29 , C07C45/59 , C07C49/687 , C07C49/798 , C07C61/35 , C07D239/26 , C07D303/04 , C07D303/14 , C07D303/16 , C07D303/22 , C07D303/46 , C07D317/72 , C07D319/06 , C09K19/14 , C09K19/20 , C09K19/30 , C09K19/34 , G02F1/13
CPC分类号: C07D303/22 , C07C13/28 , C07C255/00 , C07C403/02 , C07C43/162 , C07C43/215 , C07C45/004 , C07C45/292 , C07C45/59 , C07C49/687 , C07C49/798 , C07C61/35 , C07D303/04 , C07D303/14 , C07D303/16 , C07D303/46 , C07D317/72 , C07D319/06 , C09K19/14 , C09K19/2007 , C09K19/3001 , C09K19/3402 , C09K19/3441 , C07C2101/14 , C09K2019/3422
摘要: Compounds of the formula ##STR1## wherein R.sup.1 is hydrogen or straight-chain alkyl; R.sup.2 is --CN, --R, --COR, --COOR or when R.sup.2 is positioned on an aromatic ring R.sup.2 also can be --OR, --OOCR or --F; R is alkyl; A is a group with 1 to 4 six-membered rings, these rings being linked directly with one another and with ring B in each case via a single covalent bond or being linked at one or two positions also via --COO--, --OOC-- or --CH.sub.2 CH.sub.2 --; the six-membered rings in A and ring B each are 1,4-phenylene or trans-1,4-cyclohexylene or one of these rings also is trans-2,5-disubstituted m-dioxane, 2,5-disubstituted pyrimidine or 3,6-disubstituted pyridazine, with the proviso that a maximum of two adjacent trans-1,4-cyclohexylene rings are linked directly via a single covalent bond; and m is the integer 2, or when ring B is trans-1,4-cyclohexylene or trans-2,5-disubstituted m-dioxane, m also can be the integer 0,their manufacture, liquid crystalline mixtures which contain these compounds as well as the use of these compounds for electro-optical purposes are described.Additionally, compounds of the formula ##STR2## wherein R.sup.8 is straight-chain C.sub.1 -C.sub.12 alkyl, their manufacture, liquid crystalline mixtures which contain these compounds and their use for electro-optical purposes are described.
-
公开(公告)号:US4559147A
公开(公告)日:1985-12-17
申请号:US556677
申请日:1983-11-30
申请人: Georges Hirth , Martin Petrzilka , Inge Pracht
发明人: Georges Hirth , Martin Petrzilka , Inge Pracht
CPC分类号: G02B1/06
摘要: There are described an immersion oil containing one or more compounds of the formula ##STR1## wherein R is hydrogen or methyl, and its use in optics, especially fluorescence microscopy.
摘要翻译: 描述了含有一种或多种式(I)的化合物的浸油,其中R是氢或甲基,并且其用于光学,特别是荧光显微镜。
-
公开(公告)号:US4493533A
公开(公告)日:1985-01-15
申请号:US370120
申请日:1982-04-20
申请人: Martin Petrzilka , Inge Pracht , Urs Ruf
发明人: Martin Petrzilka , Inge Pracht , Urs Ruf
IPC分类号: C10M135/24 , G02B1/04 , G02B1/06 , G02B21/00 , C07C149/18 , C10M3/32
CPC分类号: C07C323/00
摘要: Immersion oils containing aliphatic thio compounds are described. The oils have optical properties and are useful in immersion optics such as fluorescence microscopy.
摘要翻译: 描述含有脂族硫代化合物的浸油。 这些油具有光学性质,并且可用于诸如荧光显微镜的浸没光学器件中。
-
公开(公告)号:US4419262A
公开(公告)日:1983-12-06
申请号:US396998
申请日:1982-07-12
申请人: Martin Petrzilka
发明人: Martin Petrzilka
IPC分类号: C07C45/00 , C07C45/65 , C07C45/73 , C07C49/303 , C07C59/205 , C07D237/08 , C07D237/12 , C07D237/14 , C07F7/08 , C09K19/34 , C09K3/34 , C07D237/02
CPC分类号: C07C255/00 , C07C45/00 , C07C45/65 , C07C45/73 , C07C49/303 , C07C59/205 , C07D237/08 , C07D237/12 , C07D237/14 , C07F7/0812 , C09K19/3455
摘要: Compounds of the formula ##STR1## wherein R.sup.1 is straight-chain alkyl of 1 to 12 carbon atoms, R.sup.2 is 1-alkynyl and the 1-alkynyl group in R.sup.2 is a straight-chain group of 1 to 10 carbon atoms, their manufacture, liquid crystalline mixtures containing said compounds as well as their use for electro-optical purposes are described. The novel compounds are valuable components for liquid crystalline mixtures and have a negative dielectric anisotropy.
摘要翻译: 式Ⅰ化合物其中R1是1-12个碳原子的直链烷基,R2是1-炔基,R2中的1-炔基是1-10个碳原子的直链基团,它们的制造方法 描述了含有所述化合物的液晶混合物及其用于电光学目的的用途。 新型化合物是液晶混合物的有价值的成分,具有负的介电各向异性。
-
公开(公告)号:US4247717A
公开(公告)日:1981-01-27
申请号:US73329
申请日:1979-09-07
申请人: Martin Petrzilka
发明人: Martin Petrzilka
IPC分类号: C07C391/02 , C07C47/228
CPC分类号: C07C391/02
摘要: New organo-selenenyl aldehyde of formula C.sub.6 H.sub.5 -Se-CH.sub.2 -CHO and method for its preparation.The new compound is a useful starting material for the preparation of allylic alcohols, epoxydes or olefines.
摘要翻译: 式C6H5-Se-CH2-CHO的新有机硒烯醛及其制备方法。 新化合物是制备烯丙基醇,环氧化物或烯烃的有用起始原料。
-
-
-
-
-
-
-
-
-