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公开(公告)号:US4785128A
公开(公告)日:1988-11-15
申请号:US474731
申请日:1983-03-18
IPC分类号: C09B57/00 , C11D3/42 , D06L3/12 , C07C121/64
CPC分类号: D06L3/125
摘要: A fluorescent brightener is proposed which consists of 51-99% of an unsymmetrically substituted compound of the formula ##STR1## in which R and R.sub.1 are identical or different and, if R and R.sub.1 are identical, R.sub.1 must occupy a position in the phenyl ring to which it is bonded which differs from the position occupied by R in its phenyl ring, and in which R and R.sub.1 independently of one another are CN or a carboxylic acid ester group, and 49-1% of a symmetrically substituted compound of the formula ##STR2## in which R is as defined above and the two R's are bonded to identical positions in their phenyl rings, as are also agents which contain these fluorescent brighteners and the use of these fluorescent brighteners for the fluorescent brightening of, in particular, textile materials, preferably made of polymer. The said fluorescent brighteners are prepared by reacting terephthalaldehyde preferably with a correspondingly substituted benzylphosphonate and further reacting the resulting mixture of a correspondingly substituted 4-stilbene aldehyde and a symmetrical p-bis-styrylbenzene with a benzylphosphonate which differs from the benzylphosphonate first used.
摘要翻译: 提出了一种荧光增白剂,其由51-99%的不对称取代的式(1)化合物组成,其中R和R 1相同或不同,并且如果R和R 1相同,则R1必须占据 与苯基环中R所占的位置不同的苯环,其中R和R 1彼此独立地为CN或羧酸酯基,和49-1%的对称取代的化合物 其中R如上定义并且两个R在其苯环中的相同位置键合,其中R是如上定义的,以及含有这些荧光增白剂的试剂和使用这些荧光增白剂进行荧光增白 特别是纺织材料,优选由聚合物制成。 所述荧光增白剂通过使对苯二甲醛优选与相应取代的苄基膦酸酯反应制备,并进一步使得到的相应取代的4-芪和对称的对双对苯乙烯基苯的混合物与首先使用的苄基膦酸盐不同的苄基膦酸酯反应。
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公开(公告)号:US4638078A
公开(公告)日:1987-01-20
申请号:US727162
申请日:1985-04-25
申请人: Robert A. Kirchhoff
发明人: Robert A. Kirchhoff
IPC分类号: C07D207/448 , C07C233/02 , C07C233/09 , C07C235/28 , C07C235/74 , C07C255/50 , C07C255/58 , C07C255/60 , C07C317/14 , C07C323/22 , C07C323/40 , C07C323/60 , C07D20060101 , C08F22/36 , C08F22/38 , C07C121/64 , C07C103/34
CPC分类号: C07C255/00
摘要: The invention is a compound which comprises an amido alkenoic acid or a water-soluble salt thereof and and arylcyclobutene moiety, wherein the cyclobutene moiety is fused to the aryl radical, and wherein the amide nitrogen is connected to the aryl radical of the arylcyclobutenyl moiety by a direct bond or a bridging member.
摘要翻译: 本发明是一种化合物,其包含酰氨基烯酸或其水溶性盐和芳基环丁烯部分,其中环丁烯部分与芳基稠合,并且其中酰胺氮通过芳基环丁烯基部分的芳基连接到芳基环丁烯基部分的芳基上 直接债券或桥接成员。
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公开(公告)号:US4510069A
公开(公告)日:1985-04-09
申请号:US526927
申请日:1983-08-26
申请人: Rudolf Eidenschink , Gunther Haas , Ludwig Pohl , Michael Romer , Bernhard Scheuble , Georg Weber
发明人: Rudolf Eidenschink , Gunther Haas , Ludwig Pohl , Michael Romer , Bernhard Scheuble , Georg Weber
IPC分类号: C07C13/28 , C07C17/08 , C07C17/18 , C07C23/18 , C07C43/184 , C07C43/21 , C07C43/225 , C07C69/75 , C07C255/28 , C07C255/45 , C07D211/14 , C07D239/26 , C07D239/36 , C07D317/14 , C09K19/00 , C09K19/30 , C09K19/32 , C09K19/34 , C09K19/52 , G02F1/13 , C07C121/46 , C07C121/48 , C07C121/64 , C07D319/06 , C09K3/34
CPC分类号: C07D239/26 , C07C13/28 , C07C17/08 , C07C17/18 , C07C23/18 , C07C255/00 , C07C43/184 , C07C43/21 , C07C43/225 , C07D211/14 , C07D317/14 , C09K19/3001 , C09K19/321 , C09K19/3402 , C09K19/3441 , C09K19/3469 , C09K19/3483 , C07C2101/14 , C09K2019/3422
摘要: Cyclohexane derivatives of formula IR.sup.1 --(A.sup.1).sub.m --Z.sup.1 --A--Z.sup.2 --(A.sup.2).sub.n --R.sup.2 Iwherein R.sup.1 and R.sup.2 are each H, an alkyl group which has 1-10 C atoms and in which one or two CH.sub.2 groups can also be replaced by O atoms, F, CL, Br, CN or --O--COR, A.sup.1 and A.sup.2 are each 1,4-phenylene, 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, piperidine-1,4-diyl, 1,4-bicyclo(2,2,2)-octylene or pyrimidine-2,5-diyl groups which are unsubstituted or substituted by 1-4 F atoms, A is a 1,4-cyclohexylene group which is substituted in the 1-position and/or 4-position by alkyl, alkoxy, fluorinated alkyl or fluorinated alkoxy, each of which has 1-5 C atoms, F, Cl, Br and/or CN and which can also carry 1 or 2 further F, Cl or Br atoms and/or CN groups, Z.sup.1 and Z.sup.2 are each --CO--O--, --O--CO--, --CH.sub.2 CH.sub.2 --, --OCH.sub.2 --, --CH.sub.2 O-- or a single bond, R is an alkyl group which has 1-5 C atoms, m is 1 or 2 and n is 0 or 1, it being possible, where m=2, for the two groups A.sup.1 to be identical or different from one another; and the acid addition salts of those compounds which are basic,are suitable for use as components of liquid-crystal dielectrics.
摘要翻译: 式I的环己烷衍生物R1-(A1)m-Z1-A-Z2-(A2)n-R2 I其中R1和R2各自为H,具有1-10个C原子的烷基,其中一个或两个CH2 基团也可以被O原子,F,CL,Br,CN或-O-COR取代,A1和A2各自为1,4-亚苯基,1,4-亚环己基,1,3-二恶烷-2,5-二基 ,未取代或被1-4个F原子取代的哌啶-1,4-二基,1,4-二环(2,2,2) - 亚辛基或嘧啶-2,5-二基,A是1,4 - 环己基,其在1-位和/或4-位被烷基,烷氧基,氟化烷基或氟代烷氧基取代,各自具有1-5个C原子,F,Cl,Br和/或CN, 还携带1或2个F,Cl或Br原子和/或CN基团,Z 1和Z 2各自为-CO-O-,-O-CO - , - CH 2 CH 2 - , - OCH 2 - , - CH 2 O-或单键 R为具有1-5个C原子的烷基,m为1或2,n为0或1,m = 2时,两组A1相同或不同; 和碱性的那些化合物的酸加成盐,适合用作液晶电介质的组分。
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公开(公告)号:US4265833A
公开(公告)日:1981-05-05
申请号:US91625
申请日:1979-11-05
申请人: Friedrich Werner , Heinz U. Blank
发明人: Friedrich Werner , Heinz U. Blank
IPC分类号: C07C213/02 , B01J31/00 , C07C67/00 , C07C213/00 , C07C215/82 , C07C217/92 , C07C85/06 , C07C101/04 , C07C121/64 , C07C137/00
CPC分类号: C07C215/82
摘要: A process for the preparation of hydroxy-diphenylamines by condensation of dihydroxybenzene with an excess amount of primary aromatic amine in the presence of a catalytic amount of an acid at elevated temperature is described wherein the excess aromatic amine and, if appropriate, the reaction product is distilled off from the reaction mixture in the presence of a base.
摘要翻译: 描述了一种在升高的温度下在催化量的酸存在下通过二羟基苯与过量的伯芳胺的缩合制备羟基 - 二苯胺的方法,其中过量的芳族胺和如果合适的话,反应产物是 在碱的存在下从反应混合物中蒸馏掉。
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5.
公开(公告)号:US4261652A
公开(公告)日:1981-04-14
申请号:US62623
申请日:1979-08-01
IPC分类号: C07C67/00 , C07C69/753 , C07C69/773 , C07C253/00 , C07C255/55 , C09K19/32 , C09K19/46 , G02F1/13 , G09F9/35 , C07C69/74 , C07C69/76 , C07C121/46 , C07C121/62 , C07C121/64 , C09K3/34
CPC分类号: C09K19/321
摘要: A novel liquid crystal compound has the molecular structure: ##STR1## where R is an alkyl group, which may contain up to 18 carbon atoms and which may be normal or branched and may contain a chiral center, ##STR2## is a bicyclo (2.2.2) octane ring, --X-- is and Y is a cyano group CN or R.sup.1 or OR.sup.1 where R.sup.1 has the same definition as R.The compound may be used in mixtures with other liquid crystal compounds in the same or other families and the compound or mixtures may be used in known liquid crystal devices, eg the twisted nematic and cholesteric-to-nematic phase change devices, depending on its properties.
摘要翻译: 一种新的液晶化合物具有以下分子结构:其中R是烷基,其可含有至多18个碳原子,并且其可以是正链或支链的并且可以含有手性中心, 是一个二环(2.2.2)辛烷环,-X-是< IMAGE> + TR< IMAGE> Y是氰基CN或R1或OR1,其中R1与R定义相同。化合物可以是 与其它相同或其他族中的其它液晶化合物的混合物中使用,并且该化合物或混合物可用于已知的液晶装置中,例如扭转的向列相和胆甾型至向列相变装置,这取决于其性质。
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公开(公告)号:US4219256A
公开(公告)日:1980-08-26
申请号:US62624
申请日:1979-08-01
IPC分类号: C09K19/32 , C07C121/60 , C07C121/64 , C09K3/34
CPC分类号: C09K19/321
摘要: A novel liquid crystal compound has the molecular structure: ##STR1## where R is an alkyl group, which may contain up to 18 carbon atoms and which may be normal or branched and may contain a chiral center, ##STR2## is a bicyclo (2.2.2) octane ring, ##STR3## is a phenyl ring and CN is a cyano group, n being an integer greater than 0 preferably 1 or 2.The compound may be used in mixtures with other liquid crystal compounds in the same or other families and the compound or mixtures may be used in known liquid crystal devices, eg the twisted nematic and cholesteric-to-nematic phase change devices, depending on its properties.
摘要翻译: 一种新的液晶化合物具有以下分子结构:其中R是烷基,其可以含有至多18个碳原子,并且其可以是正链或支链的并且可以含有手性中心,IMAGE是双环(2.2 .2)辛烷环,
为苯环,CN为氰基,n为大于0的整数,优选为1或2.该化合物可与其他族中其它液晶化合物的混合物使用 并且该化合物或混合物可以用于已知的液晶装置中,例如扭转的向列相和胆甾型至向列相变装置,这取决于其性质。 -
公开(公告)号:US4196975A
公开(公告)日:1980-04-08
申请号:US26781
申请日:1979-04-03
申请人: Hugh Mailer , Stanley Laskos, Jr.
发明人: Hugh Mailer , Stanley Laskos, Jr.
IPC分类号: C09K19/00 , C09K19/24 , C07C119/10 , C07C121/64 , C09K3/34
CPC分类号: C07C251/88 , C09K19/24
摘要: A light-control device includes a liquid crystal material sandwiched between a pair of planar, light-transmitting members. The liquid crystal material particularly includes an asymmetrical azine compound having the general formula: ##STR1## wherein R.sub.1 and R.sub.2 are different para-substituents selected from the group comprising cyano, halogen, alkyl, and substituted alkyl radicals in which the alkyl radical has from one to nine carbon atoms, and wherein X and Y are selected from the group comprising hydrogen and methyl radicals.
摘要翻译: 光控制装置包括夹在一对平面透光构件之间的液晶材料。 液晶材料特别包括具有以下通式的不对称吖嗪化合物:其中R 1和R 2是选自氰基,卤素,烷基和取代的烷基的不同对位取代基,其中烷基具有一个 至9个碳原子,并且其中X和Y选自氢和甲基。
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公开(公告)号:US4154697A
公开(公告)日:1979-05-15
申请号:US868573
申请日:1978-01-11
申请人: Rudolf Eidenschink , Joachim Krause , Ludwig Pohl
发明人: Rudolf Eidenschink , Joachim Krause , Ludwig Pohl
IPC分类号: C09K19/42 , C07C1/22 , C07C45/46 , C07C49/792 , C07C67/00 , C07C253/00 , C07C255/46 , C07C255/50 , C07C255/54 , C09K19/30 , C09K19/44 , C09K19/46 , C09K19/54 , C07C121/64 , C07C121/75 , C09K3/34
CPC分类号: C09K19/3003 , C07C1/22 , C07C45/46 , C07C49/792 , C07C2101/14 , C07C2521/18 , C07C2523/44
摘要: Novel liquid crystals have the formula ##STR1## wherein two of the rings A, B and C are aromatic and the third is a trans-1,4-disubstituted cyclohexane ring and R is alkyl or alkoxy each of 1 - 12 C-atoms. These compounds are particularly useful as additional components in liquid crystal dielectrics whereby the clear point of the dielectric is raised and the viscosity thereof is not deleteriously affected.
摘要翻译: 新型液晶具有式“IMAGE”,其中环A,B和C中的两个是芳族的,第三个是反式-1,4-二取代的环己烷环,R是1-12个碳原子的烷基或烷氧基。 这些化合物特别可用作液晶电介质中的附加组分,由此电介质的透明点升高并且其粘度不会受到有害影响。
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公开(公告)号:US3947375A
公开(公告)日:1976-03-30
申请号:US413247
申请日:1973-11-06
IPC分类号: C07C205/06 , C07C205/11 , C07C205/12 , C07C205/35 , C09K19/12 , C09K19/54 , C09K3/34 , C07C121/64 , C07C121/66 , C07C121/70 , G02B5/23 , G02F1/01 , G02F1/03 , G02F1/13
CPC分类号: C09K19/12 , C07C205/06 , C07C205/11 , C07C205/12 , C07C205/35 , C09K19/126 , C09K19/54 , C07C2103/18
摘要: A novel liquid crystal material contains a compound having a molecular structure such that the material exhibits a liquid crystal phase, the molecular structure of the compound being ##SPC1##Or an orthosubstituted derivative thereof, where X and Y are different parasubstituents of the kind which promote liquid crystal behaviour, where the para substituent is a group selected from the following list; an alkyl group, an acyloxy group, an unsaturated group or an alkoxy group having more than one carbon atom; and where the para-substituent Y is a group selected from the following list; a cyano group, a nitro group, a group which includes a terminal cyano group, a group which includes a terminal nitro group and an acyloxy group. The material may be the said compound or it may be a multi-component solution or mixture containing it. The liquid crystal material may be nematic, smectic or cholesteric depending on the selection of the substituents X and Y. A device such as a twisted nematic effect device, incorporating the material may be operated at low temperatures. The material does not suffer from significant chemical and/or photochemical decomposition when used in a liquid crystal device.
摘要翻译: 新型液晶材料含有具有分子结构的化合物,使得该材料表现出液晶相,该化合物的分子结构为OR或其衍生物,其中X和Y是促进液晶性能的不同的副成分 ,其中对位取代基是选自以下列表的基团; 烷基,酰氧基,不饱和基或具有多于一个碳原子的烷氧基; 并且其中对位取代基Y是选自以下列表的基团; 氰基,硝基,包括末端氰基的基团,包括末端硝基和酰氧基的基团。 该材料可以是所述化合物,或者它可以是含有它的多组分溶液或混合物。 取决于取代基X和Y的选择,液晶材料可以是向列型,近晶形或胆甾醇型。掺入该材料的扭曲向列效应器件的器件可以在低温下操作。 当用于液晶装置时,该材料不会受到显着的化学和/或光化学分解的影响。
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公开(公告)号:US3929859A
公开(公告)日:1975-12-30
申请号:US52472974
申请日:1974-11-18
申请人: STANDARD OIL CO OHIO
发明人: CALLAHAN JAMES L
IPC分类号: C07B61/00 , B01J21/00 , B01J23/00 , B01J23/72 , B01J23/76 , B01J27/00 , C07C67/00 , C07C253/00 , C07C255/04 , C07C255/33 , C07C120/00 , C07C121/20 , C07C121/26 , C07C121/64
CPC分类号: B01J23/72 , B01J23/76 , C07C253/30 , C07C255/04
摘要: The invention is the extrusion of sulfur from thiodinitriles to obtain the corresponding dinitrile by heating the thiodinitrile at a temperature of 200* to 700*C. For example, sulfur is extruded from thiodipropionitrile to obtain adiponitrile. This extrusion reaction can be either a strictly thermal reaction employing no other reactant or a reaction conducted in the presence of other gases, liquids or solids.
摘要翻译: 本发明是通过在200℃至700℃的温度下加热硫代腈来从硫代腈中挤出硫以获得相应的二腈。例如,硫从硫代二丙腈中挤出以获得己二腈。 该挤出反应可以是不使用其它反应物的严格热反应或在其它气体,液体或固体存在下进行的反应。
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