摘要:
A method of making polymeric particles by forming a suspension of ethylenically unsaturated monomer droplets in water, the water containing a particulate suspension agent, the monomer droplets containing a nonreactive hydrophobic compound where the water solubility of the nonreactive compound is less than that of the monomer and polymerizing the monomer droplets.
摘要:
Photographic elements having at least one light-sensitive layer and at least one layer having polymeric matte particles surrounded by a layer of colloidal inorganic particles.
摘要:
This invention comprises a thermally processable imaging element comprising:(1) a support;(2) a thermally processable imaging layer on one side of the support; and(3) a protective layer comprising:(A) a film-forming binder;(B) matte particles comprising a core surrounded by said film-forming binder.
摘要:
The present invention is a photographic element which includes a support, at least one silver halide emulsion layer; and at least one layer containing a binder and polymer particles. The polymeric particles are prepared by the process of mechanically forming droplets having a size less than 400 nm of an ethylenically unsaturated monomer having hydrophobic groups, the hydrophobic groups having a logP.sub.(calc) greater than a logP.sub.(calc) of the ethylenically unsaturated monomer by at least 1 unit, and polymerizing said droplets so that the polymerized droplets have a size of less than 400 nm. The present invention also is a photographic element which includes a support, at least one silver halide emulsion layer; and at least one layer containing a binder and polymer particles. The polymeric particles are prepared by the process of mechanically forming droplets having a size less than 400 nm of an ethylenically unsaturated monomer having a logP.sub.(calc) greater than 4, preferably greater than 6, and polymerizing said droplets so that the polymerized droplets have a size of less than 400 nm.
摘要:
A process of making polymeric matte bead particles for use in photographic elements which comprises forming a suspension of ethylenically unsaturated monomer droplets in an aqueous media, subsequent to the formation of droplets and before commencement of reaction, adding to the aqueous media an effective amount of a hydrophilic colloid to improve adhesion and polymerizing the monomer to form solid polymeric particles.
摘要:
This invention relates generally to compositions and methods for removing adherent materials and polishing surfaces. In one embodiment, the method employs an improved media comprising core-shell particles. The media can be applied to microelectronic objects of manufacture.
摘要:
The present invention is a method of making a stable colloidal non-aqueous wax particle dispersion. The method includes the steps of forming a mixture of a first vinyl monomer of a polymerizable mono-alpha, beta-ethylenically unsaturated compound free of ionic charge groups and capable of addition polymerization and a second vinyl monomer capable of addition polymerization and wax particle in a aqueous medum. The mixture is polymerized using an azo or diazo initiator to form an aqueous dispersion of composite wax particles. The wax particles are redispersed in an organic solvent.
摘要:
The present invention provides a photographic element comprises a support, at least one hydrophilic light-sensitive layer, and a light-insensitive layer containing a binder and polymer matte particles having the formula:(A).sub.x (B).sub.y (C).sub.z (I)where A is a monofunctional ethylenically unsaturated monomer which forms a homopolymer with a Tg less than 20.degree. C., B is a monofunctional ethylenically unsaturated monomer which forms a homopolymer with a Tg greater than 60.degree. C., C is a monomer with two or more ethylenically unsaturated groups, x is about 10 to 95 mole %, y is less than 85 mole %, and z is about 5 to 90 mole %.
摘要:
The present invention is a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having hydrophobic groups, the hydrophobic groups having a logP.sub.(calc) greater than a logP.sub.(calc) of the ethylenically unsaturated monomer by at least 1 unit in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm. The present invention is also a photographic element which includes a support, at least one silver halide emulsion layer, and a light-insensitive protective overcoat. The light insensitive protective overcoat includes a hydrophilic binder and polymer particles having a glass transition temperature of at least 70.degree. C. The polymer particles prepared by the process of mechanically forming oil-in-water droplets having a size less than 400 nm of an ethylenically unsaturated monomer having a logP.sub.(calc) greater than 4, preferably greater than 6 in an aqueous medium. A hydrophilic colloid is added to the aqueous medium in an amount sufficient to render the polymer partice compatible with the hydrophilic binder. The droplets are polymerized to a size of less than 400 nm.
摘要:
A sheet-like article comprising a continuous oriented polymer phase having dispersed therein from about 5-50% by weight of cross-linked polymeric microparticles based on the weight of the oriented polymer, the microparticles being partially bordered by void space, the void space occupying about 2 to 60% by volume of the sheet-like article, the cross-linked polymeric microparticles having been prepared by the free radical polymerization of an ethylenically mono-unsaturated monomer and an ethylenically poly-unsaturated monomer in the presence of an effective amount of diacyl peroxide to catalyze the reaction.