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37 条记录 (耗时 0.049 秒)

    Synthesis of aluminophosphates and silicoaluminophosphates
    21.
    发明授权
    Synthesis of aluminophosphates and silicoaluminophosphates 有权
    铝磷酸盐和硅铝磷酸盐的合成

    公开(公告)号：US07247287B2

    公开(公告)日：2007-07-24

    申请号：US10459204

    申请日：2003-06-11

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： C01B37/08

    CPC分类号： C01B37/04 ,  B01J29/85 ,  B01J2229/42 ,  C01B37/08 ,  C01B39/54 ,  C07C1/20 ,  C10G3/49 ,  C10G3/62 ,  C10G2400/20 ,  Y10S423/30 ,  C07C11/02

    摘要： The invention is directed to a method of synthesising silicoaluminophosphate and aluminophosphate molecular sieves using synthesis templates that contain at least one template of general formula R1R2N—R3, wherein R1 and R2 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R3 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms, and 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S. In particular, the present invention relates to the synthesis of silicoaluminophosphate molecular sieves of the CHA framework type having a low silicon to aluminium atomic ratio.

    摘要翻译： 本发明涉及一种使用含有至少一个通式为R 1，R 2，R 2，R 3，R 3，R 3，R 3，R 3， 其中R 1和R 2独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟基烷基 原子 R 3选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代，以及4至8元杂环基 具有1至3个杂原子，所述杂环基团任选被1至3个具有1至3个碳原子的烷基取代，并且所述杂环基中的杂原子选自O，N和S.特别地， 本发明涉及具有低硅铝原子比的CHA骨架类型的硅铝磷酸盐分子筛的合成。

    Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus
    22.
    发明授权
    Zeolite catalyst activity enhancement by aluminum phosphate and phosphorus 失效
    沸石催化剂活性提高磷酸铝和磷

    公开(公告)号：US6080303A

    公开(公告)日：2000-06-27

    申请号：US38649

    申请日：1998-03-11

    申请人： Guang Cao ,  Luc R. M. Martens ,  Jeffrey L. White ,  Tan-Jen Chen ,  Matu J. Shah

    发明人： Guang Cao ,  Luc R. M. Martens ,  Jeffrey L. White ,  Tan-Jen Chen ,  Matu J. Shah

    IPC分类号： B01J29/84 ,  B01J27/16 ,  B01J29/06 ,  C10G11/05 ,  C10G11/18

    CPC分类号： C10G11/05 ,  B01J27/16 ,  B01J29/06

    摘要： The present invention provides a process for improving the catalytic activity of small and medium pore acidic zeolite catalyst which comprises the steps of treating a zeolite with a phosphorus compound to form a phosphorus treated zeolite and combining the phosphorus treated zeolite with AlPO.sub.4. Optionally the phosphorus treated zeolite is calcined. The step of combining the zeolite with AlPO.sub.4 may optionally be followed by steaming the combined catalyst. Examples of useful phosphorus containing compounds useful in treating the zeolite include phosphoric acid, ammonium mono or dihydrogen phosphate, organic phosphites, and organophosphines. Preferably the phosphorus containing compound is an ammonium acid phosphate. An additional alternate embodiment provides a process for increasing the hydrothermal stability of a zeolite catalyst which comprises first treating a zeolite with a phosphorus containing compound then blending with AlPO.sub.4. The catalyst of the invention may be combined with other catalysts or used alone. The invention may be used in a process for cracking hydrocarbons which comprises contacting a hydrocarbon feedstock with a catalyst prepared as described above.

    摘要翻译： 本发明提供了改善中孔酸性沸石催化剂的催化活性的方法，其包括用磷化合物处理沸石以形成磷处理的沸石并将磷处理的沸石与AlPO 4组合的步骤。 任选地，将经磷处理的沸石煅烧。 将沸石与AlPO 4组合的步骤可以任选地随后蒸合组合的催化剂。 可用于处理沸石的含磷化合物的实例包括磷酸，磷酸一铵或二磷酸酯，有机亚磷酸酯和有机膦。 含磷化合物优选为磷酸铵。 另外的替代实施方案提供了一种提高沸石催化剂的水热稳定性的方法，其包括首先用含磷化合物处理沸石，然后与AlPO 4共混。 本发明的催化剂可与其它催化剂组合使用或单独使用。 本发明可用于裂解烃的方法，其包括使烃原料与如上所述制备的催化剂接触。

    SEEDED SYNTHESIS OF ALUMINOSILICATE MOLECULAR SIEVES
    23.
    发明申请
    SEEDED SYNTHESIS OF ALUMINOSILICATE MOLECULAR SIEVES 审中-公开
    酸性分子筛的合成

    公开(公告)号：US20150118151A1

    公开(公告)日：2015-04-30

    申请号：US14065581

    申请日：2013-10-29

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： B01J29/85 ,  B01J29/70

    CPC分类号： C01B39/04 ,  B01J29/70 ,  B01J29/7015 ,  B01J29/85 ,  C01B39/02 ,  C01B39/48

    摘要： A process for producing an aluminosilicate molecular sieve comprises crystallizing a reaction mixture comprising water, a source of silica and seeds of a silicoaluminophosphate and/or an aluminophosphate molecular sieve. The resultant aluminosilicate molecular sieve product can advantageously be substantially free of framework phosphorus.

    摘要翻译： 制备硅铝酸盐分子筛的方法包括使包含水，二氧化硅源和硅铝磷酸盐和/或磷酸铝分子筛的种子的反应混合物结晶。 所得的铝硅酸盐分子筛产物可以有利地基本上不含骨架磷。

    Synthesis of Silicoaluminophosphate Having Lev Framework-Type
    24.
    发明申请
    Synthesis of Silicoaluminophosphate Having Lev Framework-Type 审中-公开
    具有Lev框架型的硅铝磷酸盐的合成

    公开(公告)号：US20120157741A1

    公开(公告)日：2012-06-21

    申请号：US12972202

    申请日：2010-12-17

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： C07C1/20 ,  C01B39/54

    CPC分类号： C01B39/54 ,  B01J29/85 ,  C07C1/20 ,  C07C2529/85 ,  Y02P30/42 ,  C07C11/02

    摘要： A process for producing a silicoaluminophosphate molecular sieve having the LEV framework-type employs at least one source of triethylmethylammonium, R+, ions; as a templating agent. The resultant silicoaluminophosphate molecular sieve is useful as a catalyst in the conversion of methanol to olefins.

    摘要翻译： 制备具有LEV骨架型的硅铝磷酸盐分子筛的方法采用至少一种三乙基甲基铵R +离子源; 作为模板剂。 所得的硅铝磷酸盐分子筛可用作将甲醇转化为烯烃的催化剂。

    Method of synthesizing molecular sieves
    28.
    发明授权
    Method of synthesizing molecular sieves 有权
    合成分子筛的方法

    公开(公告)号：US07232787B2

    公开(公告)日：2007-06-19

    申请号：US10691268

    申请日：2003-10-22

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： B01J27/14

    CPC分类号： C10G3/49 ,  B01J29/06 ,  B01J29/83 ,  B01J29/85 ,  B01J37/0045 ,  C01B37/04 ,  C01B37/08 ,  C01B39/54 ,  C07C1/20 ,  C07C2529/83 ,  C07C2529/85 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42 ,  C07C11/02

    摘要： The invention is directed to a method of synthesizing a molecular sieve. In particular, the invention is directed to a method for synthesizing a molecular sieve, especially a silicoaluminophosphate molecular sieve, in the presence of a templating agent and a polymeric base. The invention is also directed to formulating the molecular sieve into a catalyst useful in a process for producing olefin(s), preferably ethylene and/or propylene, from a feedstock, preferably an oxygenate containing feedstock.

    摘要翻译： 本发明涉及合成分子筛的方法。 特别地，本发明涉及在模板剂和聚合物基质的存在下合成分子筛，特别是硅铝磷酸盐分子筛的方法。 本发明还涉及将分子筛配制成可用于从原料，优选含氧化合物原料生产烯烃，优选乙烯和/或丙烯的方法中的催化剂。

    Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins
    29.
    发明授权
    Synthesis of molecular sieves having the chabazite framework type and their use in the conversion of oxygenates to olefins 有权
    具有菱沸石骨架类型的分子筛的合成及其在将含氧化合物转化为烯烃的用途

    公开(公告)号：US08048402B2

    公开(公告)日：2011-11-01

    申请号：US11206444

    申请日：2005-08-18

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： C01B33/36 ,  C01B39/02 ,  C01B39/04 ,  C01B39/00 ,  C01F7/00

    CPC分类号： C01B39/54 ,  B01J29/83 ,  B01J29/85 ,  C01B37/04 ,  C01B37/08 ,  C10G3/49 ,  C10G3/62 ,  C10G2300/708 ,  C10G2400/20 ,  Y02P30/42

    摘要： The synthesis of a crystalline aluminophosphate or silicoaluminophosphate molecular sieve having a chabazite-type framework type is conducted in the presence of an organic directing agent having the formula (I) [R1R2R3N—R4]+X−  (I) wherein R1, R2 and R3 are independently selected from the group consisting of alkyl groups having from 1 to 3 carbon atoms and hydroxyalkyl groups having from 1 to 3 carbon atoms; R4 is selected from the group consisting of 4- to 8-membered cycloalkyl groups, optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms; 4- to 8-membered heterocyclic groups having from 1 to 3 heteroatoms, said heterocyclic groups being optionally substituted by 1 to 3 alkyl groups having from 1 to 3 carbon atoms and the heteroatoms in said heterocyclic groups being selected from the group consisting of O, N, and S; and aromatic groups optionally substituted by 1 to 3 alkyl groups, said alkyl groups having from 1 to 3 carbon atoms; and X− is an anion.

    摘要翻译： 在具有式（I）的有机导向剂[R1R2R3N-R4] + X-（I）的存在下进行具有菱沸石型骨架型的结晶铝磷酸盐或硅铝磷酸盐分子筛的合成，其中R1，R2和R3 独立地选自具有1至3个碳原子的烷基和具有1至3个碳原子的羟烷基; R4选自4-8元环烷基，任选被1至3个具有1至3个碳原子的烷基取代; 具有1至3个杂原子的4-至8-元杂环基，所述杂环基团任选被1至3个具有1至3个碳原子的烷基取代，所述杂环基中的杂原子选自O， N和S; 和任选被1至3个烷基取代的芳族基团，所述烷基具有1至3个碳原子; 而X-是阴离子。

    Synthesis of chabazite structure-containing molecular sieves and their use in the conversion of oxygenates to olefins
    30.
    发明授权
    Synthesis of chabazite structure-containing molecular sieves and their use in the conversion of oxygenates to olefins 有权
    含有菱沸石结构的分子筛的合成及其在含氧化合物转化为烯烃的用途

    公开(公告)号：US07939043B2

    公开(公告)日：2011-05-10

    申请号：US12137208

    申请日：2008-06-11

    申请人： Guang Cao ,  Matu J. Shah

    发明人： Guang Cao ,  Matu J. Shah

    IPC分类号： C01B37/04 ,  C01B37/08

    CPC分类号： C01B37/08 ,  B01J29/83 ,  B01J29/85 ,  C01B39/54 ,  C10G2400/20 ,  Y02P30/20 ,  Y02P30/42

    摘要： In a method of synthesizing a silicoaluminophosphate or aluminophosphate molecular sieve comprising a CHA framework-type material, a synthesis mixture is provided comprising a source of aluminum, a source of phosphorus, optionally a source of silicon and at least one organic template of formula (I): [R1R2R3R4N]+ X−  (I) wherein each of R1, R2, R3, and R4 is independently an acyclic alkyl group having at least one carbon atom, the total number of carbon atoms in said alkyl groups R1, R2, R3, and R4 is greater than 8 but less than 16, and X− is an anion. The synthesis mixture can then be crystallized to produce the desired molecular sieve.

    摘要翻译： 在合成包含CHA骨架型材料的硅铝磷酸盐或磷酸铝分子筛的方法中，提供了合成混合物，其包含铝源，磷源，任选的硅源和至少一种式（I ）：[R1R2R3R4N] + X-（I）其中R1，R2，R3和R4各自独立地为具有至少一个碳原子的无环烷基，所述烷基中的总碳原子数为R1，R2，R3 并且R4大于8但小于16，X-是阴离子。 然后可以将合成混合物结晶以产生所需的分子筛。