摘要:
The present invention relates to flame-retarding moulding compositions which are based on thermoplastic polycarbonates, copolymers of styrenes and maleic anhydride, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers, small amounts of graft polymers and optionally halogen compounds and which in addition can contain stabilizers, pigments, flow agents, release agents and/or antistatics, and to a process for their preparation.
摘要:
The present invention relates to flame-retarding, thermoplastic polycarbonate moulding materials of high impact strength consisting of halogen-containing polycarbonates, copolymers formed from styrenes and (meth)acrylonitrile, phosphorus compounds of the formula (I) ##STR1## tetrafluoroethylene polymers and small amounts of graft polymers and, if appropriate, effective amounts of stabilizers, pigments, lubricants, mould release agents and/or antistatic agents, and to a process for the preparation thereof.
摘要:
This invention provides thermoplastic moulding moulding compositions with good dimensional stability under heat and transparency consisting of particular graft polymers and optionally thermoplastic polymer resins.
摘要:
This invention relates to thermoplastic moulding compounds free from nitrile groups, containing a mixture of randomly structured copolymers containing methyl methacrylate, maleic acid anhydride and aromatic vinyl compounds, aromatic polycarbonate resins and an elastomer grafted with methyl methacrylate.
摘要:
This invention relates to thermoplastic moulding compounds which are free from nitrile groups, obtained from randomly structured aromatic vinyl copolymers containing N-phenyl- or methyl-maleimide, aromatic polycarbonate resins and an elastomer grafted with methyl methacrylate.
摘要:
The invention relates to flame-resistant ABS moulding materials containing a fluoro-organic polymer besides customary flameproofing additives and to a process for their manufactures.
摘要:
A process for the production of a pulverulent mixture consisting of(A) from 60 to 99 parts by weight of a brittle copolymer consisting of acrylonitrile and styrene, .alpha.-methylstyrene, methyl methacrylate or mixtures thereof, and(B) from 1 to 40 parts by weight of a flexible rubber-elastic polymer,by coagulating, in a first stage, a latex of (A) or a mixture of a latex of (A) and a part of a latex of (B), adding, in a second stage, the latex of (B) or the remaining part of the latex of (B), so that the desired quantity ratio of (A) to (B) is attained, and, in a third stage, separating the precipitated mixture of (A) and (B) from the aqueous phase, and drying it.
摘要:
Pourable rubber powders comprising particles having an average diameter of from 0.01 to 10 mm which contain, polymerized thereon, a shell of the polymer or copolymer of one or more vinyl monomers in a quantity of from 2 to 20% by weight, based on the rubber, and the core rubber is a latex polymer, the latex particles of which are composed of a core polymer and a sheath polymer, the core and sheath differing in their chemical composition and at least the sheath polymer being a diene or acrylate rubber having glass transition temperatures of below 0.degree. C., and a process for the preparation of such rubber powders, wherein a latex of an approximate rubber is completely broken with the formation of an aqueous suspension of the rubber; from 2 to 20% by weight, based on the rubber, of one or more vinyl monomers which form polymers having glass transition temperatures of above 25.degree. C. are then introduced into the suspension; and the monomer(s) is/are polymerized, optionally after adding a radical-forming catalyst.
摘要:
Graft copolymers having a diene rubber core surrounded by at least two different shells improve the impact strength under multi-axial stress of thermoplastic polyester moulding compositions.
摘要:
The present invention relates to a process for the preparation of bis-carbonic acid aryl esters of polyester-diols, lengthened via --OCOO-- groups, characterized in that polyester-diols with molecular weights Mn (number-average) of over 250, preferably over 600, are heated with carbonic acid bis-aryl esters at temperatures between about 100.degree. C. and 200.degree. C., preferably between about 110.degree. C. and 180.degree. C., in vacuo below about 35 mm Hg, preferably between about 25 and 1 mm Hg, in the presence of catalysts, less than one mol of carbonic acid bis-aryl ester being employed per OH group of the polyester-diol and the hydroxyaryl compounds formed being distilled off.The invention further relates to the bis-carbonic acid aryl esters of polyester-diols lengthened via --OCOO-- groups obtained according to the instant invention and their use for the preparation of polyester diol bis-diphenol carbonates, lengthened via carbonate groups, characterized in that polyester-diol bis-aryl carbonates are reacted with a diphenol at a temperature of from about 100.degree. to about 200.degree. C. in vacuo below about 35 mm Hg in the presence of a catalyst, wherein more than 1 mol of diphenol is employed per mol of carbonic acid aryl ester groups of the polyester-diol bis-aryl carbonate, lengthened via carbonate groups, and the resulting hydroxyaryl compound is distilled off.The invention finally relates to the polyester-diol bis-diphenol carbonates, lengthened via carbonate groups obtained according to the instant invention and their use for the preparation of polyester/polycarbonates and the polycarbonate/polyesters so prepared.