公开(公告)号：US4939219A

公开(公告)日：1990-07-03

申请号：US302659

申请日：1989-01-27

申请人： Hirokazu Terashima ,  Osamu Isozaki

发明人： Hirokazu Terashima ,  Osamu Isozaki

IPC分类号： C09D5/14 ,  C09D5/16 ,  C09D133/04 ,  C09D133/14 ,  C09D133/16

CPC分类号： C09D5/1668 ,  C09D133/14 ,  C09D133/16

摘要： Disclosed is a coating composition for preventing adhesion of aquatic organisms, the composition containing as a vehicle component a copolymer prepared by copolymerizing about 5 to about 85% by weight of (A) a monohydric and/or polyhydric phenol ester of acrylic or methacrylic acid; about 15 to about 75% by weight of (B) an ethylenically unsaturated monomer having a soluble parameter of about 8.0 to about 9.5 and a glass transition temperature of about 0.degree. C. or higher; and about 0 to about 50% by weight of (C) a water-soluble, ethylenically unsaturated monomer containing carboxyl group or amino group, based on the total monomer components.

公开(公告)号：US4927884A

公开(公告)日：1990-05-22

申请号：US269084

申请日：1988-11-09

申请人： Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

发明人： Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C08K5/00 ,  C08L83/06 ,  C08L83/07 ,  C08L83/10 ,  C09D183/07

CPC分类号： C08L83/06 ,  C08K5/0091 ,  C08L83/10

摘要： Disclosed is a curable composition characterized in that the composition comprises:(i) 100 parts by weight of a polymer mixture of(a) about 5 to about 95% by weight of a polymer (X) containing a specific polysiloxane macromonomer as an essential monomer or a polymer (Y) containing a specific alkoxysilane-containing vinyl monomer as an essential monomer, and(b) about 95 to about 5% by weight of a polymer (Z) containing an epoxy-containing vinyl monomer as an essential monomer; and(ii) about 0.01 to about 30 parts by weight of at least one chelate compound selected from the group consisting of aluminum chelate compound, titanium chelate compound and zirconium chelate compound.

摘要翻译： 公开了一种可固化组合物，其特征在于所述组合物包含：（i）100重量份的（a）约5至约95重量％的含有特定聚硅氧烷大分子单体作为必需单体的聚合物（X）的聚合物混合物 或含有特定烷氧基硅烷的乙烯基单体作为必需单体的聚合物（Y），和（b）含有含环氧基乙烯基单体作为必需单体的聚合物（Z）约95〜约5重量％ 和（ii）约0.01至约30重量份的选自铝螯合化合物，钛螯合物和锆螯合物的至少一种螯合化合物。

公开(公告)号：US4904504A

公开(公告)日：1990-02-27

申请号：US240657

申请日：1988-09-06

申请人： Osamu Isozaki ,  Naozumi Iwasawa

发明人： Osamu Isozaki ,  Naozumi Iwasawa

IPC分类号： C09D5/14 ,  C09D5/16 ,  C09D183/00 ,  C09D183/14

CPC分类号： C09D183/14 ,  C09D5/1675 ,  Y10T428/31663

摘要： Disclosed is a method of preventing adhesion of organisms characterized by coating a substrate with a coating composition comprising as its vehicle component a reaction product of a silane compound and/or a low condensation product thereof and an organic compound having at least two hydroxyl groups per molecule, the silane compound being represented by the formula(R.sup.1).sub.n Si--(OR.sup.2).sub.4-nwherein R.sup.1 is alkyl having 1 to 20 carbon atoms, haloalkyl having 1 to 12 carbon atoms, cycloalkyl having 3 to 7 carbon atoms, aryl or aralkyl having an alkyl portion with 1 to 12 carbon atoms, R.sup.2 is a hydrogen atom, alkyl having 1 to 8 carbon atoms, cycloalkyl having 3 to 7 carbon atoms or haloalkyl having 1 to 8 carbon atoms and n is an integer of 0 to 3.

摘要翻译： 公开了一种防止生物体粘附的方法，其特征在于用涂料组合物涂布基材，该涂料组合物包含作为其载体组分的硅烷化合物和/或其低缩合产物和每分子具有至少两个羟基的有机化合物的反应产物 硅烷化合物由式（R 1）n -Si-（OR 2）4-n表示，其中R 1是具有1至20个碳原子的烷基，具有1至12个碳原子的卤代烷基，具有3至7个碳原子的环烷基，芳基或芳烷基 具有1至12个碳原子的烷基部分，R 2是氢原子，具有1至8个碳原子的烷基，具有3至7个碳原子的环烷基或具有1至8个碳原子的卤代烷基，n是0至3的整数。

公开(公告)号：US20110196059A1

公开(公告)日：2011-08-11

申请号：US13122789

申请日：2009-09-09

申请人： Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

发明人： Akinori Nagai ,  Yoshiaki Chino ,  Masami Kobata ,  Osamu Isozaki

IPC分类号： C08F2/46 ,  C07F7/10

CPC分类号： C09D143/04 ,  C07F7/21 ,  C08F230/08 ,  C08G77/04 ,  C08G77/20 ,  C08G77/26

摘要： To provide a composition comprising a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.A silsesquioxane compound comprising organic groups each directly attached to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more urethane bonds and one (meth)acryloyloxy group.

摘要翻译： 本发明提供一种能够制造耐热性，耐划伤性优异的涂膜的倍半硅氧烷化合物，与一般的聚合性不饱和化合物以及具有高极性的聚合性不饱和化合物的相容性优异的组合物。 包含与化合物的硅原子直接相连的有机基团的倍半硅氧烷化合物，所述有机基团中的至少一个为具有1个以上的氨基甲酸酯键和1个（甲基）丙烯酰氧基的有机基团。

公开(公告)号：US20110160330A1

公开(公告)日：2011-06-30

申请号：US13060920

申请日：2009-08-12

申请人： Akinori Nagai ,  Masami Kobata ,  Osamu Isozaki

发明人： Akinori Nagai ,  Masami Kobata ,  Osamu Isozaki

IPC分类号： C08F2/46 ,  C07F7/21

CPC分类号： C07F7/21 ,  C08F30/08 ,  C08F283/12 ,  C08F290/068 ,  C08F290/148 ,  C08G77/045 ,  C08G77/20 ,  C09D183/04 ,  C08F220/10

摘要： An object of the present invention is to provide a silsesquioxane compound that is capable of producing a coating film with excellent heat resistance and scratch resistance, and that has excellent compatibility with general polymerizable unsaturated compounds as well as polymerizable unsaturated compounds with high polarity.The present invention provides a silsesquioxane compound comprising organic groups each directly bonded to a silicon atom of the compound, at least one of the organic groups being an organic group having one or more secondary hydroxyl groups and one (meth)acryloyloxy group.

摘要翻译： 本发明的目的在于提供能够制造耐热性，耐划伤性优异的涂膜，并且与一般的聚合性不饱和化合物以及高极性的聚合性不饱和化合物的相容性优异的倍半硅氧烷化合物。 本发明提供一种倍半硅氧烷化合物，其包含与化合物的硅原子直接键合的有机基团，所述有机基团中的至少一个为具有一个以上的仲羟基和一个（甲基）丙烯酰氧基的有机基团。

公开(公告)号：US06733580B2

公开(公告)日：2004-05-11

申请号：US10408549

申请日：2003-04-08

申请人： Osamu Isozaki

发明人： Osamu Isozaki

IPC分类号： C01G2304

CPC分类号： C23C18/1216 ,  C01G23/053 ,  C01P2004/84 ,  C01P2006/60

摘要： A method for preparing an inorganic film-forming coating composition. The method involves reacting a titanium monomer and/or a low condensation product thereof containing a group hydrolyzed to form a hydroxyl group with a hydrogen peroxide water.

摘要翻译： 一种无机成膜涂料组合物的制备方法。 该方法包括使含有水解形成羟基的基团的钛单体和/或其低缩合产物与过氧化氢水反应。

公开(公告)号：US5578695A

公开(公告)日：1996-11-26

申请号：US357267

申请日：1994-12-13

申请人： Osamu Isozaki

发明人： Osamu Isozaki

IPC分类号： C08G59/42 ,  C08G67/04 ,  C08L63/00 ,  C08L73/02 ,  C09D133/06

CPC分类号： C08L63/00 ,  C08G59/42 ,  C08G67/04 ,  C08L73/02 ,  C09D133/068

摘要： The invention provides a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the following formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500.The invention also provides a curable composition including (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of a resin having at least two epoxy groups in the molecule and a resin having at least two hydroxyl groups in the molecule, and (iii) a resin having at least two epoxy groups in the molecule, and (B) the above-mentioned crosslinking agent.

摘要翻译： 本发明提供了包含具有至少两个非环状酸酐基团并由下式表示的化合物的交联剂：其中R是具有2-50个碳原子的一价烃基，R'是二价烃基 具有2-50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n是1至500的整数。本发明还提供一种可固化组合物，其包含（A） 至少一种树脂，其选自（i）分子中具有至少一个环氧基和至少一个羟基的树脂，（ii）分子中具有至少两个环氧基的树脂的树脂混合物和 分子中具有至少两个羟基的树脂，和（iii）分子中具有至少两个环氧基的树脂和（B）上述交联剂。

公开(公告)号：US5426135A

公开(公告)日：1995-06-20

申请号：US177934

申请日：1994-01-06

申请人： Osamu Isozaki ,  Kiyoshi Nanishi ,  Hisashi Isaka

发明人： Osamu Isozaki ,  Kiyoshi Nanishi ,  Hisashi Isaka

IPC分类号： C08F8/42 ,  C08F8/46 ,  C08G77/442 ,  C09D5/16 ,  C09D135/00 ,  C09D183/06 ,  C09D183/10 ,  C09D201/08 ,  C09D201/10

CPC分类号： C08G77/442 ,  C08F8/42 ,  C08F8/46 ,  C09D135/00 ,  C09D183/06 ,  C09D183/10 ,  C09D201/08 ,  C09D201/10 ,  C09D5/165

摘要： The present invention provides a soil preventing coating forming composition which consists essentially of a resin having at least two acid anhydride groups in the molecule on the average, the acid anhydride groups being represented by the formula ##STR1## wherein R is a C.sub.1-40 monovalent hydrocarbon group or a monovalent chain polysiloxane group represented by the formula ##STR2## wherein R.sub.1 and R.sub.2 are the same or different and are each alkyl, cycloalkyl, aryl, aralkyl or ##STR3## group, R.sub.3, R.sub.4, R.sub.5, R.sub.6 and R.sub.7 are the same or different and are each alkyl, cycloalkyl, aryl or aralkyl, n is an integer of 1 to 6, m is an integer of 0 or 1, p is an integer of 2 to 50, and q is an integer of 0 to 50.

摘要翻译： 本发明提供一种防污涂层形成组合物，其基本上由分子中具有至少两个酸酐基团的树脂组成，平均酸酐基由式碳基团表示，或由式 式（II）其中R 1和R 2相同或不同并且各自为烷基，环烷基，芳基，芳烷基或者基团，R 3，R 4，R 5，R 6和R 7相同或不同，各自为烷基 ，环烷基，芳基或芳烷基，n为1〜6的整数，m为0或1的整数，p为2〜50的整数，q为0〜50的整数。

公开(公告)号：US5093223A

公开(公告)日：1992-03-03

申请号：US278505

申请日：1988-12-01

申请人： Naozumi Iwasawa ,  Osamu Isozaki

发明人： Naozumi Iwasawa ,  Osamu Isozaki

IPC分类号： B05D3/06 ,  C08G59/14 ,  C08J3/28 ,  G03F7/038

CPC分类号： G03F7/038 ,  B05D3/068 ,  C08G59/1433 ,  C08J3/28 ,  G03F7/0388 ,  Y10S522/904

摘要： The invention provides a method of forming a cured coating film which comprises exposing a coating composition consisting of, or containing as a main component, a resin containing polymerizable unsaturated group and aprotic onium-containing group of the formula ##STR1## wherein R.sub.1 means a hydrogen atom or a hydrocarbon group of 1 to 8 carbon atoms which may optionally be substituted by a hydroxyl, alkoxy or ester group or a halogen atom; ##STR2## where Z means a nitrogen atom or phosphorus atom and Y means a sulfur atom; R.sub.2, R.sub.3 and R.sub.4 are the same or different and respectively mean an organic group of 1 to 14 carbon atoms, provided that R.sub.2 and R.sub.3, or R.sub.2, R.sub.3 and R.sub.4 may jointly form a heterocyclic group taken together with the adjacent nitrogen, phosphorus or sulfur atom, to actinic radiation or electron beams to thereby induce a crosslinking reaction and, then, subjecting the composition to heat treatment at a temperature not less than 80.degree. C.

摘要翻译： 本发明提供一种形成固化涂膜的方法，该方法包括使包含可聚合不饱和基团的树脂和式（Ⅰ）所示的非质子含鎓基团组成或包含作为主要成分的涂料组合物，其中R 1 是指氢原子或可任选被羟基，烷氧基或酯基或卤素原子取代的1至8个碳原子的烃基; 其中Z表示氮原子或磷原子，Y表示硫原子; R 2，R 3和R 4相同或不同，分别表示1至14个碳原子的有机基团，条件是R 2和R 3或R 2，R 3和R 4可以与相邻的氮，磷或磷一起形成杂环基 硫原子，光化辐射或电子束，从而引起交联反应，然后使组合物在不低于80℃的温度下进行热处理。

公开(公告)号：US5087286A

公开(公告)日：1992-02-11

申请号：US496201

申请日：1990-03-19

申请人： Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

发明人： Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C09D133/08 ,  C09D163/00 ,  C09D167/00 ,  C09D183/04

CPC分类号： C09D167/00 ,  C09D133/08 ,  C09D163/00 ,  C09D183/04

摘要： A heat-curable resinous coating composition comprising as a binder component(A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins,(B) 5 to 50% by weight of an amino resin, and(C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.