公开(公告)号：US5087286A

公开(公告)日：1992-02-11

申请号：US496201

申请日：1990-03-19

申请人： Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

发明人： Mitsuhiro Fukuda ,  Hirotoshi Inoue ,  Akira Kasari ,  Yuzo Miyamoto ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C09D133/08 ,  C09D163/00 ,  C09D167/00 ,  C09D183/04

CPC分类号： C09D167/00 ,  C09D133/08 ,  C09D163/00 ,  C09D183/04

摘要： A heat-curable resinous coating composition comprising as a binder component(A) 5 to 90% by weight of a hydroxyl-containing resin selected from hydroxyl-containing acrylic resins and hydroxyl-containing polyester resins,(B) 5 to 50% by weight of an amino resin, and(C) 1 to 90% by weight of a crosslinkable resin selected from (C-a) polyfunctional resins having a number average molecular weight of at least 1000 and containing at least two carboxyl groups and at least two epoxy groups on an average per molecule and (C-b) polyorganosiloxanes having a number average molecular weight of at least 500 and containing at least two silanol groups on an average per molecule and if required, further containing an epoxy group.

公开(公告)号：US5641574A

公开(公告)日：1997-06-24

申请号：US553399

申请日：1995-11-21

申请人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

发明人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John David Nordstrom

IPC分类号： B05D1/36 ,  B05D7/00 ,  B05D7/24 ,  C08G59/42 ,  C09D157/00 ,  C09D163/00 ,  C09D167/00 ,  C09D167/02 ,  C09D175/00 ,  C09D175/04 ,  C09D201/00

CPC分类号： B05D7/532 ,  C08G59/42 ,  Y10T428/31511

摘要： A process for forming an overcoat by the two-coat one-bake method wherein a base coat composition and a clear coat composition are applied to a substrate ##STR1## wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is an aqueous coating composition consisting primarily of: (I) an aqueous dispersion or solution of a polymer containing a crosslinkable functional group, (II) a crosslinking agent, (III) a coloring pigment, and (IV) water, the clear coat composition being a coating composition comprising: (A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecule, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof, (B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by formula (1) wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500, and (C) a curing catalyst.

摘要翻译： PCT No.PCT / JP93 / 00678 Sec。 371日期：1995年11月21日 102（e）1995年11月21日日期PCT提交1993年5月24日PCT公布。 第WO94 / 27741号公报 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法，其中将底涂层组合物和透明涂层组合物施加到基底上（1）湿润湿润，然后在 该方法的特征在于底涂层组合物是主要由以下组成的水性涂料组合物：（I）含有可交联官能团的聚合物的水性分散体或溶液，（II）交联剂，（ III）着色颜料和（IV）水，所述透明涂料组合物为涂料组合物，其包含：（A）至少一种选自以下的树脂：（i）具有至少一个环氧基的树脂和至少一种 （ii）分子中具有至少两个环氧基的树脂（ii-1）和（ii-2）分子中具有至少两个羟基的树脂的树脂混合物，（iii）分子中具有至少两个羟基的树脂， 分子中具有至少两个环氧基的树脂，和（iv）任何混合物 （B）交联剂，其包含具有至少两个非环状酸酐基团并由式（1）表示的化合物，其中R是具有2至50个碳原子的一价烃基，R'是具有2至 50个碳原子，含有或不含醚键的烃基R和R'，氨基甲酸酯键或酯键，n为1〜500的整数，（C）固化催化剂。

公开(公告)号：US5609960A

公开(公告)日：1997-03-11

申请号：US553398

申请日：1995-11-21

申请人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John D. Nordstrom

发明人： Akira Kasari ,  Satoshi Ikushima ,  Osamu Isozaki ,  Naoji Matsumoto ,  John D. Nordstrom

IPC分类号： B05D1/36 ,  B05D3/02 ,  B05D5/00 ,  B05D7/00 ,  B05D7/24 ,  B05D7/26 ,  C08G59/42 ,  C08L33/06 ,  C08L73/02 ,  C09D133/04 ,  C09D133/06 ,  C09D133/14 ,  C09D161/20 ,  C09D163/00 ,  C09D167/00 ,  C09D167/02 ,  C09D201/02 ,  C09D201/06

CPC分类号： B05D7/532 ,  C08G59/42 ,  C09D133/068 ,  C09D163/00 ,  C08L33/066 ,  C08L73/02 ,  Y10T428/31511

摘要： A process for forming an overcoat by the two-coat one-bake method wherein a basecoat composition and a clear coat composition are applied to a substrate wet-on-wet and thereafter cured at the same time by heating, the process being characterized in that the base coat composition is a coating composition consisting primarily of a hydroxyl-containing resin, an amine resin, a pigment and an organic solvent, the clear coat composition being a coating composition comprising:(A) at least one resin selected from the group consisting of (i) a resin having at least one epoxy group and at least one hydroxyl group in the molecue, (ii) a resin mixture of (ii-1) a resin having at least two epoxy groups in the molecule and (ii-2) a resin having at least two hydroxyl groups in the molecule, (iii) a resin having at least two epoxy groups in the molecule, and (iv) any mixture thereof,(B) a crosslinking agent comprising a compound having at least two noncyclic acid anhydride groups and represented by the formula ##STR1## wherein R is a monovalent hydrocarbon group having 2 to 50 carbon atoms, R' is a bivalent hydrocarbon group having 2 to 50 carbon atoms, the hydrocarbon groups R and R' containing or not containing an ether linkage, urethane linkage or ester linkage, and n is an integer of 1 to 500 and (C) a curing catalyst.

摘要翻译： PCT No.PCT / JP93 / 00669 Sec。 371日期：1995年11月21日 102（e）日期1995年11月21日PCT提交1993年5月21日PCT公布。 公开号WO94 / 27740 日期1994年12月8日一种通过双层单烘烤法形成外涂层的方法，其中将底涂层组合物和透明涂层组合物施加到湿润基板上，然后通过加热同时固化， 方法的特征在于，底涂层组合物是主要由含羟基树脂，胺树脂，颜料和有机溶剂组成的涂料组合物，透明涂料组合物是涂料组合物，其包含：（A）至少一种树脂 选自（i）在分子中具有至少一个环氧基和至少一个羟基的树脂，（ii）（ii-1）在分子中具有至少两个环氧基的树脂的树脂混合物 和（ii-2）在分子中具有至少两个羟基的树脂，（iii）分子中具有至少两个环氧基的树脂，和（iv）其任何混合物，（B）包含化合物 具有至少两个非环酸酐基团a d由下式表示：其中R是具有2至50个碳原子的一价烃基，R'是具有2至50个碳原子的二价烃基，烃基R和R'含有或不含有醚键 氨基甲酸酯键或酯键，n为1〜500的整数，（C）固化催化剂。

公开(公告)号：US5583246A

公开(公告)日：1996-12-10

申请号：US573545

申请日：1995-12-15

申请人： Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

发明人： Haruhiko Aida ,  Noboru Nakai ,  Osamu Isozaki

IPC分类号： C08G77/445 ,  C07F7/04 ,  C08G77/02 ,  C08G77/42 ,  C09D183/04 ,  C09D183/06 ,  C07F7/18 ,  C07F7/08

CPC分类号： C08G77/02 ,  C07F7/04

摘要： The invention provides a lactone-modified organopolysiloxane compound represented by the formula ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are the same or different and each represents a methyl group, an ethyl group, a n-propyl group, an isopropyl group or a group represented by the formula ##STR2## wherein R.sub.5 is a methyl group, an ethyl group, a n-propyl group or an isopropyl group, X is a saturated divalent hydrocarbon group having 2 to 14 carbon atoms, and m is an integer of 1 to 3, provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is a group represented by the formula ##STR3## wherein R.sub.5, X and m are as defined above, and n is an integer of 1 to 100. The polysiloxane compound of the invention is excellent in compatibility with various organic resins.

摘要翻译： 本发明提供由式（I）表示的内酯改性的有机聚硅氧烷化合物，其中R 1，R 2，R 3和R 4相同或不同，并且各自表示甲基，乙基，正丙基， 异丙基或由下式表示的基团：其中R 5为甲基，乙基，正丙基或异丙​​基，X为碳原子数2〜14的饱和二价烃基，m为 其中R 1，R 2，R 3和R 4中的至少一个是由下式表示的基团：其中R 5，X和m定义同上，n为1至100的整数。 本发明的聚硅氧烷化合物与各种有机树脂的相容性优异。

公开(公告)号：US5408001A

公开(公告)日：1995-04-18

申请号：US107580

申请日：1993-08-18

申请人： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

发明人： Akimasa Nakahata ,  Nobushige Numa ,  Masahiro Yamane ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C08L63/00 ,  C09D201/04 ,  C08L27/12 ,  C08L27/14 ,  C08L33/14 ,  C08L63/02

CPC分类号： C08L63/00 ,  C09D201/04

摘要： Disclosed are:1) a three-component resin composition comprising a hydroxyl group-containing compound (A), an epoxy group-containing compound (B) and a silane group-containing compound (C);2) a two-component resin composition comprising a hydroxyl group-containing compound (A) and silane group- and epoxy group-containing compound (D);3) a two-component resin composition comprising hydroxyl group- and silane group-containing compound (E) and epoxy group-containing compound (B); and4) two-component resin composition comprising hydroxyl group- and epoxy group-containing compound (F) and silane group-containing compound (C); wherein at least one of the components in each of the resin compositions 1) to 4) is (are) fluorine-containing resin;5) a curable composition comprising one of the resin compositions 1) to 4) and a metal chelate compound as curing catalyst; and6) coating compositions comprising such curing composition and when required a pigment.

摘要翻译： 公开的是：1）包含含羟基的化合物（A），含环氧基的化合物（B）和含硅烷基的化合物（C）的三组分树脂组合物; 2）包含含羟基的化合物（A）和含硅烷基和含环氧基的化合物（D）的双组分树脂组合物; 3）包含含羟基和含硅烷基的化合物（E）和含环氧基的化合物（B）的双组分树脂组合物; 和4）包含含羟基和含环氧基的化合物（F）和含硅烷基化合物（C）的双组分树脂组合物; 其中，树脂组合物1）〜4）中的至少一种成分为含氟树脂， 5）包含树脂组合物1）至4）之一的可固化组合物和作为固化催化剂的金属螯合物; 和6）包含这种固化组合物和需要时颜料的涂料组合物。

公开(公告)号：US5079312A

公开(公告)日：1992-01-07

申请号：US522401

申请日：1990-05-11

申请人： Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

发明人： Osamu Isozaki ,  Noboru Nakai ,  Koichiro Murata

IPC分类号： C08F30/08 ,  C08F283/12 ,  C08F290/00 ,  C08F299/08 ,  C08G77/20 ,  C08G77/22 ,  C08G77/42

CPC分类号： C08F283/124 ,  C08G77/20

摘要： The invention provides a process for preparing a polysiloxane-containing resin which comprises copolymerizing a polysiloxane-type macromonomer with a vinyl monomer, characterized in that the polysiloxane-type macromonomer is one prepared by reacting about 70 to about 99.999 mole % of a compound (A) represented by the formula ##STR1## wherein R.sub.1 represents aliphatic hydrocarbon group having 1 to 8 carbon atoms or phenyl group, and R.sub.2, R.sub.3 and R.sub.4 each represent alkoxyl group having 1 to 4 carbon atoms or hydroxyl group with about 30 to about 0.001 mole % of a compound (B) represented by the formula ##STR2## wherein R.sub.5 represents hydrogen atom or methyl group, R.sub.6, R.sub.7 and R.sub.8 each represent hydroxyl group, alkoxyl group having 1 to 4 carbon atoms or aliphatic hydrocarbon group having 1 to 8 carbon atoms with the proviso that R.sub.6, R.sub.7 and R.sub.8 can not be aliphatic hydrocarbon groups having 1 to 8 carbon atoms at the same time, and n is an integer of 1 to 6, the polysiloxane-type macromonomer having at least two free functional groups selected from hydroxyl groups and alkoxyl groups per molecule, and the macromonomer having a number-average molecular weight of about 400 to about 100,000.

摘要翻译： 本发明提供一种制备含聚硅氧烷的树脂的方法，其包括将聚硅氧烷型大分子单体与乙烯基单体共聚，其特征在于，所述聚硅氧烷型大分子单体是通过使约70-约99.999摩尔％的化合物（A ），其中R 1表示具有1至8个碳原子的脂族烃基或苯基，R 2，R 3和R 4各自表示具有1至4个碳原子的烷氧基或羟基，其中约30至 约0.001摩尔％的由式（II）表示的化合物（B），其中R5表示氢原子或甲基，R6，R7和R8各自表示羟基，具有1至4个碳原子的烷氧基或脂族烃 具有1至8个碳原子的基团，条件是R 6，R 7和R 8不能同时为具有1至8个碳原子的脂族烃基，n为1至6的整数，聚硅氧烷型大分子量 具有至少两个选自每个分子的羟基和烷氧基的游离官能团，并且大分子单体的数均分子量为约400至约100,000。

公开(公告)号：US4965312A

公开(公告)日：1990-10-23

申请号：US924477

申请日：1986-10-29

申请人： Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

发明人： Noboru Nakai ,  Osamu Isozaki ,  Susumu Midogohchi

IPC分类号： C08F2/14 ,  C08F2/00 ,  C08F2/08 ,  C08F2/18 ,  C08F2/24 ,  C08F2/44 ,  C08L83/04 ,  C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C09D201/00

CPC分类号： C09D133/06 ,  C09D157/00 ,  C09D183/04 ,  C08L83/04

摘要： A vehicle composition for coating materials is disclosed. The vehicle composition includes an organic liquid, finely divided particles of a vinyl polymer dispersed in the organic liquid and a polymer of alkoxysiloxane having an alkoxy group of 3 to 5 carbon atoms dissolved in the organic liquid. The vehicle composition is prepared by polymerizing at least one vinyl monomer in the organic liquid which has the alkoxysiloxane polymer dissolved therein, the organic liquid being capable of dissolving the vinyl monomer but incapable of dissolving the vinyl polymer obtained therefrom.

摘要翻译： 公开了一种用于涂料的载体组合物。 车辆组合物包括有机液体，分散在有机液体中的细分散的乙烯基聚合物颗粒和溶解在有机液体中的具有3至5个碳原子的烷氧基的烷氧基硅氧烷的聚合物。 载体组合物通过使溶解有烷氧基硅氧烷聚合物的有机液体中的至少一种乙烯基单体聚合而制备，有机液体能够溶解乙烯基单体，但不能溶解由其获得的乙烯基聚合物。

公开(公告)号：US4927884A

公开(公告)日：1990-05-22

申请号：US269084

申请日：1988-11-09

申请人： Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

发明人： Naozumi Iwasawa ,  Osamu Isozaki ,  Noboru Nakai

IPC分类号： C08K5/00 ,  C08L83/06 ,  C08L83/07 ,  C08L83/10 ,  C09D183/07

CPC分类号： C08L83/06 ,  C08K5/0091 ,  C08L83/10

摘要： Disclosed is a curable composition characterized in that the composition comprises:(i) 100 parts by weight of a polymer mixture of(a) about 5 to about 95% by weight of a polymer (X) containing a specific polysiloxane macromonomer as an essential monomer or a polymer (Y) containing a specific alkoxysilane-containing vinyl monomer as an essential monomer, and(b) about 95 to about 5% by weight of a polymer (Z) containing an epoxy-containing vinyl monomer as an essential monomer; and(ii) about 0.01 to about 30 parts by weight of at least one chelate compound selected from the group consisting of aluminum chelate compound, titanium chelate compound and zirconium chelate compound.

摘要翻译： 公开了一种可固化组合物，其特征在于所述组合物包含：（i）100重量份的（a）约5至约95重量％的含有特定聚硅氧烷大分子单体作为必需单体的聚合物（X）的聚合物混合物 或含有特定烷氧基硅烷的乙烯基单体作为必需单体的聚合物（Y），和（b）含有含环氧基乙烯基单体作为必需单体的聚合物（Z）约95〜约5重量％ 和（ii）约0.01至约30重量份的选自铝螯合化合物，钛螯合物和锆螯合物的至少一种螯合化合物。

公开(公告)号：US5026793A

公开(公告)日：1991-06-25

申请号：US402408

申请日：1989-09-05

申请人： Noboru Nakai ,  Osamu Isozaki ,  Naozumi Iwasawa

发明人： Noboru Nakai ,  Osamu Isozaki ,  Naozumi Iwasawa

IPC分类号： C08G59/40 ,  C07F7/08 ,  C07F7/18 ,  C08G59/00 ,  C08G59/02 ,  C08G59/04 ,  C08G59/30 ,  C08G59/32 ,  C08G59/70 ,  C08K5/00 ,  C08K5/07 ,  C08K5/1515 ,  C08K5/5415 ,  C08L33/06 ,  C08L43/04 ,  C08L63/00 ,  C08L75/04 ,  C08L101/06 ,  C09D133/06 ,  C09D133/14 ,  C09D143/04 ,  C09D163/00

CPC分类号： C08L63/00 ,  C07F7/0836 ,  C07F7/0858 ,  C07F7/0859 ,  C07F7/182 ,  C07F7/1836 ,  C07F7/1844 ,  C07F7/1896 ,  C08G59/02 ,  C08G59/04 ,  C08G59/306 ,  C08G59/3254 ,  C08G59/70 ,  C08K5/00 ,  C08K5/0091 ,  C08K5/07 ,  C08K5/1515 ,  C08K5/5415 ,  C08L101/06 ,  C08L75/04 ,  C09D133/064 ,  C09D133/068 ,  C09D143/04 ,  C09D163/00 ,  C08L33/068 ,  C08L43/04

摘要： A resinous composition containing (A) a high molecular weight hydroxy compound having 2 or more hydroxy groups per molecule and having a number average molecular weight of 3,000 to 200,000, (B) a high molecule weight epoxy compound having 2 or more epoxy groups per molecule and having a number average molecular weight of 120 to 200,000, (C) a silane compound having one or more silicon-containing functional groups per molecule and (D) a chelate of aluminum, titanium or zirconium with a ligand exhibiting ketoenol tautomerism, can be cured at temperatures not exceeding 100.degree. C. and forms a desirable coating when cured.

公开(公告)号：US4972027A

公开(公告)日：1990-11-20

申请号：US271268

申请日：1988-11-15

申请人： Osamu Isozaki ,  Noboru Nakai ,  Shinji Sugiura ,  Satoru Ito ,  Seiji Takami

发明人： Osamu Isozaki ,  Noboru Nakai ,  Shinji Sugiura ,  Satoru Ito ,  Seiji Takami

IPC分类号： C08F2/08 ,  C08K5/00 ,  C09D143/04

CPC分类号： C08K5/0091 ,  C08F2/08 ,  C09D143/04

摘要： Disclosed is a composition curable at a low temperature and characterized in that the composition comprises:(a) a nonaqueous dispersion of a particulate polymer insoluble in an organic liquid and prepared by polymerizing a radical-polymerizable unsaturated monomer in the organic liquid in the presence of a dispersion stabilizer resin, the stabilizer resin being at least one of a copolymer comprising as its monomer components an oxirane-containing vinyl monomer and an alkoxysilane-containing vinyl monomer and a vinyl copolymer comprising as its monomer components a polysiloxane macromonomer and an oxirane-containing vinyl monomer,(b) a chelate compound admixed with a nonaqueous dispersion.

摘要翻译： 本发明公开了一种可在低温下固化的组合物，其特征在于该组合物包括：（a）不溶于有机液体的颗粒状聚合物的非水分散体，其通过在有机液体存在下使可自由基聚合的不饱和单体聚合而制备 分散稳定剂树脂，所述稳定剂树脂是包含作为其单体组分的含环氧乙烷的乙烯基单体和含烷氧基硅烷的乙烯基单体和乙烯基共聚物中的至少一种，其包含作为其单体组分的聚硅氧烷大分子单体和含环氧乙烷的乙烯基共聚物 乙烯基单体，（b）与非水分散体混合的螯合化合物。