公开(公告)号：US20070269699A1

公开(公告)日：2007-11-22

申请号：US11708599

申请日：2007-02-21

申请人： Chan-ho Pak ,  Seol-ah Lee ,  Hyuk Chang ,  Ji-rae Kim ,  Dae-jong Yoo ,  Sang-hoon Joo

发明人： Chan-ho Pak ,  Seol-ah Lee ,  Hyuk Chang ,  Ji-rae Kim ,  Dae-jong Yoo ,  Sang-hoon Joo

IPC分类号： H01M8/10

CPC分类号： H01M4/921 ,  H01M4/8657 ,  H01M4/8668 ,  H01M4/881 ,  H01M4/8814 ,  H01M4/8828 ,  H01M4/8875 ,  H01M4/8882 ,  H01M4/926 ,  H01M4/928

摘要： A catalyst coated membrane (CCM) comprising an anode catalyst layer having a first catalyst layer composed of a non-supported catalyst and a second catalyst layer composed of a supported catalyst, a cathode catalyst layer composed of a supported catalyst, and an electrolyte membrane interposed between the anode catalyst layer and a cathode catalyst layer, the first catalyst layer of the anode catalyst layer being disposed adjacent to the electrolyte membrane; a membrane electrode assembly (MEA) comprising the catalyst coated membrane; a method of preparing the membrane electrode assembly; and a fuel cell comprising the membrane electrode assembly, are provided. The CCM, which comprises a bilayered anode catalyst layer including the first catalyst layer composed of a non-supported catalyst and the second catalyst layer composed of a supported catalyst, exhibits reduced electrical resistance and interfacial resistance, and has increased catalyst availability. The use of the CCM and an MEA having the same results in a decrease in the interfacial resistance between the electrodes and the electrolyte membrane, a decrease in the amount of the catalyst used in the electrode catalyst layer, and a decrease in the thickness deviation in the electrode layers. The fuel cell employing the MEA exhibits maximal activity of the supported catalyst, and has improved cell characteristics such as output voltage, output density, efficiency, and the like.

摘要翻译： 一种催化剂涂覆膜（CCM），其包括具有由非负载型催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的阳极催化剂层，由负载型催化剂构成的阴极催化剂层和插入 在阳极催化剂层和阴极催化剂层之间，阳极催化剂层的第一催化剂层设置在电解质膜附近; 包含所述催化剂涂覆膜的膜电极组件（MEA） 一种制备膜电极组件的方法; 以及包括膜电极组件的燃料电池。 包含由非载体催化剂构成的第一催化剂层和由负载型催化剂构成的第二催化剂层的双层阳极催化剂层的CCM显示出降低的电阻和界面电阻，并且提高了催化剂的可利用性。 使用具有相同结果的CCM和MEA在电极和电解质膜之间的界面电阻降低，电极催化剂层中使用的催化剂量的减少以及厚度偏差的降低 电极层。 使用MEA的燃料电池显示出负载型催化剂的最大活性，并且具有改善的电池特性，例如输出电压，输出密度，效率等。

公开(公告)号：US20070042268A1

公开(公告)日：2007-02-22

申请号：US11443165

申请日：2006-05-31

申请人： Chan-ho Pak ,  Yeong-suk Choi ,  Hyuk Chang ,  Sang-hoon Joo

发明人： Chan-ho Pak ,  Yeong-suk Choi ,  Hyuk Chang ,  Sang-hoon Joo

IPC分类号： H01M4/60 ,  H01M4/62 ,  B01J31/00 ,  B01J21/18

CPC分类号： B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J35/10 ,  B01J35/1023 ,  B01J35/1047 ,  B01J35/1061 ,  B01J37/0018 ,  B01J37/084 ,  H01M4/90 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/08 ,  H01M8/086 ,  H01M8/10 ,  H01M8/1007 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A mesoporous carbon composite includes mesoporous carbon having mesopores; a conductive polymer coated on only an outer surface of the mesoporous carbon; and an organic electrolyte comprising a lithium salt and an organic solvent. The mesoporous carbon composite may be prepared by impregnating an ordered mesoporous silica (OMS) with a carbon precursor mixture comprising a carbon precursor, an acid, and a solvent; heat-treating and carbonizing the impregnated OMS to form an OMS-carbon composite; mixing the OMS-carbon composite with a monomer that forms a conductive polymer and a solvent to provide a surface of the OMS-carbon composite with the monomer that forms a conductive polymer; polymerizing the monomer to obtain a conductive polymer-coated OMS-carbon composite; removing the OMS from the conductive polymer-coated OMS-carbon composite to obtain a conductive polymer-coated mesoporous carbon; and doping the conductive polymer-coated mesoporous carbon with an organic electrolyte comprising a lithium salt and an organic solvent to form the mesoporous carbon composite. A supported catalyst contains the mesoporous carbon composite, and a fuel cell uses an electrode containing the mesoporous carbon composite.

摘要翻译： 介孔碳复合材料包括具有中孔的中孔碳; 只涂覆在介孔碳外表面上的导电聚合物; 以及包含锂盐和有机溶剂的有机电解质。 介孔碳复合材料可以通过用含碳前体，酸和溶剂的碳前体混合物浸渍有序介孔二氧化硅（OMS）来制备; 对浸渍的OMS进行热处理和碳化以形成OMS-碳复合材料; 将OMS-碳复合物与形成导电聚合物和溶剂的单体混合以提供OMS-碳复合材料与形成导电聚合物的单体的表面; 聚合单体以获得导电聚合物涂覆的OMS-碳复合材料; 从导电聚合物涂覆的OMS-碳复合材料中除去OMS以获得导电聚合物涂覆的介孔碳; 并用包含锂盐和有机溶剂的有机电解质掺杂导电聚合物涂覆的介孔碳以形成中孔碳复合物。 载体催化剂含有介孔碳复合材料，燃料电池使用含有介孔碳复合材料的电极。

公开(公告)号：US20060263288A1

公开(公告)日：2006-11-23

申请号：US11434113

申请日：2006-05-16

申请人： Chan-ho Pak ,  Sang-hoo Joo ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

发明人： Chan-ho Pak ,  Sang-hoo Joo ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

IPC分类号： C01B31/08 ,  B01J21/18 ,  H01M4/96

CPC分类号： B01J21/18 ,  B01J23/42 ,  B01J37/0018 ,  B01J37/084 ,  C01B32/00 ,  H01M4/8605 ,  H01M4/8807 ,  H01M4/885 ,  H01M4/8882 ,  H01M4/9083 ,  H01M4/92 ,  H01M4/921 ,  H01M4/926 ,  H01M4/96 ,  H01M8/086 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： Provided are a mesoporous carbon and a method of preparing the same, where the mesoporous carbon is prepared using phenanthrene as a carbon source and a mesoporous silica as a template. The mesoporous carbon has a significantly low plane resistance, which can be obtained without sacrificing other physical properties, and thus obtains a high conductivity and effectively transfers electrical energy. Accordingly, a fuel cell electrode or a fuel cell which is produced using the mesoporous carbon as a conductive material has high efficiency. Furthermore, the mesoporous carbon may be used in various electrochemical devices as a conductive material.

摘要翻译： 提供介孔碳及其制备方法，其中介孔碳是使用菲作为碳源和介孔二氧化硅作为模板制备的。 中孔碳具有显着低的平面电阻，其可以在不牺牲其他物理性能的情况下获得，从而获得高导电性并有效转移电能。 因此，使用介孔碳作为导电材料制造的燃料电池电极或燃料电池具有高效率。 此外，介孔碳可以用作各种电化学装置中的导电材料。

公开(公告)号：US07981826B2

公开(公告)日：2011-07-19

申请号：US12615514

申请日：2009-11-10

申请人： Chan-ho Pak ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

发明人： Chan-ho Pak ,  Hyuk Chang ,  Dae-jung Yoo ,  Seol ah Lee ,  Gongquan Sun ,  Luhua Jiang ,  Qin Xin

IPC分类号： B01J31/00 ,  B01J37/00 ,  B01J21/18 ,  B01J23/40 ,  B01J23/74 ,  C08F4/02 ,  C08F4/60 ,  H01M4/88 ,  H01M4/02 ,  H01M4/36 ,  H01M4/92 ,  H01M4/90

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

公开(公告)号：US07867941B2

公开(公告)日：2011-01-11

申请号：US11966266

申请日：2007-12-28

申请人： Sang Hoon Joo ,  Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

发明人： Sang Hoon Joo ,  Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim ,  Hyung-ik Lee

IPC分类号： B01J21/18 ,  C01B31/00 ,  H01M4/64

CPC分类号： B01J37/0018 ,  B01J21/18 ,  B01J35/1061 ,  B01J37/084 ,  C01B32/00 ,  H01M4/92 ,  H01M4/926 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A sulfur-containing mesoporous carbon that has mesopores with an average diameter of 2 to 10 nm, a method of preparing the same, a catalyst containing the mesoporous carbon as a catalyst support, and a fuel cell using the catalyst in which the sulfur-containing mesoporous carbon has a good affinity for and adhesion to catalyst particles so as to strongly support the catalyst particles due to the sulfur atoms substituting for carbons in an OMC carbon skeleton structure. The growth of metal catalyst particles is prevented when heat-treating the metal catalyst particles. The catalyst using the sulfur-containing mesoporous carbon can be applied to a fuel cell to prevent a reduction in catalytic activity due to increased particle size by an accumulation of catalyst particles. The catalyst containing the sulfur-containing mesoporous carbon as a catalyst support can be used to manufacture a fuel cell having an improved performance.

摘要翻译： 具有平均直径为2〜10nm的介孔的含硫中孔碳，其制备方法，含有介孔碳作为催化剂载体的催化剂，以及使用该催化剂的燃料电池，其中，含硫 中孔碳对催化剂颗粒具有良好的亲和性和粘附性，从而由于在OMC碳骨架结构中用硫原子代替碳而强烈地支持催化剂颗粒。 当对金属催化剂颗粒进行热处理时，可防止金属催化剂颗粒的生长。 使用含硫介孔碳的催化剂可以应用于燃料电池，以防止由于催化剂颗粒的积聚引起的粒度增加导致的催化活性降低。 含有含硫介孔碳作为催化剂载体的催化剂可用于制造具有改进性能的燃料电池。

公开(公告)号：US07867940B2

公开(公告)日：2011-01-11

申请号：US11334472

申请日：2006-01-19

申请人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

发明人： Chan-ho Pak ,  Hyuk Chang ,  Dae-Jong Yoo ,  Seol ah Lee ,  Gongguan Sun ,  Luhua Jiang ,  Qin Xin

IPC分类号： H01M4/02 ,  H01M4/88 ,  B01J31/00 ,  B01J21/18 ,  B01J23/00 ,  B01J23/40 ,  B01J23/74 ,  H01M4/36 ,  H01M4/92 ,  H01M4/90 ,  B01J37/00 ,  C08F4/02 ,  C08F4/60

CPC分类号： B82Y30/00 ,  B01J21/18 ,  B01J21/185 ,  B01J23/42 ,  B01J37/035 ,  B01J37/16 ,  H01M4/9083 ,  H01M4/926 ,  H01M8/1011 ,  H01M2008/1095 ,  Y02E60/523 ,  Y02P70/56

摘要： A method of preparing a supported catalyst includes dissolving a cation exchange polymer in alcohol to prepare a solution containing cation exchange polymer; mixing the cation exchange polymer containing solution with a catalytic metal precursor or a solution containing catalytic metal precursor; heating the mixture after adjusting its pH to a predetermined range; adding a reducing agent to the resultant and stirring the solution to reduce the catalytic metal precursor; mixing the resultant with a catalyst support; adding a precipitating agent to the resultant to form precipitates; and filtering and drying the precipitates. The method of preparing a supported catalyst can provide a highly dispersed supported catalyst containing catalytic metal particles with a reduced average size regardless of the type of catalyst support, which provides better catalytic activity than conventional catalysts at the same loading amount of catalytic metal.

摘要翻译： 制备负载型催化剂的方法包括将阳离子交换聚合物溶解在醇中以制备含有阳离子交换聚合物的溶液; 将含阳离子交换聚合物的溶液与催化金属前体或含有催化金属前体的溶液混合; 将其pH调节至预定范围后加热混合物; 向所得物中加入还原剂并搅拌溶液以还原催化金属前体; 将所得物与催化剂载体混合; 向所得物中加入沉淀剂形成析出物; 并过滤并干燥沉淀物。 制备负载型催化剂的方法可以提供高分散的载体催化剂，其含有平均尺寸较小的催化金属颗粒，而不管催化剂载体的类型如何，这在催化金属的相同负载量下提供比常规催化剂更好的催化活性。

公开(公告)号：US07585584B2

公开(公告)日：2009-09-08

申请号：US10601872

申请日：2003-06-24

申请人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

发明人： Won-bong Choi ,  Jae-uk Chu ,  Chan-ho Pak ,  Hyuk Chang

IPC分类号： H01M4/00

CPC分类号： H01M4/8605 ,  B82Y30/00 ,  B82Y40/00 ,  C01B32/162 ,  H01M4/9083 ,  H01M4/926 ,  H01M2008/1095 ,  Y10S977/70 ,  Y10S977/701 ,  Y10S977/72 ,  Y10S977/743 ,  Y10S977/843 ,  Y10S977/847

摘要： Carbon nanotubes for use in a fuel cell, a method for fabricating the same, and a fuel cell using the carbon nanotubes for its electrode are provided. The internal and external walls of the carbon nanotubes are doped with nano-sized metallic catalyst particles uniformly to a degree of 0.3-5 mg/cm2. The carbon nanotubes are grown over a carbon substrate using chemical vapor deposition or plasma enhanced chemical vapor deposition. Since the carbon nanotubes have a large specific surface area, and metallic catalyst particles are uniformly distributed over the internal and external walls thereof, the reaction efficiency in an electrode becomes maximal when the carbon nanotubes are used for the electrode of a fuel cell. The carbon nanotubes fabricated using the method can be applied to form a large electrode. The carbon nanotubes grown over the carbon substrate can be readily applied to an electrode of a fuel cell, providing economical advantages and simplifying the overall electrode manufacturing process. A fuel cell using as the carbon nanotubes for its electrode provides improved performance.

摘要翻译： 提供了用于燃料电池的碳纳米管，其制造方法和使用该碳纳米管作为其电极的燃料电池。 碳纳米管的内壁和外壁均匀掺杂有纳米尺寸的金属催化剂颗粒至0.3-5mg / cm2的程度。 使用化学气相沉积或等离子体增强化学气相沉积在碳衬底上生长碳纳米管。 由于碳纳米管具有大的比表面积，并且金属催化剂颗粒均匀地分布在其内壁和外壁上，所以当将碳纳米管用于燃料电池的电极时，电极中的反应效率最大。 使用该方法制造的碳纳米管可以应用于形成大电极。 生长在碳基板上的碳纳米管可以容易地应用于燃料电池的电极，提供经济的优点并简化整个电极的制造过程。 使用作为其电极的碳纳米管的燃料电池提供改进的性能。

公开(公告)号：US20090098442A1

公开(公告)日：2009-04-16

申请号：US12168284

申请日：2008-07-07

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

IPC分类号： B01J21/18 ,  C01B31/02 ,  H01M4/02

CPC分类号： B01J21/18 ,  B01J29/0308 ,  B01J35/1066 ,  B01J37/0018 ,  C01B32/00 ,  H01M4/9016 ,  H01M4/9083 ,  H01M8/1011 ,  Y02E60/523 ,  Y02P70/56

摘要： A hierarchical mesoporous carbon is provided in which a total volume of mesopores of the hierarchical mesoporous carbon is 80% or greater of a total volume of pores of the hierarchical mesoporous carbon; a volume of mesopores with a average diameter greater than 20 nm and no greater than 50 nm is 3% or greater of the total volume of the pores; and a volume of mesopores with a average diameter greater than 2 nm and no greater than 10 nm is 65% or greater of the total volume of the pores. The hierarchical mesoporous carbon, which also contains macropores, has an optimized mesoporous distribution characteristic, and has an increased total volume of pores, thereby having a significantly improved catalytic activity when used as a catalyst support. When such a supported catalyst including the hierarchical mesoporous carbon as a support is used in a fuel cell, supply of fuel and transporting of byproducts are facilitated.

摘要翻译： 提供了分级介孔碳，其中分层介孔碳的介孔的总体积为分级介孔碳的总体积的80％或更大; 平均直径大于20nm且不大于50nm的介孔的体积为孔的总体积的3％或更大; 并且平均直径大于2nm且不大于10nm的体积的介孔为孔的总体积的65％或更大。 还含有大孔的层状中孔碳具有优化的介孔分布特征，并且具有增加的孔体积，从而当用作催化剂载体时具有显着改善的催化活性。 当在燃料电池中使用包含分层介孔碳作为载体的这种负载型催化剂时，燃料的供给和副产物的输送变得容易。

公开(公告)号：US20070172721A1

公开(公告)日：2007-07-26

申请号：US11688537

申请日：2007-03-20

申请人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

发明人： Chan-ho Pak ,  Hyuk Chang ,  Ji-man Kim

IPC分类号： H01M4/96 ,  B01J21/18

CPC分类号： B01J35/1061 ,  B01J21/18 ,  B01J23/42 ,  B01J29/0308 ,  B01J37/06 ,  B01J37/084 ,  C01B32/00 ,  H01M4/9083 ,  H01M4/926

摘要： The present invention is related to a mesoporous carbon molecular sieve, which can be used as a catalyst carrier capable of improving the activity of a supported catalyst and a method of preparing the same. Additionally, the invention is related to a supported catalyst employing the mesoporous carbon molecular sieve as a carrier, and a fuel cell employing the supported catalyst. The mesoporous carbon molecular sieve has an average primary particle size of less than about 500 nm, an average mesopore size in the range of about 3 nm to about 6 nm, and a surface area in the range of about 500 m2/g to about 2000 m2/g.

摘要翻译： 本发明涉及可用作能够提高负载型催化剂的活性的催化剂载体的介孔碳分子筛及其制备方法。 另外，本发明涉及使用中孔碳分子筛作为载体的负载催化剂和使用负载型催化剂的燃料电池。 介孔碳分子筛的平均一次粒径小于约500nm，平均中孔尺寸在约3nm至约6nm的范围内，表面积在约500μm2范围内， /约至约2000m 2 / g。

公开(公告)号：US20070148515A1

公开(公告)日：2007-06-28

申请号：US11635031

申请日：2006-12-07

申请人： Seol-ah Lee ,  Hyuk Chang ,  Chan-ho Pak ,  Dae-jong Yoo

发明人： Seol-ah Lee ,  Hyuk Chang ,  Chan-ho Pak ,  Dae-jong Yoo

IPC分类号： H01M8/10 ,  C10L1/16

CPC分类号： H01M8/1009 ,  C10L1/10 ,  C10L1/12 ,  C10L1/1824 ,  C10L1/1881 ,  Y02P70/56

摘要： Provided is a fuel composition for a fuel cell including a first fuel which generates protons and electrons, and hydrogen gas. Also, provided is a fuel cell using the fuel composition. Using the fuel composition for a fuel cell, catalyst activation can be increased. Also, a fuel cell having high efficiency and excellent performance can be prepared using the fuel composition.

摘要翻译： 本发明提供一种燃料电池用燃料组合物，其包括产生质子和电子的第一燃料和氢气。 此外，提供了使用燃料组合物的燃料电池。 使用燃料电池用燃料组合物可以提高催化剂活化。 此外，可以使用燃料组合物来制备具有高效率和优异性能的燃料电池。