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21.发明授权Controlled gelation of hydrocarbon solutions containing interpolymer complexes 失效含有互聚物配合物的烃溶液的受控凝胶化
公开(公告)号：US4647603A
公开(公告)日：1987-03-03
申请号：US749020
申请日：1985-06-26
IPC分类号： B05D5/08 , C08J3/09 , C09K8/50 , C09K8/82 , E21B43/32 , C08J3/08 , C08L15/00 , C08L23/34 , C08L39/08
摘要： The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming two solvent systems of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent systems, a viscosity of both solvent systems being less than about 1,000 cps; dissolving an anionic polymer such as neutralized sulfonated polymer (water insoluble) in one of the solvent systems to form a first solution, and dissolving a cationic polymer such as a copolymer of vinyl pyridine, a concentration of the neutralized sulfonated polymer in the first solution being about 0.2 to about 10 weight percent, a concentration of the copolymer or vinyl pyridine in the second solution being about 0.2 to about 10 weight percent, a viscosity of both solutions being less than about 200 cps; mixing both solutions together to form a solution of an interpolymer complex of sulfonated polymer and vinyl pyridine polymer, and admixing or contacting said solution of said interpolymer complex with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent transferring from the organic liquid to the water phase, thereby causing the polymer containing phase to gel (i.e. thicken).
摘要翻译： 本发明涉及一种水性液体的增粘方法，其包括形成有机液体或油和极性助溶剂的两种溶剂体系的步骤，极性助溶剂小于溶剂体系的约15重量％， 两种溶剂体系的粘度小于约1,000cps; 将阴离子聚合物如中和的磺化聚合物（水不溶性）溶解在一种溶剂体系中以形成第一溶液，并将阳离子聚合物如乙烯基吡啶的共聚物溶解，将中和的磺化聚合物的浓度溶解在第一溶液中 约0.2至约10重量％，第二溶液中共聚物或乙烯基吡啶的浓度为约0.2至约10重量％，两种溶液的粘度小于约200cps; 将两种溶液混合在一起形成磺化聚合物和乙烯基吡啶聚合物的互聚物络合物的溶液，并将所述互聚物络合物的溶液与约5至约500体积％的水混合或接触，所述水与有机液体不混溶， 极性共溶剂从有机液体转移到水相，从而使含有相的聚合物凝胶化（即增稠）。
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公开(公告)号：US4584339A
公开(公告)日：1986-04-22
申请号：US625972
申请日：1984-06-29
CPC分类号： C10M173/02 , C08L57/04 , C09K3/18 , C09K8/588 , C10M2217/02 , C10M2221/02 , C10N2240/08 , C10N2250/02 , Y10S260/31 , Y10T137/0391
摘要： The present invention relates to aqueous solutions having dilatant properties in which the aqueous solution contains a polymer complex which is a water soluble polymer backbone containing an anionic comonomer and a copolymer of a water soluble polymer backbone containing a cationic comonomer.
摘要翻译： 本发明涉及具有膨胀特性的水溶液，其中水溶液含有聚合物配合物，其是含有阴离子共聚单体的水溶性聚合物主链和含有阳离子共聚单体的水溶性聚合物主链的共聚物。
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公开(公告)号：US4489180A
公开(公告)日：1984-12-18
申请号：US560515
申请日：1983-12-12
CPC分类号： C08J3/03 , B63B1/38 , C09K3/00 , C09K8/035 , C09K8/588 , C08J2300/10 , C10M2201/02 , C10M2217/024 , C10M2217/06 , C10M2221/02 , C10N2240/06 , C10N2240/08 , C10N2250/02 , Y02T70/122 , Y10S260/31 , Y10S525/919
摘要： The present invention discloses a class of water soluble complex polymers of relatively low molecular weight, which have been found to be improved drag reducing agents. These complex polymers are a mixture of a cationic copolymer having a water soluble polymer backbone and an anionic copolymer having a water soluble polymer backbone. The solutions of these complex polymers are improved drag reducing agents for aqueous systems at low concentrations (i.e., 10 to 500 ppm) relative to individual solutions of the copolymers which make upon the polymer complex.
摘要翻译： 本发明公开了一类相对低分子量的水溶性复合聚合物，已被发现是改进的减阻剂。 这些复合聚合物是具有水溶性聚合物主链和具有水溶性聚合物主链的阴离子共聚物的阳离子共聚物的混合物。 这些复合聚合物的溶液相对于在聚合物复合物上形成的共聚物的各个溶液，在低浓度（即10至500ppm）的水性体系中是改进的减阻剂。
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公开(公告)号：US4330447A
公开(公告)日：1982-05-18
申请号：US222484
申请日：1981-01-05
CPC分类号： C08L23/32
摘要： This invention relates to a blend composition of a metal neutralized sulfonated polymer, a preferential plasticizer and polydialkylsiloxane, wherein the blend composition has improved melt flow and a lower coefficient of friction while substantially maintaining physical properties as compared to the blend of either the metal neutralized sulfonated polymer and preferential plasticizer or the metal neutralized sulfonated polymer itself.
摘要翻译： 本发明涉及金属中和磺化聚合物，优选增塑剂和聚二烷基硅氧烷的共混组合物，其中共混物组合物具有改善的熔体流动性和较低的摩擦系数，同时与金属中和磺化的共混物相比基本保持物理性能 聚合物和优选增塑剂或金属中和的磺化聚合物本身。
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25.发明授权Halogenated isobutylene-based copolymers having enhanced viscosity and thermoplastic compositions thereof 有权具有增强的粘度和热塑性组合物的卤化异丁烯基共聚物公开(公告)号：US07226962B2
公开(公告)日：2007-06-05
申请号：US10476541
申请日：2002-04-30
申请人： Andy H. Tsou , Hsien-Chang Wang , Kenneth O. McElrath , Ilan Duvdevani , Michael K. Lyon , Mun Fu Tse
发明人： Andy H. Tsou , Hsien-Chang Wang , Kenneth O. McElrath , Ilan Duvdevani , Michael K. Lyon , Mun Fu Tse
CPC分类号： C08K9/04 , C08L21/00 , C08L23/22 , C08L101/00 , C08L23/28 , C08L2666/02
摘要： The invention provides a method for increasing the viscosity of halogenated (brominated) elastomeric copolymers of a C4 to C7 isomonoolefin (isobutylene) and a para-alkylstryrene (p-methylstyrene) by mixing the copolymer with a silica or clay particulate filler which has been contacted with an aminosilane containing at least one C1 to C4 alkoxy group and at least one primary, secondary or tertiary amine group. The resulting elastomer compositions are used to prepare thermoplastic elastomer blend compositions, containing more finely dispersed elastomers which results in compositions having improved mechanical properties.
摘要翻译： 本发明提供了一种用于提高C 4 O 4的异氰酸酯（异丁烯）和对 - 烷基苯乙烯（对甲基苯乙烯）的卤代（溴化）弹性共聚物的粘度的方法 ）与通过与含有至少一个C 1至C 4烷氧基的氨基硅烷接触的二氧化硅或粘土颗粒填料混合共聚物，和至少一种伯， 仲胺或叔胺基。 所得的弹性体组合物用于制备含有更细的分散弹性体的热塑性弹性体共混组合物，其导致具有改进的机械性能的组合物。
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公开(公告)号：US06626219B2
公开(公告)日：2003-09-30
申请号：US09736524
申请日：2000-12-13
申请人： Donald S. Tracey , Ilan Duvdevani , Hsien-Chang Wang , Takashi Takeda , Shinichiro Yamashita , Arthur E. Parente , Utpal Paul
发明人： Donald S. Tracey , Ilan Duvdevani , Hsien-Chang Wang , Takashi Takeda , Shinichiro Yamashita , Arthur E. Parente , Utpal Paul
IPC分类号： B60C502
CPC分类号： B60C5/02 , B60C1/00 , B60C1/0008 , C08L21/00 , C08L23/22 , C08L23/283 , C08L2312/00 , Y10T152/10855 , C08L2666/04 , C08L2666/06
摘要： Halogenated isobutylene-co-paramethylstyrene polymer, preferably brominated isobutylene-co-paramethylstyrene polymer (BIMS) and blends thereof, preferably blends of isobutylene based rubber, show improved heat resistance versus butyl inner tube compositions and retain the superior barrier properties of butyl inner tube compositions versus inner tube compositions with butyl/EP blends.
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公开(公告)号：USH1077H
公开(公告)日：1992-07-07
申请号：US527232
申请日：1990-05-21
摘要： The present invention relates to a process for the viscosification of an aqueous liquid which includes the steps of forming a solvent system of an organic liquid or oil and a polar cosolvent, the polar cosolvent being less than about 15 weight percent of the solvent system, a viscosity of the solvent system being less than about 1,000 cps; forming an interpolymer complex of neutralized sulfonated polymer (water insoluble) and copolymer of styrene/vinylpyridine in the solvent system to form a solution, a concentration of the water insoluble interpolymer complex polymer in the solution being about 0.01 to about 0.5 weight percent, a viscosity of the solution being less than about 200 cps; and admixing or contacting said solution with about 5 to about 500 volume percent water, the water being immiscible with the organic liquid and the polar cosolvent and interpolymer complex transferring from the organic liquid to the water phase, thereby causing the water phase to gel (i.e., thicken). The large increase in viscosity of the aqueous phase is directly attributed to the formation of a large number of minute water-filled particles dispersed in the continuous aqueous phase.
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公开(公告)号：USH818H
公开(公告)日：1990-09-04
申请号：US34493
申请日：1987-04-03
IPC分类号： C08L23/32
CPC分类号： C08L23/32
摘要： This invention relates to extrusion and injection moldable type elastomeric compositions having a viscosity at 200.degree. C. at 0.73 sec.sup.-1 of about 8.times.10.sup.4 to about 8.times.10.sup.6 poises. The compositions used for elastomeric articles include neutralized sulfonated co- and terpolymers of octene-1/ethylene/ENB or sulfonated terpolymers of hexene-1/ethylene/ENB, about 15 to about 200 parts by weight of a non-polar process oil per 100 parts of polymer; about 50 to about 300 parts by weight of a filler per 100 parts of polymer; and a preferential plasticizer at about 1 to about 50 parts by weight per 100 parts of the sulfonated elastomeric polymer. The composition may also include a crystalline polyolefinic thermoplastic at less then about 100 parts per hundred by weight.These blend compositions can be readily processed due to their superior rheological properties on conventional plastic fabrication equipment into elastomeric articles having excellent physical properties and desirable rubbery characteristics.
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29.发明授权
公开(公告)号：US4904722A
公开(公告)日：1990-02-27
申请号：US788963
申请日：1985-10-18
摘要： A method for controlling the viscosity of organic liquids, said organic liquid having a solubility parameter of less than 9.5, a viscosity, as measured at 25.degree. C., of less than 200 centipoises and said organic liquid is selected from the group consisting of mineral oils, synthetic oils, naphthanes, alkanes, cycloalkanes and aromatics and mixtures thereof, which comprises incorporating in said organic liquid about 0.01 to 20 grams of polymer complex per 100 ml. of said organic liquid, said polymer complex being formed "in situ" in said organic liquid or dissolved in said organic liquid, said complex being comprised of polymer A, containing about 4 meq. to 500 meq. of neutralized sulfonate groups, and polymer B, containing basic nitrogen groups, both functional groups being present at a level of from about 4 to 500 meq. per 100 g. of polymer, wherein polymer B has the formula: ##STR1## wherein x is about 50.0 to 99.8 weight percent and y is about 0.2 to about 50.0 weight percent, wherein said sulfonate groups of said polymer A being neutralized with basic compounds selected from the group consisting of transition elements, said polymer A having a polymeric backbone substantially soluble in said organic liquid and said polymer having a molecular weight of about 1,000 to 10,000,000.
摘要翻译： 一种用于控制有机液体的粘度的方法，所述有机液体的溶解度参数小于9.5，在25℃下测得的小于200厘泊的粘度和所述有机液体选自矿物质 油，合成油，萘烷，烷烃，环烷烃和芳族化合物及其混合物，其包括在每一100ml中在所述有机液体中加入约0.01至20克聚合物复合物。 的所述有机液体，所述聚合物复合物在所述有机液体中“原位”形成或溶解在所述有机液体中，所述复合物由聚合物A组成，含有约4meq。 至500毫克 的中和磺酸盐基团和含有碱性氮基团的聚合物B，两个官能团的存在量为约4至500meq。 每100克 的聚合物，其中聚合物B具有下式：其中x为约50.0至99.8重量％，y为约0.2至约50.0重量％，其中所述聚合物A的所述磺酸盐基团用碱性化合物中和，所述碱性化合物选自 由过渡元素组成，所述聚合物A具有基本上可溶于所述有机液体的聚合物骨架，所述聚合物的分子量为约1,000至10,000,000。
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公开(公告)号：USH363H
公开(公告)日：1987-11-03
申请号：US808117
申请日：1985-12-12
申请人： Ilan Duvdevani , Robert D. Lundberg
发明人： Ilan Duvdevani , Robert D. Lundberg
CPC分类号： C10L1/2462 , C08F8/36 , C08F8/44 , C08F210/18
摘要： A method for improving the antimisting properties of an organic liquid which comprises the step of dissolving about 0.1 to about 3.0 weight percent of a neutralized sulfonated polymer in such organic liquid, having a solubility parameter of less than 9, wherein said neutralized sulfonated polymer has about 5 to about 200 meq. of pendant sulfonate groups per 100 grams of polymer and about 90.0 to 100% of said sulfonate groups are neutralized, wherein the solution of the organic liquid and the neutralized sulfonated polymer has an approximate polymer concentration, C.sub.A, which can be characterized by the formula: ##EQU1## wherein [.eta.] is the intrinsic viscosity of said solution and the polymer concentration range is 0.1 times to 10 times C.sub.A.
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