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    Catalyst and support, their methods of preparation, and processes employing same
    22.
    发明授权
    Catalyst and support, their methods of preparation, and processes employing same 失效
    催化剂和载体，它们的制备方法和使用它们的方法

    公开(公告)号：US4495062A

    公开(公告)日：1985-01-22

    申请号：US485185

    申请日：1983-04-15

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick

    IPC: B01J21/02 ,  B01J21/12 ,  B01J23/28 ,  B01J27/16 ,  B01J35/10 ,  B01J37/10 ,  C10G45/04 ,  C10G47/12 ,  C10G45/08

    CPC classification number: B01J37/10 ,  B01J21/02 ,  B01J21/12 ,  B01J23/28 ,  B01J27/16 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/108 ,  C10G2300/107

    Abstract: A catalyst support is prepared from a composite comprising two or more inorganic oxides by forming the composite into a shaped support material having at least 0.8 cc/gm of its pore volume in pore diameters of 0 nm (0 .ANG.) to 120 nm (1,200 .ANG.) and at least 0.1 cc/gm of its pore volume in pore diameters of 120 nm (1,200 .ANG.) to 5,000 nm (50,000 .ANG.) and heating said shaped support material in the presence of steam at sufficient elevated temperature, steam pressure, and time period to increase the average pore diameter of said shaped support in the absence of any appreciable reduction in pore volume. The inorganic oxide composite is selected from the group consisting of a mixture of alumina and silica; a mixture of alumina, silica, and oxides of phosphorus; a mixture of alumina and oxides of phosphorus; a mixture of alumina and boria; a mixture of alumina, boria and oxides of phosphorus; and a mixture of alumina, magnesia, and oxides of phosphorus, the oxides of phosphorus being calculated as P.sub.2 O.sub.5 and the quantities being based upon the weight of the composite.A catalyst is prepared by impregnating the steam-treated support with at least one hydrogenating metal.The catalyst can be used suitably in hydrocarbon conversion processes, such as a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals.

    Abstract translation: 催化剂载体由包含两种或更多种无机氧化物的复合材料制备，通过将复合材料形成为孔径为0nm（0安格姆）至120纳米（1,200安格姆）的孔体积至少为0.8cc /克的成形载体材料 ）和至少0.1cc / gm的孔径为120nm（1,200安格姆）至5,000nm（50,000安培）的孔体积，并在蒸汽存在下在足够高的温度，蒸汽压力和时间下加热所述成形的支撑材料 在没有任何明显的孔体积减小的情况下增加所述成形载体的平均孔径。 无机氧化物复合材料选自氧化铝和二氧化硅的混合物; 氧化铝，二氧化硅和磷的氧化物的混合物; 氧化铝和磷的氧化物的混合物; 氧化铝和氧化硼的混合物; 氧化铝，氧化硼和磷的氧化物的混合物; 以及氧化铝，氧化镁和磷的氧化物的混合物，磷的氧化物计算为P 2​​ O 5，其数量基于复合材料的重量。 通过用至少一种氢化金属浸渍蒸汽处理的载体来制备催化剂。 催化剂可以适用于烃转化方法，例如含有沥青质的烃物流和大量金属的加氢脱金属的方法。

    Three-catalyst process for the hydrotreating of heavy hydrocarbon streams
    23.
    发明授权
    Three-catalyst process for the hydrotreating of heavy hydrocarbon streams 失效
    用于加氢处理重质烃流的三催化过程

    公开(公告)号：US4431525A

    公开(公告)日：1984-02-14

    申请号：US371815

    申请日：1982-04-26

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick

    IPC: B01J35/10 ,  C10G45/04 ,  C10G45/08 ,  C10G65/04

    CPC classification number: B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  C10G2300/107

    Abstract: There is disclosed a process for hydrotreating a heavy hydrocarbon stream containing metals, asphaltenes, nitrogen compounds, and sulfur compounds to reduce the contents of these contaminants. The process comprises contacting said stream in the presence of hydrogen and under suitable hydrotreating conditions in sequence with a first catalyst in a first reaction zone, a second catalyst in a second reaction zone, and a third catalyst in a third reaction zone. The first catalyst comprises a Group VIB metal and/or a Group VIII metal on a porous inorganic oxide support; the second catalyst consists essentially of at least one hydrogenation metal selected from Group VIB deposed on a support material comprising alumina; and the third catalyst comprises a hydrogenating component comprising molybdenum, chromium, and cobalt on a large-pore, catalytically-active alumina. Each catalyst has specific physical properties.

    Abstract translation: 公开了一种加氢处理含有金属，沥青质，氮化合物和硫化合物的重质烃流的方法，以减少这些污染物的含量。 该方法包括在氢气存在下，在合适的加氢处理条件下，将第一催化剂在第一反应区，第二反应区中的第二催化剂和第三反应区中的第三催化剂依次接触。 第一催化剂在多孔无机氧化物载体上包含VIB族金属和/或Ⅷ族金属; 第二催化剂基本上由至少一种氢化金属组成，所述氢化金属选自ⅤB组，其包含氧化铝的载体材料; 并且第三催化剂包含在大孔催化活性氧化铝上的包含钼，铬和钴的氢化组分。 每种催化剂都具有特定的物理性质。

    Hydrotreating catalyst and process
    26.
    发明授权
    Hydrotreating catalyst and process 失效
    加氢处理催化剂和工艺

    公开(公告)号：US4454026A

    公开(公告)日：1984-06-12

    申请号：US387332

    申请日：1982-06-11

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick

    IPC: B01J23/28 ,  B01J23/88 ,  B01J27/16 ,  B01J35/10 ,  B01J37/10 ,  C10G45/04 ,  C10G49/04

    CPC classification number: C10G49/04 ,  B01J23/28 ,  B01J23/88 ,  B01J27/16 ,  B01J35/10 ,  B01J37/10 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  B01J35/1066 ,  B01J35/109 ,  C10G2300/107

    Abstract: Hydrotreating catalysts comprise a hydrogenating component and a support comprising at least one porous refractory inorganic oxide, said catalyst having BET surface area of 150 to about 190 m.sup.2 /g, bulk density of at least about 0.2 g/cc, total pore volume of at least about 0.9 cc/g with mercury penetration pore volume of at least about 0.1 cc/g in macropores with radii of 600 to 25,000 .ANG., such surface area, pore size distribution and total pore volume being effective to give an average pore diameter of at leat 230 .ANG. calculated as 4V/A. Hydrotreating process comprises contacting a hydrocarbon feed with hydrogen in the presence of the aforesaid catalyst under hydrotreating conditions. The catalyst and process are particularly useful in hydrotreating feeds comprising high metals or high metals and sulfur content materials.

    Abstract translation: 加氢处理催化剂包括氢化组分和包含至少一种多孔耐火无机氧化物的载体，所述催化剂的BET表面积为150至约190m 2 / g，堆积密度为至少约0.2g / cc，总孔体积至少为 大约0.9cc / g，具有至少约0.1cc / g的汞渗透孔体积，半径为600至25,000的大孔，这种表面积，孔径分布和总孔体积有效地给出了平均孔径 230 ANGSTROM计算为4V / A。 加氢处理方法包括在加氢处理条件下在上述催化剂存在下使烃进料与氢气接触。 催化剂和方法在加氢处理包含高金属或高金属和硫含量材料的进料中特别有用。

    Catalyst and support, their methods of preparation, and processes employing same
    27.
    发明授权
    Catalyst and support, their methods of preparation, and processes employing same 失效
    催化剂和载体，它们的制备方法和使用它们的方法

    公开(公告)号：US4395328A

    公开(公告)日：1983-07-26

    申请号：US274553

    申请日：1981-06-17

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick

    IPC: B01J21/02 ,  B01J21/12 ,  B01J27/16 ,  B01J35/10 ,  B01J37/10 ,  C10G45/04 ,  B01J27/18 ,  C10G45/08 ,  C10G45/26

    CPC classification number: B01J37/10 ,  B01J21/02 ,  B01J21/12 ,  B01J27/16 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1047 ,  B01J35/1061 ,  C10G2300/107

    Abstract: A catalyst support is prepared from a composite comprising alumina and one or more oxides of phosphorous by forming the composite into a shaped support material having at least 0.8 cc/gm of its pore volume in pores having diameters of 0 nm (0 A) to 120 nm (1,200 A) and at least 0.1 cc/gm of its pore volume in pores having diameters of 120 nm (1,200 A) to 5,000 nm (50,000 A) and heating said shaped support material in the presence of steam at sufficient elevated temperature, steam pressure, and time period to increase the average pore diameter of said shaped support in the absence of any appreciable reduction in pore volume.A catalyst is prepared by impregnating the steam-treated support with at least one hydrogenating metal.The catalyst can be used suitably in hydrocarbon conversion processes, such as a process for the hydrodemetallization of a hydrocarbon stream containing asphaltenes and a substantial amount of metals.

    Abstract translation: 催化剂载体由包含氧化铝和一种或多种磷的氧化物的复合材料制备，通过将复合材料形成成直径为0nm（0A）至120的孔的孔体积至少为0.8cc / gm的成形载体材料 （1200A）和在直径为120nm（1,200A）至5,000nm（50,000）的孔中的孔体积为至少0.1cc / gm，并且在足够高的温度下在蒸汽存在下加热所述成形的载体材料， 蒸汽压力和时间段，以在没有任何明显的孔体积减小的情况下增加所述成形支撑件的平均孔径。 通过用至少一种氢化金属浸渍蒸汽处理的载体来制备催化剂。 催化剂可以适用于烃转化方法，例如含有沥青质的烃物流和大量金属的加氢脱金属的方法。

    Hydrotreating process
    28.
    发明授权
    Hydrotreating process 失效
    加氢处理

    公开(公告)号：US4278566A

    公开(公告)日：1981-07-14

    申请号：US139231

    申请日：1980-04-11

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick ,  P. Donald Hopkins

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick ,  P. Donald Hopkins

    IPC: B01J21/12 ,  B01J23/88 ,  B01J23/887 ,  B01J35/10 ,  C10G45/08 ,  C10G45/38

    CPC classification number: B01J23/8878 ,  B01J35/10 ,  C10G45/08 ,  B01J21/12 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061

    Abstract: A process for hydrotreating a hydrocarbon stream to remove nitrogen and sulfur which process comprises contacting a hydrocarbon stream comprising a stream selected from petroleum distillate, tar sands distillate, and shale oil, with hydrogen and a catalyst comprising a porous refractory inorganic oxide and deposited thereon hydrogenation components comprising chromium, molybdenum and at least one Group VIII metal, said catalyst having a pore volume distribution comprising 20-50% of pore volume in pores with diameters of 0-50 Angstrom units, 30-70% of pore volume in pores with diameters of 50-100 Angstrom units, 0-20% of pore volume in pores with diameters of 100-150 Angstrom units, and 0-10% of pore volume in pores with diameters greater than 150 Angstrom units.

    Abstract translation: 一种用于加氢处理烃流以除去氮和硫的方法，该方法包括使包含选自石油馏出物，焦油砂馏出物和页岩油的物流的烃流与氢气和包含多孔耐火无机氧化物的催化剂接触，并在其上沉积氢化 包含铬，钼和至少一种第Ⅷ族金属的组分，所述催化剂的孔体积分布包括孔直径为0-50埃单位的孔体积的20-50％，直径为孔的孔体积的30-70％ 50-100埃单位孔径，直径100-150埃单位孔隙中孔体积的0-20％，直径大于150埃的孔隙孔体积的0-10％。

    Process for demetallation and desulfurization of heavy hydrocarbons
    29.
    发明授权
    Process for demetallation and desulfurization of heavy hydrocarbons 失效
    重质烃脱金属脱硫工艺

    公开(公告)号：US4212729A

    公开(公告)日：1980-07-15

    申请号：US928141

    申请日：1978-07-26

    Applicant: Albert L. Hensley, Jr. ,  Leonard M. Quick

    Inventor： Albert L. Hensley, Jr. ,  Leonard M. Quick

    IPC: B01J21/04 ,  B01J23/24 ,  B01J23/28 ,  B01J23/40 ,  B01J23/64 ,  B01J23/74 ,  B01J23/84 ,  B01J27/02 ,  B01J35/10 ,  C10G45/04 ,  C10G45/08 ,  C10G65/04 ,  C10G23/02

    CPC classification number: B01J23/24 ,  B01J23/28 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/108 ,  B01J21/04 ,  C10G2300/107

    Abstract: Disclosed is a two-stage catalytic process for hydrodemetallation and hydrodesulfurization of heavy hydrocarbon streams containing asphaltenes and a substantial amount of metals. The first stage of this process comprises contacting the feedstock in a first reaction zone with hydrogen and a demetallation catalyst comprising hydrogenation metal selected from Group VIB and/or Group VIII deposed on a large-pore, high surface area inorganic oxide support; the second stage of the process comprises contacting the effluent from the first reaction zone with a catalyst consisting essentially of hydrogenation metal selected from Group VIB deposed on a smaller pore, catalytically active support comprising alumina, said second stage catalyst having a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, having a majority of its pore volume in pore diameters within the range of about 80 A to about 130 A, and the catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.9 cc/gm.

    Abstract translation: 公开了用于含有沥青质和大量金属的重质烃流的加氢脱金属和加氢脱硫的两阶段催化方法。 该方法的第一阶段包括使第一反应区中的原料与氢气和脱金属催化剂接触，所述脱金属催化剂包含选自分布在大孔，高表面积无机氧化物载体上的VIB族和/或VIII族的氢化金属; 该方法的第二阶段包括将来自第一反应区的流出物与基本上由选自ⅥB组合的氢化金属组成的催化剂接触，所述组VIB位于包含氧化铝的较小孔催化活性载体上，所述第二阶段催化剂的表面积在该范围内 约150m 2 / g至约300m 2 / gm，其孔径的大部分孔径在约80至约130的范围内，并且催化剂的孔体积在约0.4cc / gm至约0.9cc / gm。

    Process for the hydrotreating of heavy hydrocarbon streams
    30.
    发明授权
    Process for the hydrotreating of heavy hydrocarbon streams 失效
    重烃流加氢处理工艺

    公开(公告)号：US4188284A

    公开(公告)日：1980-02-12

    申请号：US967432

    申请日：1978-12-07

    Applicant: Leonard M. Quick ,  Albert L. Hensley, Jr.

    Inventor： Leonard M. Quick ,  Albert L. Hensley, Jr.

    IPC: B01J23/28 ,  B01J23/88 ,  B01J23/887 ,  B01J35/10 ,  C10G45/04 ,  C10G23/02

    CPC classification number: B01J23/8878 ,  B01J23/28 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1042 ,  B01J35/1061 ,  B01J35/1085 ,  C10G2300/107

    Abstract: The process comprises contacting a heavy hydrocarbon stream containing metals and asphaltenes to reduce the contents of nitrogen compounds, sulfur compounds, metals and asphaltenes in the hydrocarbon stream under suitable conditions and in the presence of hydrogen with a catalyst comprising a hydrogenating component consisting essentially of molybdenum and chromium, their oxides, their sulfides, or mixtures thereof on a large-pore, catalytically active alumina. The catalyst has a pore volume within the range of about 0.4 cc/gm to about 0.8 cc/gm, a surface area within the range of about 150 m.sup.2 /gm to about 300 m.sup.2 /gm, and an average pore diameter within the range of about 100 A to about 200 A.

    Abstract translation: 该方法包括使含有金属和沥青质的重质烃流接触以在合适的条件下和在氢的存在下，使烃催化剂中的氮化合物，硫化合物，金属和沥青质的含量降低，所述催化剂包含基本上由钼组成的氢化组分 和铬，它们的氧化物，它们的硫化物或其混合物在大孔催化活性氧化铝上。 催化剂的孔体积在约0.4cc / gm至约0.8cc / gm范围内，表面积在约150m 2 / gm至约300m 2 / gm范围内，平均孔径在 约100 A至约200 A.

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