摘要:
A method for manufacturing ceramic/metal or ceramic/ceramic composite articles is disclosed. The articles can be useful for the production of aluminum in fused salt electrolysis cells, as armour plates for the protection against projectiles, cutting tools, or in abrasion resistance applications. The temperature slope of the process if optimized such that one of the reactants in the manufacturing proceeds through peritectic decomposition at a heating rate of low temperature increase for desirably uniform temperature distribution over the reaction mixture. Then the temperature increase is greatly elevated to obtain a reaction sintering condition for avoiding grain growth of undesired reaction products. Elevated temperature reaction sintering conditions can be maintained to decompose undesired components before they are entrapped by the reaction product.
摘要:
A composite for protection against armor-piercing projectiles is disclosed. The composite can be a ceramic composite which may be utilized alone or with other materials, e.g., a metallic or plastic base or substrate layer. Composites of AlN with TiB.sub.2, SiC, B.sub.4 C or their mixtures are utilized. These ceramic composites can be prepared by hot pressing, reaction hot pressing, hot isostatic pressing or pressureless sintering. The composite may have well dispersed grains for at least one component, which grains can be interconnected with grains of the second component, and the grains may be of a size less than about five microns. The composite in layer form can have a metallic cover layer.
摘要:
An environmental compensation apparatus for an electrochemical fuel cell assembly, wherein a compressible material is dispersed within a coolant flow of the fuel cell assembly and is utilized to compensate for the expansion of the coolant when said fuel cell assembly is subjected to harsh environmental conditions. The compressible material is formed as a plurality of either polymeric or elastomer microspheres, each microsphere having a diameter larger than the pores of an anode or cathode flow field plate, yet smaller than the diameter of a coolant channel.
摘要:
A battery assembly of the consumable metal anode type has now been constructed for ready assembly as well as disassembly. In a non-conductive and at least substantially inert cell body, space is provided for receiving an open-structured, non-consumable anode cage. The cage has an open top for facilitating insertion of an anode. A modular cathode is used, comprising a peripheral current conductor frame clamped about a grid reinforced air cathode in sheet form. The air cathode may be double gridded. The cathode frame can be sealed, during assembly, with electrolyte-resistant-sealant as well as with adhesive. The resulting cathode module can be assembled outside the cell body and readily inserted therein, or can later be easily removed therefrom.
摘要:
In an aluminium reduction cell including a cell lining and embedded therein at least one cathode current collector including a high temperature section comprising an electrically conducting refractory material such as titanium diboride, generally in conjunction with molten aluminium metal, corrosion is a problem. The invention provides a substance to protect the collector section. The substance may be a liquid impermeable layer e.g. particulate material impregnated with a molten fluoride-or chloride-containing salt mixture; for a getter such as particulate aluminium to react chemically with gaseous corrosive species. Combinations of these substances may be used, optionally in conjunction with a solid layer such as an alumina or aluminium metal tube.
摘要:
An aluminium reduction cell includes an anode 10, electrolyte 12, a cathode 14, a potlining 16 which may be of alumina and cathode current collectors embedded therein. The collectors include a section comprising a major proportion by volume of bodies 22, e.g. of titanium diboride or a TiB.sub.2 /Al cermet, joined or surrounded by aluminium, the section being so positioned that the aluminium is at least partly fluid when the cell is in operation. The bodies, which are preferably close-packed, may be cubic or cuboid or in the form of sheets or thin slabs arranged with their major faces parallel to one another and to the axis of the collector section. The collectors show good electrical conductivity together with satisfactory resistance to magnetic stirring and impact and transverse forces.