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公开(公告)号:US08592806B2
公开(公告)日:2013-11-26
申请号:US13203299
申请日:2010-02-25
IPC分类号: H01L35/24
CPC分类号: C07D209/34 , C07D403/10 , C07D403/14 , H01L51/506
摘要: The invention relates to novel quinone compounds and to the use thereof as dopants in organic electronics.
摘要翻译: 本发明涉及新的醌化合物及其作为有机电子学中掺杂剂的用途。
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公开(公告)号:US20120283432A1
公开(公告)日:2012-11-08
申请号:US13406016
申请日:2012-02-27
申请人: Neil Gregory PSCHIRER , Felix Eickemeyer , Jan Schöneboom , Jianqiang Qu , Martin Könemann , Klaus Müllen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
发明人: Neil Gregory PSCHIRER , Felix Eickemeyer , Jan Schöneboom , Jianqiang Qu , Martin Könemann , Klaus Müllen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
IPC分类号: C07D311/78 , C07D491/16 , C07D417/10 , C07D405/10 , C07D417/14 , C07D491/06 , C07D471/16
CPC分类号: H01G9/2031 , C07D221/18 , C07D311/78 , C07D311/92 , C07D405/04 , C07D405/12 , C07D409/14 , C07D413/04 , C07D417/04 , C07D417/14 , C07D471/06 , C07D491/06 , C09B5/62 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1088 , H01G9/2059 , H01L51/0053 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要: Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译: 使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是自由基-L-NR1R2(y1)-L-Z-R3(y2)另一个基团氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R1,R2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
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公开(公告)号:US08231809B2
公开(公告)日:2012-07-31
申请号:US12093081
申请日:2006-11-06
申请人: Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoeneboom , Jianqiang Qu , Martin Koenemann , Klaus Muellen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
发明人: Neil Gregory Pschirer , Felix Eickemeyer , Jan Schoeneboom , Jianqiang Qu , Martin Koenemann , Klaus Muellen , Chen Li , Andreas Herrmann , Peter Erk , Gero Nordmann , Alfred Kuhn , Anders Hagfeldt , Tomas Edvinsson
IPC分类号: H01C13/00 , H01L31/00 , C07D221/18
CPC分类号: H01G9/2031 , C07D221/18 , C07D311/78 , C07D311/92 , C07D405/04 , C07D405/12 , C07D409/14 , C07D413/04 , C07D417/04 , C07D417/14 , C07D471/06 , C07D491/06 , C09B5/62 , C09K11/06 , C09K2211/1007 , C09K2211/1011 , C09K2211/1014 , C09K2211/1029 , C09K2211/1033 , C09K2211/1037 , C09K2211/1044 , C09K2211/1048 , C09K2211/1059 , C09K2211/1088 , H01G9/2059 , H01L51/0053 , H01L51/006 , H01L51/0067 , H01L51/0068 , H01L51/0069 , H01L51/0071 , H01L51/4226 , Y02E10/542 , Y02E10/549
摘要: Rylene derivatives useful in solar cells, where the rylene derivatives are represented by formula I where each X group is joined to form a six-membered ring, one Y group is an amine group, one Y group is a hydrogen atom, each R group is an alkoxy group, m is 1, n is 4, and P is 0.
摘要翻译: 可用于太阳能电池的二烯衍生物,其中二烯衍生物由式I表示,其中每个X基团连接形成六元环,一个Y基团是胺基团,一个Y基团是氢原子,每个R基团是 烷氧基,m是1,n是4,P是0。
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公开(公告)号:US08071775B2
公开(公告)日:2011-12-06
申请号:US11994719
申请日:2006-07-06
IPC分类号: C07D471/08 , H01L51/50
CPC分类号: C07D493/06 , C07D471/06 , C08K5/0041 , C08K5/3437
摘要: Rylene derivatives of the general formula I in which the variables are each defined as follows: Rylene is a polycyclic conjugated ring system which comprises at least one perylene unit may comprise heteroatoms as ring atoms, may be functionalized by moieties comprising —CO— groups and/or may bear further substituents other than the A radicals; A is a radical of the formula X is oxygen or sulfur; R are identical or different radicals: optionally substituted alkyl, cycloalkyl, aryl, hetaryl, —U-aryl where U is an —O—, —S—, —NR2—, —CO—, —SO— or —SO2— moiety, or C1-C12-alkoxy, C1-C6-alkylthio, —C≡CR2, —CR2═CR22, hydroxy, mercapto, halogen, cyano, nitro, —NR3R4, —NR3COR4, —CONR3R4, —SO2NR3R4, —COOR3 or —SO3R3; R′ are identical or different radicals: hydrogen or one of the R radicals; R2 is hydrogen or alkyl, where the R2 radicals may be the same or different when they occur more than once; R3, R4 are each independently hydrogen; optionally substituted alkyl, aryl or hetaryl; n is from 1 to 8.
摘要翻译: 通式I的亚芳基衍生物各自定义如下:Rylene是多环共轭环系,其包含至少一个苝单元可以包含杂原子作为环原子,可以由包含-CO-基团和/ 或者可以承担除了A基团之外的其它取代基; A是式X的基团是氧或硫; R是相同或不同的基团:任选取代的烷基,环烷基,芳基,杂芳基,-U-芳基,其中U是-O - , - S - , - NR 2 - , - CO - , - SO-或-SO 2 - 或C 1 -C 12 - 烷氧基,C 1 -C 6烷硫基,-C≡CR2,-CR 2 = CR 22,羟基,巯基,卤素,氰基,硝基,-NR 3 R 4,-NR 3 COR 4,-CONR 3 R 4,-SO 2 NR 3 R 4,-COOR 3或-SO 3 R 3 ; R'是相同或不同的基团:氢或R基团之一; R2是氢或烷基,其中R2基团当它们不止一次出现时可以相同或不同; R3,R4各自独立地为氢; 任选取代的烷基,芳基或杂芳基; n为1至8。
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公开(公告)号:US20100317876A1
公开(公告)日:2010-12-16
申请号:US12849079
申请日:2010-08-03
IPC分类号: C07D493/06
CPC分类号: C07D493/06 , C07C1/2078 , C07D221/18 , C07D311/78 , C07D491/06 , C07F5/025 , C09B3/14 , C09B5/62 , C07C13/62
摘要: Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2,R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.
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公开(公告)号:US07795432B2
公开(公告)日:2010-09-14
申请号:US10547516
申请日:2004-02-27
申请人: Christopher Kohl , Jianqiang Qu , Klaus Müllen
发明人: Christopher Kohl , Jianqiang Qu , Klaus Müllen
IPC分类号: C07D471/02 , C07D471/08
摘要: The invention relates to novel perylenetetracarboxylic acid bisimide derivatives with improved performance properties.
摘要翻译: 本发明涉及具有改进性能的新型苝四羧酸双酰亚胺衍生物。
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27.
公开(公告)号:US20100072438A1
公开(公告)日:2010-03-25
申请号:US12513410
申请日:2007-10-25
IPC分类号: F21V9/04 , C07D221/18 , C08K5/3432 , C09D17/00 , C09K3/00 , C09K11/06
CPC分类号: C07D471/06 , C07D221/18
摘要: The present invention relates to heptarylene- and octarylenetetracarboximides of the general formula (I) to precursors thereof or mixtures thereof, and to processes for their preparation and to their use.
摘要翻译: 本发明涉及通式(I)的前述或其混合物的通式(I)的七芳基 - 和八芳基四甲酰亚胺化合物,以及其制备方法及其用途。
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公开(公告)号:US08569500B2
公开(公告)日:2013-10-29
申请号:US12849079
申请日:2010-08-03
IPC分类号: C07D471/00 , C07D491/00 , C07D498/00
CPC分类号: C07D493/06 , C07C1/2078 , C07D221/18 , C07D311/78 , C07D491/06 , C07F5/025 , C09B3/14 , C09B5/62 , C07C13/62
摘要: A process for preparing a rylenetetracarboxylic dianhydride, or a salt thereof having application formula Ib by subjecting a rylenetetracarboximide of application formula II to a hydrolysis under alkaline conditions in the presence of a polar organic solvent and removing the rylenetetracarboxylic dianhydride Ib from any rylenetetracarboxylic monoimide monoanhydride of application formula Ia which is formed to form the rylenetetracarboxylic dianhydride, or the salt thereof having formula Ib; or hydrolyzing the rylenetetracarboximide of application formula II under conditions that form the compound of application formula Ib and substantially no rylenetetracarboxylic monoimide monoanhydride of application formula Ia.
摘要翻译: 通过在极性有机溶剂的存在下,在碱性条件下使应用式II的四亚甲基四酰亚胺进行水解,并从任何四环四羧酸单酰亚胺单酸酐中除去三环四羧酸二酐1b,从而制备具有应用通式Ib的四环四羧酸二酐的方法或其盐 其形成为形成四环四羧酸二酐的式Ia或其具有式Ib的盐; 或在施用式Ib化合物的条件下水解应用式II的三环四甲酰亚胺,并且基本上不应用式Ia的四环四羧酸单酰亚胺单酸酐。
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公开(公告)号:US08399669B2
公开(公告)日:2013-03-19
申请号:US12989293
申请日:2009-04-21
IPC分类号: C07D471/08 , H01L51/50 , C09K11/06
CPC分类号: C07D471/06
摘要: The present invention relates to pentarylenetetracarboximides of the formula (I) or (Ia) or mixtures thereof to processes for preparation thereof, and to the precursors and use thereof.
摘要翻译: 本发明涉及式(I)或(Ia)的五亚甲基四羧酰亚胺或其混合物,其制备方法及其前体及其用途。
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30.
公开(公告)号:US08119802B2
公开(公告)日:2012-02-21
申请号:US11846969
申请日:2007-08-29
申请人: Nicolle Moonen , Stephan Hess , Jianqiang Qu , Markus Hoffmann , Ying-Syi Li , Jin Yang , Gerhard Wagenblast , Alfred Rennig , Thomas Gessner , Helmut Reichelt , Patrick Amrhein
发明人: Nicolle Moonen , Stephan Hess , Jianqiang Qu , Markus Hoffmann , Ying-Syi Li , Jin Yang , Gerhard Wagenblast , Alfred Rennig , Thomas Gessner , Helmut Reichelt , Patrick Amrhein
IPC分类号: C07D471/08 , C09B3/14
摘要: This invention relates to process for preparing fluorinated dyes selected from the group consisting of compounds of the general formulae (I) and (III) and mixtures thereof by reacting the corresponding compounds which do not have R12 or R30 as substituents with compounds of the general formula R12A or R30A where A is selected from the group consisting of I and Br, the compounds obtained from said process and the use of these fluorinated dyes in electrophoretic displays.
摘要翻译: 本发明涉及通过使不具有R 12或R 30作为取代基的相应化合物与通式(I)和(III)的化合物反应的化合物与通式 R12A或R30A,其中A选自I和Br,从所述方法获得的化合物和在电泳显示器中使用这些氟化染料。
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