摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是自由基-L-NR1R2(y1)-L-Z-R3(y2)另一个基团氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R1,R2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是自由基-L-NR1R2(y1)-L-Z-R3(y2)另一个基团氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R1,R2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z-R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是一个根本的<?in-line-formula description =“In-line Formulas”end =“lead”?> - L-NR <1> SUP> 2(y1) ?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> - LZR < / SUP>(y2)<?in-line-formula description =“In-line Formulas”end =“tail”?>另一个自由基氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR 1 R 2 O 2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO 3 M; -PO 3 M 2 N 2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR 5] 4 u> sup> L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R 1,R 2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S- R 3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R 5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Rylene derivatives useful in solar cells, where the rylene derivatives are represented by formula I where each X group is joined to form a six-membered ring, one Y group is an amine group, one Y group is a hydrogen atom, each R group is an alkoxy group, m is 1, n is 4, and P is 0.
摘要:
Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要:
Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要:
Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要:
Novel mono-azide substituted rylene-imide derivatives, their use in methods for the detection of analytes and reagents kits for the detection of analytes comprising said novel mono-azide substituted rylene-imide derivatives.
摘要:
Rylene derivatives of the general formula I in which the variables are each defined as follows: X are joined to one another with formation of a six-membered ring to give a radical of the formula (a), (b) or (c) are both a —COOM radical; are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) Y are joined to one another with formation of a six-membered ring to give a radical of the formula (a) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or together are a radical of the formula (a), (b) or (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (b) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c); are joined to one another with formation of a six-membered ring to give a radical of the formula (c) when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical or together are a radical of the formula (c) which may be arranged in the cis or trans position to the other (c) radical; are both a —COOM radical when one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d) or when both X radicals are hydrogen or a —COOM radical, M being different from hydrogen in the case that one X radical is a radical of the formula (d); are both hydrogen or one of the two radicals is hydrogen and the other radical is halogen or a radical of the formula (d) when both X radicals are hydrogen or one of the two X radicals is hydrogen and the other X radical is halogen or a radical of the formula (d); R are identical or different radicals: substituted or unsubstituted aryloxy, arylthio, hetaryloxy or hetarylthio; R′ is hydrogen; substituted or unsubstituted alkyl, cycloalkyl, aryl or hetaryl; A are each independently substituted or unsubstituted phenylene, naphthylene or pyridylene; M is hydrogen, ammonium or alkali metal cation; R″ are each independently hydrogen, alkyl, cycloalkyl, aryl or hetaryl, or are joined together with formation of a 5- to 7-membered, fused or unfused and substituted or unsubstituted ring comprising the two oxygen atoms and also the boron atom; R1 is hydrogen or alkyl, where the R1 radicals may be the same or different when they occur more than once; R2,R3 are each independently hydrogen; substituted or unsubstituted alkyl, aryl or hetaryl; m is 1 or 2; n is from 3 to 6 where m=1; is from 2 to 8 where m=2, and mixtures thereof.
摘要:
The present invention relates to processes for preparing pentarylene- and hexarylenetetracarboximides of the general formula (I) or (Ia) or mixtures thereof, to pentarylene and hexarylenetetracarboximides having a high degree of substitution, and to their use.