摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是自由基-L-NR1R2(y1)-L-Z-R3(y2)另一个基团氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R1,R2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z—R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是自由基-L-NR1R2(y1)-L-Z-R3(y2)另一个基团氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR1R2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO3M; -PO3M2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR5] 4+; L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R1,R2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S-; R3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Use of rylene derivatives I with the following definition of the variables: X together both —COOM; Y a radical -L-NR1R2 (y1) -L-Z-R3 (y2) the other radical hydrogen; together both hydrogen; R is optionally substituted (het)aryloxy, (het)arylthio; P is —NR1R2; B is alkylene; optionally substituted phenylene; combinations thereof; A is —COOM; —SO3M; —PO3M2; D is optionally substituted phenylene, naphthylene, pyridylene; M is hydrogen; alkali metal cation; [NR5]4+; L is a chemical bond; optionally indirectly bonded, optionally substituted (het)arylene radical; R1, R2 are optionally substituted (cyclo)alkyl, (het)aryl; together optionally substituted ring comprising the nitrogen atom; Z is —O—; —S—; R3 is optionally substituted alkyl, (het)aryl; R′ is hydrogen; optionally substituted (cyclo)alkyl, (het)aryl; R5 is hydrogen; optionally substituted alkyl (het)aryl; m is 0, 1, 2; n, p m=0: 0, 2, 4 where: n+p=2, 4, if appropriate 0; m=1: 0, 2, 4 where: n+p=0, 2, 4; m=2: 0, 4, 6 where: n+p=0, 4, 6, or of mixtures thereof as photosensitizers in solar cells.
摘要翻译:使用二烯衍生物I与以下变量的定义:X一起-COOM; Y是一个根本的<?in-line-formula description =“In-line Formulas”end =“lead”?> - L-NR <1> SUP> 2(y1) ?in-line-formula description =“In-line Formulas”end =“tail”?> <?in-line-formula description =“In-line Formulas”end =“lead”?> - LZR < / SUP>(y2)<?in-line-formula description =“In-line Formulas”end =“tail”?>另一个自由基氢; 一起氢; R是任选取代的(het)芳氧基,(het)芳硫基; P是-NR 1 R 2 O 2; B是亚烷基; 任选取代的亚苯基; 其组合; A是-COOM; -SO 3 M; -PO 3 M 2 N 2; D是任选取代的亚苯基,亚萘基,亚吡啶基; M是氢; 碱金属阳离子; [NR 5] 4 u> sup> L是化学键; 任选间接结合的,任选取代的(亚乙基)亚芳基; R 1,R 2是任选取代的(环)烷基,(het)芳基; 一起任选取代的包含氮原子的环; Z为-O- -S- R 3是任选取代的烷基,(het)芳基; R'是氢; 任选取代的(环)烷基,(het)芳基; R 5是氢; 任选取代的烷基(het)芳基; m为0,1,2; n,p m = 0:0,2,4其中:n + p = 2,4,如果合适0; m = 1:0,2,4其中:n + p = 0,2,4; m = 2:0,4,6其中:n + p = 0,4,6或其混合物作为太阳能电池中的光敏剂。
摘要:
Rylene derivatives useful in solar cells, where the rylene derivatives are represented by formula I where each X group is joined to form a six-membered ring, one Y group is an amine group, one Y group is a hydrogen atom, each R group is an alkoxy group, m is 1, n is 4, and P is 0.
摘要:
The present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide or amine moiety and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In additional embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between a nitrogen atom of an acyl hydrazine and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In other embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of a nitrogen-containing heteroaromatic, e.g., indole, pyrazole, and indazole, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-oxygen bond between the oxygen atom of an alcohol and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. The present invention also relates to copper-catalyzed methods of forming a carbon-carbon bond between a reactant comprising a nucleophilic carbon atom, e.g., an enolate or malonate anion, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. Importantly, all the methods of the present invention are relatively inexpensive to practice due to the low cost of the copper comprised by the catalysts.
摘要:
The present invention relates to aqueous liquid formulations comprising 5-25% by weight of a dye composition comprising 70-95% by weight of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 1-30% by weight of a blue direct dye and 0-20% by weight of a red direct dye (all based on the dye composition) 1-15% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups, and 1-30% by weight of urea based on the total weight of the aqueous liquid formulation, wherein the total amount of water-soluble amine and urea does not exceed 40% by weight, and also their use for dyeing cellulose material especially paper.
摘要:
The present invention relates to a process for preparing transparent conductive oxides, comprising the following steps in the sequence of a-b-c:(a) reaction of at least one starting compound (A) comprising at least one metal or semimetal M and optionally of a dopant (D) comprising at least one doping element M′, where at least one M′ is different than M, in the presence of a block copolymer (B) and of a solvent (C) to form a composite material (K), (b) optional application of the composite material (K) to a substrate (S) and (c) heating of the composite material (K) to a temperature of at least 350° C., wherein the block copolymer (B) comprises at least one alkylene oxide block (AO) and at least one isobutylene block (IB). The present invention further relates to the transparent conductive oxides thus obtainable, and to their use in electronic components, as an electrode material and as a material for antistatic applications. The present invention finally relates to electronic components comprising the transparent conductive oxides.
摘要:
The present invention relates to aqueous liquid formulations comprising 5-25% by weight of a dye composition comprising 70-95% by weight of a dye obtainable by reduction or thermal treatment of Direct Yellow 11 1-30% by weight of a blue direct dye and 0-20% by weight of a red direct dye (all based on the dye composition) 1-15% by weight of a saturated, cyclic or acyclic water-soluble amine comprising a primary, secondary or tertiary amino group and at least one further functional group selected from primary, secondary and tertiary amino groups, OH groups and ether groups, and 1-30% by weight of urea based on the total weight of the aqueous liquid formulation, wherein the total amount of water-soluble amine and urea does not exceed 40% by weight, and also their use for dyeing cellulose material especially paper.
摘要:
The present invention relates to copper-catalyzed carbon-heteroatom and carbon-carbon bond-forming methods. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of an amide or amine moiety and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In additional embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between a nitrogen atom of an acyl hydrazine and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In other embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-nitrogen bond between the nitrogen atom of a nitrogen-containing heteroaromatic, e.g., indole, pyrazole, and indazole, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. In certain embodiments, the present invention relates to copper-catalyzed methods of forming a carbon-oxygen bond between the oxygen atom of an alcohol and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. The present invention also relates to copper-catalyzed methods of forming a carbon-carbon bond between a reactant comprising a nucleophilic carbon atom, e.g., an enolate or malonate anion, and the activated carbon of an aryl, heteroaryl, or vinyl halide or sulfonate. Importantly, all the methods of the present invention are relatively inexpensive to practice due to the low cost of the copper comprised by the catalysts.
摘要:
This invention relates to an additive package containing an organic solvent, a detergent additive and a reaction product mixture obtained by reacting a carboxylic acid compound of formula (I): R1COOR2 with an alkanol amine of formula (II): NHR3R4 to form a reaction product containing a polysubstituted alkanol amine derivative, where the reaction is performed by: (a) heating the carboxylic acid of formula (I) to a first temperature; (b) adding thereto the alkanol amine of formula (II) under controlled conditions avoiding an increase of temperature above the first temperature range; (c) maintaining temperature in the first temperature range; and (d) increasing the temperature of the reaction mixture to a second temperature in a second temperature range of 160 to 210° C. and allowing further reaction of residual free carboxylic acid molecules with any reactive group in the reaction mixture.
摘要翻译:本发明涉及含有有机溶剂,洗涤剂添加剂和通过使式(I)的羧酸化合物:R1COOR2与式(II)的链烷醇胺:NHR 3 R 4反应形成反应产物而得到的反应产物混合物的添加剂包 含有多取代的烷醇胺衍生物,其中反应通过以下步骤进行:(a)将式(I)的羧酸加热至第一温度; (b)在控制条件下加入式(II)的链烷醇胺,避免温度升高至高于第一温度范围; (c)将温度保持在第一温度范围内; 和(d)在160至210℃的第二温度范围内将反应混合物的温度升至第二温度,并允许残余游离羧酸分子与反应混合物中的任何反应性基团进一步反应。