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公开(公告)号:US20210376201A1
公开(公告)日:2021-12-02
申请号:US17303376
申请日:2021-05-27
Applicant: NICHIA CORPORATION
Inventor: Makiko IWASA , Kazuya NISHIMATA , Atsushi YOSHINARI , Shoji HOSOKAWA , Masato OKAWA , Yasuaki MASHIMA
Abstract: A light emitting device includes a light emitting element having a dominant wavelength in a range of 400 nm or more and 500 nm or less, and a wavelength conversion member that is arranged on a light emitting side of the light emitting element and includes a rare earth aluminate fluorescent material having a composition represented by the following formula (I), wherein the light emitting device emits light having a dominant wavelength in a range of 475 nm or more and 500 nm or less, and wherein the light emitting device emits light having an S/P ratio of 6.5 or less derived from the formula (1), which is the ratio of a luminous flux in scotopic vision relative to a luminous flux in photopic vision: (Lu1-p-nLnpCen)3(Al1-mGam)5kO12 (I) wherein in the formula (I), Ln represents at least one rare earth element selected from the group consisting of Y, La, Gd, and Tb, and the parameters k, m, n, and p satisfy 0.95≤k≤1.05, 0.05≤m≤0.70, 0.002≤n≤0.050, and 0≤p≤0.30, respectively.
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22.
公开(公告)号:US20210371975A1
公开(公告)日:2021-12-02
申请号:US17303476
申请日:2021-05-28
Applicant: NICHIA CORPORATION
Inventor: Ryuta MIYAI , Kazuya NISHIMATA , Shoji HOSOKAWA
IPC: C23C16/442 , C23C16/40 , C09K11/02 , C09K11/08 , C23C16/56
Abstract: A method of producing a silicate fluorescent material, the method includes: providing a raw material mixture that contains an M source containing M, an Mg source, an Eu source, and an Si source, and optionally an Mn source, obtaining at least one core particle comprising a silicate fluorescent composition having a formula: (M1-cEuc)3a(Mg1-dMnd)bSi2O8, in which M is at least one element selected from the group consisting of Ca, Sr, and Ba, and a, b, c, and d are numbers respectively satisfying 0.93≤a≤1.07, 0.90≤b≤1.10, 0.016≤c≤0.090, and 0≤d≤0.22; using a chemical vapor deposition method, depositing aluminum oxide on surfaces of the at least one core particle; and heat treating at a temperature in a range of 210° C. to 490° C. in an oxygen-containing atmosphere.
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23.
公开(公告)号:US20200318004A1
公开(公告)日:2020-10-08
申请号:US16905340
申请日:2020-06-18
Applicant: NICHIA CORPORATION
Inventor: Kazuya NISHIMATA , Tomokazu YOSHIDA , Shoji HOSOKAWA
Abstract: Disclosed are a method of producing an aluminate fluorescent material, such an aluminate fluorescent material, and a light emitting device. The aluminate fluorescent material production method includes: subjecting a first mixture prepared by mixing a compound containing at least one metal element selected from the group consisting of Ba, Sr and Ca, and at least one compound selected from the group consisting of a compound containing Mn and a compound containing Eu, and a compound containing Al, in which a compound containing Mg may be optionally mixed, to first heat treatment to give a first calcined product having an average particle diameter D1, as measured according to a Fisher Sub-Sieve Sizer method, of 6 μm or more; and subjecting a second mixture prepared by mixing a compound containing at least one metal element selected from the group consisting of Ba, Sr and Ca, at least one compound selected from the group consisting of a compound containing Mn and a compound containing Eu, and a compound containing Al, and the first calcined product whose content is 10% by mass or more and 90% by mass or less relative to the total amount of the second mixture, in which a compound containing Mg may be optionally mixed, to second heat treatment to give a second calcined product.
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公开(公告)号:US20190207064A1
公开(公告)日:2019-07-04
申请号:US16296803
申请日:2019-03-08
Applicant: NICHIA CORPORATION
Inventor: Shoji HOSOKAWA , Kazuya NISHIMATA , Tomokazu YOSHIDA
CPC classification number: H01L33/504 , C09K11/0883 , C09K11/643 , C09K11/7731 , C09K11/7734 , G02F1/1336 , H01L33/32 , H01L33/486 , H01L33/507 , H01L33/508 , H01L2933/0091
Abstract: Provided is a light-emitting device including a light-emitting element having a peak emission wavelength in a range of from 400 nm to 470 nm, and a fluorescent member including a first fluorescent material including an aluminate that contains Mg, Mn, and at least one alkali earth metal selected from the group consisting of Ba, Sr, and Ca, a second fluorescent material having a different composition from the first fluorescent material, and a third fluorescent material. The first, second and third fluorescent materials have a peak emission wavelength in a range of from 510 nm to 525 nm, from 510 nm to 550 nm, and from 620 nm to 670 nm, respectively.
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公开(公告)号:US20190062632A1
公开(公告)日:2019-02-28
申请号:US16116871
申请日:2018-08-29
Applicant: NICHIA CORPORATION
Inventor: Kazuya NISHIMATA , Tomokazu YOSHIDA , Shoji HOSOKAWA
Abstract: Disclosed are an aluminate fluorescent material having a high light emission intensity, and a light emitting device using the same. The aluminate fluorescent material includes a composition represented by the following formula (I): X1pEutMgqMnrAlsOp+t+q+r+1.5s (I) wherein X1 represents at least one element selected from the group consisting of Ba, Sr, and Ca; and p, q, r, s, and t each satisfy 0.5≤p≤1.0, 0≤q≤0.6, 0.4≤r≤0.7, 8.5≤s≤13.0, 0≤t≤0.3, 0.5
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26.
公开(公告)号:US20180086975A1
公开(公告)日:2018-03-29
申请号:US15704689
申请日:2017-09-14
Applicant: NICHIA CORPORATION
Inventor: Shozo TAKETOMI , Shoji HOSOKAWA , Tomokazu YOSHIDA , Kazuya NISHIMATA
CPC classification number: C09K11/643 , H01L33/502 , H01L33/505 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265
Abstract: Provided are a method of producing an aluminate fluorescent material, an aluminate fluorescent material and a light emitting device. The production method includes heat-treating a mixture prepared by mixing a compound containing at least one alkaline earth metal element selected from the group consisting of Ba, Sr and Ca, a Mg-containing compound not acting as a flux, a Mn-containing compound, an Al-containing compound, a first flux containing at least one alkali metal element selected from the group consisting of Na, K, Rb and Cs, and a Mg-containing second flux to give an aluminate fluorescent material.
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公开(公告)号:US20180037469A1
公开(公告)日:2018-02-08
申请号:US15667975
申请日:2017-08-03
Applicant: NICHIA CORPORATION
Inventor: Kazuya NISHIMATA , Shoji HOSOKAWA , Tomokazu YOSHIDA
CPC classification number: C01G45/006 , C01F1/00 , C01P2004/03 , C01P2006/60 , C09K11/576 , C09K11/643 , H01J61/44 , H01L33/50 , H01L33/502
Abstract: Provided is an aluminate fluorescent material having a composition represented by the formula X1aMgbMncAldOa+b+c+1.5d, in which X1 is at least one element selected from the group consisting of Ba, Sr; and Ca, a, b, c, and d satisfy 0.5≦a≦1.0, 0.0≦b
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28.
公开(公告)号:US20170355904A1
公开(公告)日:2017-12-14
申请号:US15615896
申请日:2017-06-07
Applicant: NICHIA CORPORATION
Inventor: Tomokazu YOSHIDA , Kazuya NISHIMATA , Shoji HOSOKAWA
CPC classification number: C09K11/643 , C09K11/576 , H01L33/502 , H01L2224/48247 , H01L2224/48257 , H01L2224/73265
Abstract: Provided is an aluminate fluorescent material having a high emission intensity and having a composition containing a first element that contains one or more of Ba and Sr, and a second element that contains Mg and Mn. In the composition, when a molar ratio of Al is 10, a total molar ratio of the first element is a parameter a, a total molar ratio of the second element is a parameter b, a molar ratio of Sr is a product of a parameter m and the parameter a, a molar ratio of Mn is a product of a parameter n and the parameter b. The parameters a and b satisfy 0.5
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