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    Hydrocracking with phosphomolybdic acid and phosphoric acid
    24.
    发明授权
    Hydrocracking with phosphomolybdic acid and phosphoric acid 失效
    用磷钼酸和磷酸进行加氢裂化

    公开(公告)号：US4637870A

    公开(公告)日：1987-01-20

    申请号：US785986

    申请日：1985-10-10

    Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

    Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

    IPC: B01J27/19 ,  C10G49/04 ,  C10G49/12 ,  C10G47/04

    CPC classification number: B01J27/19 ,  C10G49/04 ,  C10G49/12

    Abstract: Hydroconversion processes for converting oil, coal or mixtures thereof are provided utilizing a catalyst prepared by first forming an aqueous solution of phosphomolybdic acid and phosphoric acid at a specified ratio of atoms of P/Mo, and subsequently adding this solution to a hydrocarbon material, followed by heating in the presence of H.sub.2 and/or H.sub.2 S to form a solid molybdenum and phosphorus-containing catalyst.

    Abstract translation: 用于转化油，煤或其混合物的加氢转化方法使用通过首先以规定的P / Mo原子比形成磷钼酸和磷酸的水溶液制备的催化剂，随后将该溶液加入到烃材料中，随后 通过在H 2和/或H 2 S存在下加热以形成固体含钼和磷的催化剂。

    Coal liquefaction process
    25.
    发明授权
    Coal liquefaction process 失效
    煤液化过程

    公开(公告)号：US4369106A

    公开(公告)日：1983-01-18

    申请号：US244082

    申请日：1981-03-16

    Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

    Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

    IPC: C10G1/08 ,  C10G1/06

    CPC classification number: C10G1/086 ,  Y10S208/951

    Abstract: In a process for catalytically converting coal in a diluent wherein the catalyst is prepared in situ in the coal-diluent mixture by converting a metal compound to a metal-containing catalyst, the metal compound is added to the coal-diluent mixture in a liquid medium comprising at least 30 weight percent of a phenol.

    Abstract translation: 在将稀释剂中的煤进行催化转化的方法中，其中通过将金属化合物转化为含金属的催化剂，在煤 - 稀释剂混合物中原位制备催化剂，将金属化合物加入到液体介质中的煤 - 稀释剂混合物中 包含至少30重量％的苯酚。

    Hydrocracking process utilizing high surface area catalysts
    26.
    发明授权
    Hydrocracking process utilizing high surface area catalysts 失效
    使用高表面积催化剂的加氢裂化工艺

    公开(公告)号：US4313818A

    公开(公告)日：1982-02-02

    申请号：US105249

    申请日：1979-12-19

    Applicant: Clyde L. Aldridge ,  Roby Bearden, Jr.

    Inventor： Clyde L. Aldridge ,  Roby Bearden, Jr.

    IPC: B01J37/08 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02 ,  C10G47/06

    CPC classification number: B01J37/08 ,  B01J37/086 ,  C10G11/02 ,  C10G35/06 ,  C10G49/02

    Abstract: A hydrocracking process is provided utilizing high surface area metal-containing catalysts prepared by dispersing a thermally decomposable metal compound in a hydrocarbon oil having a Conradson carbon content of up to about 50 weight percent, the thermally decomposable metal compound being added in an amount sufficient to obtain a specified ratio of atoms of Conradson carbon of the oil chargestock to atoms of metal constituent of the thermally decomposable compound, heating the compound in the presence of a gas comprising either hydrogen or hydrogen sulfide or hydrogen and hydrogen sulfide to form a solid high surface area catalyst. The metal constituent of the thermally decomposable metal compound may be a metal of Groups II, III, IV, V, VIB, VIIB, VIII or mixtures thereof.

    Abstract translation: 使用通过将可热分解的金属化合物分散在具有高达约50重量％的康拉逊碳含量的烃油中而制备的高表面积含金属催化剂的加氢裂化方法，所述可热分解的金属化合物的加入量足以 获得指定比例的含油原料的康拉德森碳与可热分解化合物的金属成分原子，在包含氢或硫化氢或氢气和硫化氢的气体存在下加热该化合物，形成固体高表面 区域催化剂。 可热分解的金属化合物的金属组分可以是II，III，IV，V，VIB，VIIB，VIII族的金属或其混合物。

    Catalyst for the hydroconversion of heavy hydrocarbons
    27.
    发明授权
    Catalyst for the hydroconversion of heavy hydrocarbons 失效
    用于加氢转化重质烃的催化剂

    公开(公告)号：US4226742A

    公开(公告)日：1980-10-07

    申请号：US924818

    申请日：1978-07-14

    Applicant: Roby Bearden, Jr. ,  Clyde L. Aldridge

    Inventor： Roby Bearden, Jr. ,  Clyde L. Aldridge

    IPC: B01J23/28 ,  C10G45/16 ,  B01J31/12 ,  B01J27/04

    CPC classification number: B01J23/28 ,  C10G2300/107

    Abstract: A catalytic hydroconversion process for a hydrocarbonaceous oil is effected by dissolving an oil-soluble metal compound in the oil, converting the compound to a solid, non-colloidal catalyst within the oil and reacting the oil containing the catalyst with hydrogen. Preferred compounds are molybdenum compounds.

    Abstract translation: 烃油的催化加氢转化方法是通过将油溶性金属化合物溶解在油中，将化合物转化成油中的固体非胶态催化剂并使含有催化剂的油与氢反应。 优选的化合物是钼化合物。

    Hydroconversion with group IA, IIA metal compounds
    29.
    发明授权
    Hydroconversion with group IA, IIA metal compounds 失效
    与IA，IIA金属化合物进行加氢转化

    公开(公告)号：US4127470A

    公开(公告)日：1978-11-28

    申请号：US820859

    申请日：1977-08-01

    Applicant: William C. Baird, Jr. ,  Roby Bearden, Jr. ,  Thomas H. Ledford

    Inventor： William C. Baird, Jr. ,  Roby Bearden, Jr. ,  Thomas H. Ledford

    IPC: C10G45/04 ,  C10G65/04 ,  C10G13/04 ,  B01J27/04

    CPC classification number: C10G45/04 ,  C10G65/04

    Abstract: Processes for the treating of sulfur-containing petroleum oil feedstocks employing alkali metal compounds, alkaline earth metal compounds, and mixtures thereof are disclosed. Specifically, processes for hydrotreating feedstocks which have been previously partially desulfurized using conventional hydrodesulfurization catalysts by contacting such feedstocks with alkali metal compounds, alkaline earth metal compounds, and mixtures thereof, are disclosed. Preferably, the products of such a treatment are employed as feeds for catalytic cracking processes. In addition, processes for the combined hydrotreating and hydroconversion of various sulfur-containing petroleum oil feeds are disclosed, employing at least two hydroconversion agents selected from the group consisting of the alkali metal compounds and alkaline earth metal compounds, in the presence of added hydrogen, and at elevated temperatures. The reaction products formed thereby include a substantially desulfurized and demetallized, as well as a significantly upgraded petroleum product. The latter is demonstrated by a reduced Conradson carbon content and an increased API gravity.

    Abstract translation: 公开了使用碱金属化合物，碱土金属化合物及其混合物处理含硫石油原料的方法。 具体地，公开了使用常规加氢脱硫催化剂预先部分脱硫的原料加氢处理方法，其通过使这些原料与碱金属化合物，碱土金属化合物及其混合物接触。 优选地，这种处理的产物用作催化裂化方法的进料。 另外，公开了各种含硫石油原料进料的组合加氢处理和加氢转化的方法，在加入的氢气存在下使用至少两种选自碱金属化合物和碱土金属化合物的加氢转化剂， 并在升高的温度。 由此形成的反应产物包括基本上脱硫和脱金属的，以及显着升级的石油产品。 后者通过降低的Conradson碳含量和增加的API重力来证明。

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