摘要:
This invention provides a luminescent composition comprising a polymer and at least one phosphorescent compound, characterized in that the electronic conjunction chain coefficient Ze of the main repeating minimum unit of the polymer falls within the following range: 0
摘要翻译:本发明提供一种包含聚合物和至少一种磷光化合物的发光组合物,其特征在于聚合物的主要重复最小单元的电子连接系数Z∈E在下列范围内:0 < 其中电子连接链系数Z e e被定义为通过函数T N的线性近似获得的斜率, = 1×(1 / n),其中n e表示以重复的最小单位包含的共轭电子的数目; 对于通过键合重复的最小单位获得的m-mer,当数m从1变化到3时,每个m-mer中的最低三重态激发能一个接一个地表示。 这里,在共轭电子数中,仅考虑存在于重复最小单位的主链中的共轭电子,条件是当存在多个主重复最小单元时,最小Z e e SUB>被使用。
摘要:
A light emitting material comprising a conjugated polymer compound (A) containing an aromatic ring in the main chain and a compound (B) showing light emission from the triplet excited state, wherein an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, calculated by a computational chemical means, is 1.3 eV or more, or an energy difference between the vacuum level and the lowest unoccupied orbital (LUMO) level in the ground state, experimentally measured, is 2.2 eV or more, in the polymer compound (A), and either the following (Condition 1) or the following (Condition 2) or both of them are satisfied.(Condition 1): Energy (ESA0) in the ground state of the polymer compound (A), energy (ETA) in the lowest excited triplet state of the polymer compound (A), energy (ESB0) in the ground state of the compound (B) and energy (ETB) in the lowest excited triplet state of the compound (B) satisfy the relation (Eq1): ETA−ESA0>ETB−ESB0 (Eq1) (Condition 2): The ratio PLA/PLB of photoluminescence intensity (PLA) of the polymer compound (A) to photoluminescence intensity (PLB) of the compound (B) showing light emission from the triplet excited state is 0.8 or less.
摘要翻译:包含在主链中含有芳环的共轭高分子化合物(A)和显示三重激发态发光的化合物(B)的发光材料,其中真空度与最低未占据轨道之间的能量差(LUMO )电平为1.3 eV以上,实验测量的基态中的真空度与最低未占轨道(LUMO)能级之间的能量差为2.2eV以上 (A),以下(条件1)或以下(条件2)或两者均满足。 (条件1):高分子化合物(A)的基态中的能量(ESA0),聚合物的最低激发三重态的能量(ET> A) 化合物(A),化合物(B)的基态中的能量(ES B B)和化合物的最低激发三重态的能量(ET B B) B)满足关系式(Eq 1):<?in-line-formula description =“In-line Formulas”end =“lead”?> ET sub> AES SUB> (Eq1)<?in-line-formula description =“In-line Formulas”end =“tail”?>(条件2) :高分子化合物(A)的光致发光强度(PLΛA)与光致发光强度(PL 显示出来自三线态激发状态的发光的化合物(B)的重量比> B <!>为0.8以下。
摘要:
A data code generator produces a data code, while a reference code generator produces a reference code. The data code is phase-shifted by the data code generator in a predetermined sweep range, according to a sweep command signal given by a phase difference detector. The phase difference detector compares the phase of the data code with that of the reference code to obtain phase difference data. Based on the phase difference data, a correction signal generator produces a correction signal to keep the data code in phase with the reference, code. The phase setter optimizes the phase of the data code according to the correction signal.
摘要:
A sound-signal generating unit generates, when a positional relationship between a local information processing apparatus and a user is acquired, a sound signal that makes the user perceive a virtual sound source at a predetermined position in a three-dimensional space based on the acquired positional relationship.
摘要:
There are provided a method of manufacturing an information recording medium 1 having a water-based ink absorbing layer 2 on a surface of a base material 3, and the information recording medium 1 obtained by the manufacturing method. The method includes: (1) coating the surface of the base material with a water-based ink absorbent containing a water-absorptive filler to form a coated layer 2a; (2) covering a surface of the coated layer 2a with a cover material 10; (3) irradiating the coated layer 2a with active energy beam to cure the coated layer 2a; and (4) removing the cover material 10 from the coated layer 2a.
摘要:
A data code transmission device that detects and corrects phase differences between serial data codes to ensure the quality of data transmission. A data code generator produces a data code, while a reference code generator produces a reference code. The data code is phase-shifted by the data code generator in a predetermined sweep range, according to a sweep command signal given by a phase difference detector. The phase difference detector compares the phase of the data code with that of the reference code to obtain phase difference data. Based on the phase difference data, a correction signal generator produces a correction signal to keep the data code in phase with the reference code. The phase setter optimizes the phase of the data code according to the correction signal.
摘要:
A dose distribution-measuring method capable of grasping a three-dimensional form of an object to be measured or evaluating a three-dimensional dose distribution thereof. The method comprises providing a multiple-eye type radiation meter probe in which at least two directional radiation detectors are arranged so as to be spaced from each other and directed toward a point to be measured; and carrying out dose measurement by directing the radiation meter probe toward an object to be measured from different positions to thereby determine a three-dimensional dose distribution of the object to be measured. Each of the radiation detectors has a structure in which a periphery of the radiation detector main body, except for a detection surface thereof, is surrounded by a radiation shield to reduce the effect of radiation from other than the object to be measured and from Compton scattering.
摘要:
Materials containing fine natural organic material particles are disclosed. As the fine particles, superfine silk fibroin particles are produced by a process comprising a first step of comminuting silk fibroin into coarse particles with dry mechanical comminuting means, a second step of comminuting the coarse silk fibroin particles into fine particles with dry mechanical comminuting means, and a third step of comminuting the fine silk fibroin particles into superfine particles with an average particle diameter of 10 .mu.m or below with dry mechanical comminuting means, the silk fibroin particles being beta-treated during or after at least one of the first to third comminuting steps. Specific examples of the material are films, sheets, paints, fiber treating materials, etc.
摘要:
A polymer light emitting material which contains a polymer compound comprising a repeating unit of the following formula (1) or (2) and having a polystyrene-reduced number-average molecular weight of 103 to 108, and which exhibits light emission from the triplet excited state. [wherein Ar1 and Ar2 each independently represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group. X1 and X2 each independently represent O, S, C(═O), S(═O), SO2, C(R1)(R2), Si(R3)(R4), N(R5), B(R6), P(R7) or P(═O)(R8). X1 and Ar2 bond to adjacent carbon atoms in the aromatic ring of Ar1; and X2 and Ar1 bond to adjacent carbon atoms in the aromatic ring of Ar2]; [wherein Ar3 and Ar4 each independently represent a trivalent aromatic hydrocarbon group or a trivalent heterocyclic group. X3 and X4 each independently represent N, B, P, C(R9) or Si(R10). X3 and Ar4 bond to adjacent carbon atoms in the aromatic ring of Ar3; and X4 and Ar3 bond to adjacent carbon atoms in the aromatic ring of Ar4].
摘要:
Disclosed is a metal complex containing a composition represented by the following formula (a). [(PdII)2(MI)2(X)2(L)4(L′)2] (In the formula (a), MI represents AgI, AuI or CuI; X represents Cl, Br or I; L represents a group represented by formula (1); L′ represents a group represented by formula (2); two MIs may be the same as or different from each other; four Ls may be the same as or different from each other; and two L's may be the same as or different from each other.) (In the formulae (1) and (2), R1, R2 and R3 independently represent a hydrogen atom, a halogen atom, a hydroxy group, an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted monovalent heterocyclic group.)