公开(公告)号：US4595548A

公开(公告)日：1986-06-17

申请号：US643524

申请日：1984-08-23

申请人： Anne K. St. Clair ,  Terry L. St. Clair

发明人： Anne K. St. Clair ,  Terry L. St. Clair

IPC分类号： C08G73/10 ,  C08J3/09 ,  C08J5/18

CPC分类号： C08J5/18 ,  C08G73/1028 ,  C08J3/091 ,  C08J2379/08

摘要： An aromatic condensation polyimide film that is approximately 90% transparent at 500 nm, useful for thermal protective coatings and the like, and the processes for preparing same by thermal and chemical conversion are disclosed. An essential feature of the invention for achieving maximum optical transparency films requires utilizing recrystallized and/or sublimated specific aromatic diamines and dianhydride monomers and introducing phenoxy or thiophenyl separator groups and isomeric m,m'- or o,p'-oriented diamines into the polymer molecular structure. The incorporation of these groups in the polymer structure serves to separate the chromaphoric centers and reduce the formation of inter-chain and intra-chain charge transfer complexes which normally cause absorptions in the UV-visible range. The films may be obtained by hand, brushing, casting or spraying a layer of the polyamic acid solutions onto a surface and thermally converting the applied layer to the polyimide or the polyamic acid solution can be chemically converted to the polyimide, subsequentially dissolved in an organic solvent, and applied as a polyimide film layer with the solvent therein thermally removed.

摘要翻译： 公开了一种在500nm下约90％透明度的用于热保护涂层等的芳族缩合聚酰亚胺膜及其通过热和化学转化制备方法。 本发明实现最大光学透明膜的本质特征需要使用重结晶和/或升华的特定芳族二胺和二酐单体，并将苯氧基或噻吩基隔离基和异构体m，m'-或o，p'-取向的二胺引入聚合物 分子结构。 这些基团在聚合物结构中的引入用于分离色盲中心并减少通常在UV-可见光范围内引起吸收的链间和链内电荷转移络合物的形成。 可以通过手工，刷涂，浇铸或将一层聚酰胺酸溶液喷涂到表面上并将所施加的层热转化为聚酰亚胺或聚酰胺酸溶液而将聚合物化学转化为聚酰亚胺，随后溶解在有机 溶剂，并作为聚酰亚胺膜层施加其中热溶解的溶剂。

公开(公告)号：US4510277A

公开(公告)日：1985-04-09

申请号：US548583

申请日：1983-11-03

申请人： Anne K. St. Clair ,  Diane M. Stoakley ,  Terry L. St. Clair ,  Jag J. Singh

发明人： Anne K. St. Clair ,  Diane M. Stoakley ,  Terry L. St. Clair ,  Jag J. Singh

IPC分类号： C08G59/00 ,  C08G59/10 ,  C08G59/14 ,  C08G59/18 ,  C08G59/28 ,  C08G59/32 ,  C08G59/44 ,  C08G59/70 ,  C08G79/00 ,  C08K5/00 ,  C08K5/04 ,  C08L63/00 ,  C08G59/40

CPC分类号： C08G79/00 ,  C08K5/0091

摘要： A product and the process for preparing the same to improve the moisture resistance properties of epoxidized TGMDA and DGEBA resin systems by chemically incorporating chromium (III) ions therein without impairing the mechanical strength properties of the resins.

摘要翻译： 一种产品及其制备方法，通过在其中化学引入其中的铬（III）离子来改善环氧化TGMDA和DGEBA树脂体系的耐湿性，而不损害树脂的机械强度性能。

公开(公告)号：US4281102A

公开(公告)日：1981-07-28

申请号：US92141

申请日：1979-11-07

申请人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Terry L. St. Clair ,  John M. Butler

发明人： Robert A. Administrator of the National Aeronautics and Space Administration, with respect to an invention of Frosch ,  Terry L. St. Clair ,  John M. Butler

IPC分类号： C08G73/10 ,  C08G12/00 ,  C08G16/00

CPC分类号： C08G73/1007 ,  C08G73/1042 ,  Y10T428/31721

摘要： An improvement of addition polyimides wherein an essentially solventless, high viscosity laminating resin is synthesized from low-cost liquid monomers. The improved process takes advantage of a reactive, liquid plasticizer such as monoethylphthalate (MEP) which is used in lieu of an alcohol solvent, and helps solve a major problem of maintaining good prepreg tack and drape, or the ability of the prepreg to adhere to adjacent plies and conform to a desired shape during the layup process. This improvement results in both longer life of the polymer prepreg and the processing of low-void laminates and appears to be applicable to all addition polyimide systems.

摘要翻译： 加成聚酰亚胺的改进，其中由低成本液体单体合成基本上无溶剂的高粘度层压树脂。 改进的方法利用反应性液体增塑剂，例如用于代替醇溶剂的邻苯二甲酸单乙酯（MEP），并且有助于解决保持良好的预浸料粘性和悬垂性的主要问题，或预浸料粘附于 相邻层并且在铺层过程中符合期望的形状。 这种改进导致聚合物预浸料坯的寿命更长和低空隙层压板的加工，并且似乎适用于所有加成聚酰亚胺体系。

公开(公告)号：US06545391B1

公开(公告)日：2003-04-08

申请号：US09696524

申请日：2000-10-23

申请人： Ji Su ,  Joycelyn S. Harrison ,  Terry L. St. Clair

发明人： Ji Su ,  Joycelyn S. Harrison ,  Terry L. St. Clair

IPC分类号： H01L4109

CPC分类号： F03G7/06 ,  F03G7/065 ,  H01L41/094 ,  H01L41/193 ,  Y10S310/80

摘要： A device for providing an electromechanical response includes two polymeric webs bonded to each other along their lengths. At least one polymeric web is activated upon application thereto of an electric field and exhibits electrostriction by rotation of polar graft moieties within the polymeric web. In one embodiment, one of the two polymeric webs in an active web upon application thereto of the electric field, and the other polymeric web is a non-active web upon application thereto of the electric field. In another embodiment, both of the two polymeric webs are capable of being active webs upon application thereto of the electric field. However, these two polymeric webs are alternately activated and non-activated by the electric field.

摘要翻译： 用于提供机电响应的装置包括沿其长度彼此结合的两个聚合物网。 至少一个聚合物纤维网在施加电场时被激活，并且通过旋转聚合物网内的极性接枝部分显示电致伸缩。 在一个实施方案中，当施加到电场上时，活性纤维网中的两个聚合物网中的一个是电场施加时的非活性纤维网。 在另一个实施方案中，两个聚合物网络都可以在施加到电场上时成为活性纤维网。 然而，这两个聚合物网络被电场交替活化并且不被活化。

公开(公告)号：US6114156A

公开(公告)日：2000-09-05

申请号：US742068

申请日：1996-10-31

申请人： Patricia R. McDaniel ,  Terry L. St. Clair

发明人： Patricia R. McDaniel ,  Terry L. St. Clair

IPC分类号： A61K8/19 ,  A61K8/00 ,  A61K8/11 ,  A61K8/25 ,  A61K8/28 ,  A61K8/29 ,  A61K8/31 ,  A61K8/34 ,  A61K8/72 ,  A61K8/88 ,  A61K8/92 ,  A61Q17/00 ,  A61Q19/00 ,  C08J3/21 ,  C08K9/08 ,  C09C1/30 ,  C09C1/36 ,  C09C3/10 ,  C09D7/12 ,  C09D11/02 ,  D01F1/10 ,  D01F6/74 ,  D21H17/55 ,  D21H17/67 ,  D21H17/69 ,  C12P13/00 ,  C07D209/12

CPC分类号： C09D11/03 ,  A61K8/11 ,  A61K8/25 ,  A61K8/28 ,  A61K8/29 ,  A61K8/34 ,  A61K8/88 ,  A61K8/92 ,  A61Q19/00 ,  C08K9/08 ,  C09D7/1225 ,  D01F1/10 ,  D01F6/74 ,  D21H17/69 ,  A61Q17/00 ,  C08K3/22 ,  C08K9/10 ,  C08L79/08 ,  D21H17/55 ,  D21H17/675 ,  Y10T428/25

摘要： Polymer encapsulated metal oxide particles are prepared by combining a polyamide acid in a polar aprotic solvent with a metal alkoxide solution. The polymer was imidized and the metal oxide formed simultaneously in a refluxing organic solvent. The resulting polymer-metal oxide is an intimately mixed commingled blend, possessing synergistic properties of both the polymer and preceramic metal oxide. The encapsulated metal oxide particles have multiple uses including, being useful in the production of skin lubricating creams, weather resistant paints, as a filler for paper, making ultraviolet light stable filled printing ink, being extruded into fibers or ribbons, and coatings for fibers used in the production of composite structural panels.

摘要翻译： 通过将极性非质子溶剂中的聚酰胺酸与金属醇盐溶液组合来制备聚合物包封的金属氧化物颗粒。 将聚合物酰亚胺化，同时在回流有机溶剂中形成金属氧化物。 所得聚合物 - 金属氧化物是紧密混合的混合共混物，具有聚合物和陶瓷前体金属氧化物的协同性质。 包封的金属氧化物颗粒具有多种用途，包括用于生产皮肤润滑霜，耐候性油漆，作为纸张的填料，制备紫外线稳定的填充印刷油墨，挤出成纤维或带状物，以及用于所用纤维的涂层 在复合结构板的生产中。

公开(公告)号：US6084000A

公开(公告)日：2000-07-04

申请号：US394534

申请日：1999-09-10

申请人： Erik S. Weiser ,  Terry L. St. Clair ,  Yoshiaki Echigo ,  Hisayasu Kaneshiro

发明人： Erik S. Weiser ,  Terry L. St. Clair ,  Yoshiaki Echigo ,  Hisayasu Kaneshiro

IPC分类号： B01J13/04 ,  C08J9/02 ,  C08J9/32 ,  C08J9/36

CPC分类号： C08J9/32 ,  B01J13/04 ,  C08J2379/08 ,  Y10S264/06

摘要： A shaped article composed of an aromatic polyimide has a hollow, essentially spherical structure and a particle size of about 100 to about 1500 .mu.m, a density of about 1 to about 6 pounds/ft.sup.3 and a volume change of 1 to about 20% by a pressure treatment of 30 psi for 10 minutes at room temperature. A syntactic foam, made of a multiplicity of the shaped articles which are bonded together by a matrix resin to form an integral composite structure, has a density of about 3 to about 30 pounds/ft.sup.3 and a compression strength of about 100 to about 1400 pounds/in.sup.2.

摘要翻译： 由芳族聚酰亚胺组成的成形制品具有中空的，基本上为球形的结构，并且具有约100至约1500μm的粒度，约1至约6磅/ ft 3的密度和1至约20％的体积变化，由 在室温下压力处理30psi 10分钟。 由多个成形制品制成的复合泡沫体，其通过基质树脂粘合在一起以形成整体复合结构，其密度为约3至约30磅/英3 3，压缩强度为约100至约1400磅 / in2。

公开(公告)号：US5789025A

公开(公告)日：1998-08-04

申请号：US772052

申请日：1996-12-09

申请人： Terry L. St. Clair

发明人： Terry L. St. Clair

IPC分类号： C08L83/04 ,  D06N3/00 ,  D06N3/12 ,  B05D5/00

CPC分类号： D06N3/128 ,  C08L83/04 ,  D06N3/0059 ,  D06N3/125 ,  C08G77/12 ,  C08G77/18 ,  C08G77/20 ,  Y10T428/31663

摘要： A waterproof and breathable, fire-resistant laminate is provided for use in tents, garments, shoes, and covers, especially in industrial, military and emergency situations. The laminate permits water vapor evaporation while simultaneously preventing liquid water penetration. Further, the laminate is fire-resistant and significantly reduces the danger of toxic compound production when exposed to flame or other high heat source. The laminate may be applied to a variety of substrates and is comprised of a silicone rubber and plurality of fire-resistant, inherently thermally-stable polyimide particles.

公开(公告)号：US5338826A

公开(公告)日：1994-08-16

申请号：US954108

申请日：1992-09-28

申请人： Anne K. St. Clair ,  Terry L. St. Clair ,  William P. Winfree

发明人： Anne K. St. Clair ,  Terry L. St. Clair ,  William P. Winfree

IPC分类号： C08G73/10 ,  B05D5/06 ,  B32B27/00

CPC分类号： C08G73/1007 ,  Y10T428/31681 ,  Y10T428/31721

摘要： A structure which is effective as an electrical insulator or as a transmitter-receiver of electromagnetic energy is prepared by providing a suitable substrate and covering the substrate with an adhering layer of a low dielectric, high temperature, linear aromatic polyimide. This polyimide is prepared by:(1) selecting aromatic diamine and aromatic dianhydride reactants to meet at least two of the following three conditions:(a) a reactant must have minimal permanent or inducible electrical dipolar characteristics as a result of the presence of pendant or bridging groups therein;(b) a reactant must impart a high degree of free volume to the polymer caused by inefficient chain packing therein in the solid state as a result of the presence of pendant or bridging groups therein; and(c) a reactant must have fluorine atoms chemically attached thereto; and(2) chemically combining equimolar quantities of the aromatic diamine and aromatic dianhydride reactants in a solvent to form a high molecular weight polyamic acid solution, and converting the high molecular weight polyamic acid to the corresponding low dielectric, high temperature linear aromatic polyimide.

摘要翻译： 作为电绝缘体或作为电磁能的发射器 - 接收器有效的结构通过提供合适的衬底并用低电介质，高温线性芳族聚酰亚胺的粘附层覆盖衬底来制备。 该聚酰亚胺通过以下方法制备：（1）选择芳族二胺和芳族二酐反应物以满足以下三个条件中的至少两个：（a）反应物必须具有最小的永久或可诱导的电偶极特性，这是由于存在侧基或 桥接基团; （b）由于在其中存在侧基或桥连基团，反应物必须赋予聚合物在固态中由于无效的链填料而导致的高度的自由体积; 和（c）反应物必须具有化学连接的氟原子; 和（2）将等摩尔量的芳族二胺和芳族二酐反应物在溶剂中化学组合以形成高分子量聚酰胺酸溶液，并将高分子量聚酰胺酸转化为相应的低电介质，高温线性芳族聚酰亚胺。

公开(公告)号：US5218083A

公开(公告)日：1993-06-08

申请号：US429574

申请日：1989-10-31

申请人： Margaret K. Gerber ,  Terry L. St. Clair ,  J. Richard Pratt ,  Anne K. St. Clair

发明人： Margaret K. Gerber ,  Terry L. St. Clair ,  J. Richard Pratt ,  Anne K. St. Clair

IPC分类号： C08G73/10

CPC分类号： C08G73/1085 ,  C08G73/1039 ,  C08G73/106 ,  C08G73/1064

摘要： High performance, thermooxidatively stable polyimides are prepared by reacting aromatic diamines with pendant trifluoromethyl groups and dianhydrides in an amide solvent to form a poly(amic acid), followed by cyclizing the poly(amic acid) to form the corresponding polyimide, which has the following general structure: ##STR1##

摘要翻译： 通过使芳族二胺与侧基三氟甲基和二酐在酰胺溶剂中反应形成聚（酰胺酸）制备高性能，热氧化稳定的聚酰亚胺，然后使聚（酰胺酸）环化形成相应的聚酰亚胺，其具有以下 一般结构：其中R是任何芳族或取代的芳族基团，Ar是任何芳族或取代的芳族基团，n APPROX 10-100。

公开(公告)号：US4713439A

公开(公告)日：1987-12-15

申请号：US834978

申请日：1986-02-27

申请人： Terry L. St. Clair ,  Shubha Maudgal ,  J. Richard Pratt

发明人： Terry L. St. Clair ,  Shubha Maudgal ,  J. Richard Pratt

IPC分类号： C08G69/44 ,  C08G69/26

CPC分类号： C08G69/44

摘要： A novel series of polymers and copolymers based on a polyimide backbone with the incorporation of carbonate moieties along the backbone. The process for preparing these polymers and copolymers is also disclosed as is a novel series of dinitrodiphenyl carbonates and diaminodiphenyl carbonates. The novel polymers and copolymers exhibit high temperature capability and because of the carbonate unit, many exhibit a high degree of order and/or crystallinity.

摘要翻译： 一种基于聚酰亚胺骨架的新型聚合物和共聚物系列，其中沿骨架加入碳酸酯部分。 还公开了制备这些聚合物和共聚物的方法，是一系列新的一系列二硝基二苯基碳酸酯和二氨基二苯基碳酸酯。 新型聚合物和共聚物表现出高温能力，并且由于碳酸酯单元，许多表现出高度的顺序和/或结晶度。