公开(公告)号：US20080048150A1

公开(公告)日：2008-02-28

申请号：US11892102

申请日：2007-08-20

申请人： Tomoya Hosoda ,  Satoshi Okamoto ,  Shiro Katagiri

发明人： Tomoya Hosoda ,  Satoshi Okamoto ,  Shiro Katagiri

IPC分类号： B29C45/00 ,  C09K19/54

CPC分类号： C09K19/3809 ,  B29C43/18 ,  B29K2105/0079 ,  C08K3/22 ,  H05K1/0373 ,  H05K2201/0141 ,  H05K2201/0209 ,  H05K2201/09118

摘要： A method for producing a molded article is provided, the method comprising the step of press-molding a resin composition comprising a filler and a powder of a liquid crystal polymer having a flow starting temperature of 280° C. or higher and an average particle size of 0.5 to 50 μm. In the molded article obtained by the method of the present invention, the functions provided by the filler, such as thermal conductivity and dielectric property, can be effectively and uniformly expressed.

摘要翻译： 提供了一种成型体的制造方法，其特征在于，包括将流动开始温度为280℃以上的液晶聚合物的填料和粉末的树脂组合物进行加压成型，平均粒径 为0.5〜50um。 在通过本发明的方法获得的模塑制品中，可以有效地均匀地表现由填料提供的诸如导热性和介电性能的功能。

公开(公告)号：US20070057236A1

公开(公告)日：2007-03-15

申请号：US11483673

申请日：2006-07-11

申请人： Tomoya Hosoda ,  Satoshi Okamoto ,  Mitsuo Maeda

发明人： Tomoya Hosoda ,  Satoshi Okamoto ,  Mitsuo Maeda

IPC分类号： H01B1/12

CPC分类号： H01B1/24 ,  H01M8/0221 ,  H01M8/0226 ,  H01M8/0232

摘要： The present invention provides a conductive resin composition comprising a liquid crystalline polyester which comprises the following structure units having the formulas (i), (ii) and (iii), and has an aromatic group having 2,6-naphthalenediyl group in a ratio of not less than 5% by mole; and at least one filler selected from a metal oxide conductive filler and a carbon conductive filler. According to the present invention, the composition is easy to mold and can give molded products having high hydrolysis resistance. The resulting molded products are hardly to lower the strength even if they are exposed to high temperature and humid condition, and can be suitably used for a separator in a fuel cell.

摘要翻译： 本发明提供一种包含液晶聚酯的导电树脂组合物，其包含具有式（i），（ii）和（iii）的以下结构单元，并且具有2,6-萘二基的芳族基团， 不低于5摩尔％ 和选自金属氧化物导电填料和碳导电填料的至少一种填料。 根据本发明，组合物易于模塑，并且可以得到具有高耐水解性的模制品。 所得到的成型体即使暴露在高温高湿条件下也难以降低强度，能够适合用于燃料电池中的隔膜。

公开(公告)号：US07063892B2

公开(公告)日：2006-06-20

申请号：US10736635

申请日：2003-12-17

申请人： Satoshi Okamoto ,  Tomoya Hosoda ,  Shinji Ohtomo

发明人： Satoshi Okamoto ,  Tomoya Hosoda ,  Shinji Ohtomo

IPC分类号： B32B25/08 ,  B32B25/12 ,  B32B27/00 ,  B32B27/06 ,  C08G63/00 ,  C08F63/06 ,  C08F2/00

CPC分类号： B32B15/08 ,  B32B7/12 ,  B32B27/36 ,  B32B2305/55 ,  B32B2310/14 ,  B32B2457/08 ,  C08G63/605 ,  C09K19/3809 ,  Y10T428/31558 ,  Y10T428/31565 ,  Y10T428/31786

摘要： An aromatic liquid-crystalline polyester having a small dielectric loss in a wide frequency region is provided. An aromatic liquid-crystalline polyester is provided that can manufacture a film having a small volume expansion by heating. An aromatic liquid-crystalline polyester substantially comprising a repeating structural unit originating in 2-hydroxy-6-naphthoic acid 30 to 80 mol %, a repeating structural unit originating in aromatic diol 35 to 10 mol %, and a repeating structural unit originating in aromatic dicarboxylic acid 35 to 10 mol %.

摘要翻译： 提供了在宽频率区域具有小介电损耗的芳族液晶聚酯。 提供一种芳族液晶聚酯，其可以通过加热制造具有小体积膨胀的膜。 一种芳香族液晶聚酯，其基本上包含30-80摩尔％的2-羟基-6-萘甲酸的重复结构单元，35-10摩尔％的芳族二醇的重复结构单元和源自芳香族的重复结构单元 二羧酸35〜10摩尔％。

公开(公告)号：US07014921B2

公开(公告)日：2006-03-21

申请号：US10979120

申请日：2004-11-03

申请人： Satoshi Okamoto ,  Tomoya Hosoda

发明人： Satoshi Okamoto ,  Tomoya Hosoda

IPC分类号： B32B27/06 ,  C08G63/18

CPC分类号： C08G63/605 ,  Y10T428/31681 ,  Y10T428/31786

摘要： An aromatic liquid-crystalline polyester with good moldability into a film is provided. The resulting film has small dielectric loss. The polyester comprises repeating units represented by formulae (I), (II), (III) and (IV), and the molar amounts of repeating units (I)–(IV) are 40–74.8%, 12.5–30%, 12.5–30% and 0.2–15%, respectively, wherein the molecular amounts of repeating units (III) and (IV) satisfy the relation of (III)/[(III)+(IV)]≧0.5.

摘要翻译： 提供了具有良好成型性的薄膜的芳族液晶聚酯。 所得膜具有小的介电损耗。 聚酯包含由式（I），（II），（III）和（IV）表示的重复单元，重复单元（I） - （IV）的摩尔量为40-74.8％，12.5-30％，12.5 -30％和0.2-15％，其中重复单元（III）和（IV）的分子量满足（III）/ [（III）+（IV）]> = 0.5的关系。

公开(公告)号：US08492500B2

公开(公告)日：2013-07-23

申请号：US13556963

申请日：2012-07-24

申请人： Tomoya Hosoda ,  Eiji Hosoda ,  Masanobu Matsubara

发明人： Tomoya Hosoda ,  Eiji Hosoda ,  Masanobu Matsubara

IPC分类号： C08G63/02 ,  C08G64/00

CPC分类号： C09K19/3809 ,  C08G63/605 ,  C08G63/80 ,  C08G63/87

摘要： The present invention provides a method for producing a liquid-crystalline polyester, the method comprising: a step of melt-polymerizing raw monomers in a melt polymerization vessel to obtain a polymer melt; a step of drawing the polymer melt from the melt polymerization vessel and granulating the polymer melt to obtain a granulate; a step of allowing the granulate to undergo solid phase polymerization in a solid phase polymerization vessel to obtain a solid phase polymer; and a step of making an impact on the solid phase polymerization vessel containing the solid phase polymer, and taking out the solid phase polymer from the solid phase polymerization vessel.

摘要翻译： 本发明提供了一种液晶聚酯的制造方法，该方法包括：在熔融聚合容器中熔融聚合原料单体以获得聚合物熔体; 从熔融聚合容器中拉伸聚合物熔体并使聚合物熔体成粒以获得颗粒的步骤; 使该颗粒在固相聚合釜中进行固相聚合以获得固相聚合物的步骤; 以及对含有固相聚合物的固相聚合容器产生影响，从固相聚合容器中取出固相聚合物的步骤。

公开(公告)号：US08501897B2

公开(公告)日：2013-08-06

申请号：US13556871

申请日：2012-07-24

申请人： Tomoya Hosoda ,  Eiji Hosoda ,  Masanobu Matsubara

发明人： Tomoya Hosoda ,  Eiji Hosoda ,  Masanobu Matsubara

IPC分类号： C08G63/02 ,  C08G64/00

CPC分类号： C09K19/3809 ,  C08G63/605 ,  C08G63/87

摘要： The present invention provides a method for producing a liquid-crystalline polyester, which comprises melt-polymerizing monomers in a reactor having a draw outlet to obtain a polymer melt and drawing the polymer melt through the draw outlet, characterized in that the monomers comprise a compound selected from an aromatic hydroxycarboxylic acid and derivatives thereof, a compound selected from an aromatic dicarboxylic acid and derivatives thereof and a compound selected from an aromatic diol, an aromatic hydroxyamine, an aromatic diamine and derivatives thereof; the amount of units derived from a compound containing a 1,2-phenylene and/or a 1,3-phenylene skeleton(s) in the polyester is from 0 to 10 mol %; the melt polymerization is performed in the presence of a heterocyclic compound containing two or more nitrogen atoms; and the polymer melt has a flow initiation temperature of from 220 to 250° C.

摘要翻译： 本发明提供一种液晶聚酯的制造方法，其包括在具有拉出口的反应器中使单体熔融聚合以获得聚合物熔体并通过拉出口拉伸聚合物熔体，其特征在于，所述单体包含化合物 选自芳族羟基羧酸及其衍生物，选自芳族二羧酸及其衍生物的化合物和选自芳族二醇，芳族羟胺，芳族二胺及其衍生物的化合物; 衍生自聚酯中含有1,2-亚苯基和/或1,3-亚苯基骨架的化合物的单元的量为0至10mol％; 在含有两个或更多个氮原子的杂环化合物的存在下进行熔融聚合; 聚合物熔体的起始温度为220-250℃。