摘要:
A method for producing a molded article is provided, the method comprising the step of press-molding a resin composition comprising a filler and a powder of a liquid crystal polymer having a flow starting temperature of 280° C. or higher and an average particle size of 0.5 to 50 μm. In the molded article obtained by the method of the present invention, the functions provided by the filler, such as thermal conductivity and dielectric property, can be effectively and uniformly expressed.
摘要:
A method for producing a polyester is provided, the method comprising the step of reacting an acylated product of a compound having at least one phenolic hydroxyl group with an aromatic carboxylic acid under microwave irradiation. Polyester can be produced by the method in a relatively short period of time at high temperature with a suppressed thermal hysteresis.
摘要:
An aromatic liquid-crystalline polyester with good moldability into a film is provided. The resulting film has small dielectric loss. The polyester comprises repeating units represented by formulae (I), (II), (III) and (IV), and the molar amounts of repeating units (I)-(IV) are 40-74.8%, 12.5-30%, 12.5-30% and 0.2-15%, respectively, wherein the molecular amounts of repeating units (III) and (IV) satisfy the relation of (III)/[(III)+(IV)]≧0.5.
摘要:
An object of the present invention is to provide a back sheet for a solar cell that improves weather resistance while also being advantageous in terms of cost. In a back sheet 7 for a solar cell of a preferred embodiment, a liquid crystal polyester that composes a liquid crystal polyester base material is formed of structural units represented by the following formulas (1), (2) and (3). When a total of divalent aromatic groups Ar1, Ar2 and Ar3 contained in the formulas (1), (2) and (3) is defined to be 100 mol %, a 2,6-naphthalenediyl group is contained at 40 mol % or more therein: —O—Ar1—CO— (1) —CO—Ar2—CO— (2) —O—Ar3—O— (3) (wherein, Ar1 represents one or more types of groups selected from the group consisting of a 2,6-naphthalenediyl group, 1,4-phenylene group and 4,4′-biphenylene group, and Ar2 and Ar3 respectively and independently represent one or more types of groups selected from the group consisting of a 2,6-naphthalenediyl group, 1,4-phenylene group, 1,3-phenylene group and 4,4′-biphenylene group).
摘要:
The present invention provides a liquid crystalline polymer composition comprising (A) a polymer including units of formula (I), and units of formula (II) and/or units of formula (III), the units of formula (I) being included in 15-80% by mol, based on the total units [(I)+(II)+(III)]; and (B) a polymer (B) including units of formula (IV), formula (V) and the formula (VI), each of units being included in 30-80% by mol, 10-35% by mol and 10-35% by mol, respectively, based on the total units [(IV)+(V)+(VI)], the component (B) being included in 5-80% by weight based on the total weight of the components (A) and (B); wherein (I) —(VI) are —OC—Ar1-0-, —O—Ar2—O—, —OC—Ar3—CO—, —OC—Ar4—O—, —O—Ar5—X— and —OC—Ar6—CO—, respectively.
摘要:
A liquid-crystalline polymer composition with less warpage not only in molding but also in a high temperature treatment conducted after molding is provided. The liquid-crystalline polymer comprises (i) 30 to 95% by weight of a first liquid-crystalline polymer having a deflection temperature under load of 200° C. or higher and (ii) 5 to 70% by weight of a second liquid-crystalline polymer having a deflection temperature under load lower than that of the first liquid-crystalline polymer, a melting point from 270° C. to lower than 400° C. and a flow-beginning temperature of 270° C. or higher.
摘要:
A resin composition comprising an inorganic material with a thermal conductivity of 10 W/mK or higher at a temperature of 20° C. and an aromatic polyester is provided. The aromatic polyester may have structural units derived from (I) 2-hydroxy-6-naphthoic acid, (II) a compound selected from hydroquinone, 4,4′-dihydroxybiphenyl and 2,6-dihydroxynaphthalene, (III) naphthalenedicarboxylic acid and (IV) a compound selected from terephthalic acid, isophthalic acid and phthalic acid.
摘要:
The invention relates to an insulating film for an electromagnetic coil which is composed of a liquid crystal polyester, in which the liquid crystal polyester has a structural unit represented by the following formula (1), a structural unit represented by the following formula (2), and a structural unit represented by the following formula (3), and the amount of the structural units including a 2,6-naphthalenediyl group is 40 mol % or more with respect to the total amount of all the structural units. —O—Ar1—CO—, (1) —CO—Ar2—CO—, and (2) —O—Ar3—O— (3) (In the formulae, Ar1 represents a 2,6-naphthalenediyl group, a 1,4-phenylene group, or a 4,4′-biphenylylene group; Ar2 and Ar3 respectively represent a 2,6-naphthalenediyl group, a 1,4-phenylene group, a 1,3-phenylene group, or a 4,4′-biphenylylene group; and hydrogen atoms in the groups represented by Ar1, Ar2, and Ar3 may be substituted respectively with a halogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl group having 6 to 20 carbon atoms.)
摘要:
The present invention provides a liquid-crystalline polyester having a structural unit represented by the formula (i), a structural unit represented by the formula (ii) and a structural unit represented by the formula (iii): wherein Ar1 is, at each occurrence, a member selected from the group consisting of a 2,6-naphthalenediyl group, a 1,4-phenylene group and a 4,4′-biphenylene group; and Ar2 and Ar3 are, at each occurrence, a member selected from the group consisting of a 2,6-naphthalenediyl group, a 1,4-phenylene group, a 1,3-phenylene group and a 4,4′-biphenylene group; wherein 40% by mole or more of all the groups Ar1, Ar2 and Ar3 are 2,6-naphthalenediyl groups; and wherein the polyester has a flow initiation temperature of from about 280 to about 320° C.
摘要:
The present invention provides a resin composition comprising a liquid crystal polymer and a filler comprising a composite oxide containing Ba, Sm, and Ti. The resin composition can provide a molded article which has excellent dielectric characteristics and is excellent in dimension stability.