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21.发明申请Curable composition and methods for improving recovery properties and creep properties 有权用于改善回收性能和蠕变性能的可固化组合物和方法公开(公告)号：US20060128919A1
公开(公告)日：2006-06-15
申请号：US10533309
申请日：2003-10-22
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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公开(公告)号：US20050171315A1
公开(公告)日：2005-08-04
申请号：US11091509
申请日：2005-03-29
CPC分类号： C08L83/04 , C08K5/09 , C09K3/1018
摘要： The present invention provides a curable composition which has a high recovery ratio, a high creep resistance, a practical curability and a storage stability. The present invention relates to a curable composition comprising a reactive silicon group-containing organic polymer (A) and a carboxylic acid (B), (I) wherein the composition comprises, as the carboxylic acid (B), a carboxylic acid (C) in which the carbon atom adjacent to the carbonyl group is a quaternary carbon atom; and/or (II) wherein the composition comprises a metal carboxylate (D) formed between a carboxylic acid in which the carbon atom adjacent to the carbonyl group is a quaternary carbon atom and a metal atom of 208 or less in atomic weight.
摘要翻译： 本发明提供了一种具有高回收率，高抗蠕变性，实用的固化性和储存稳定性的可固化组合物。 本发明涉及包含含活性硅基团的有机聚合物（A）和羧酸（B），（I）的可固化组合物，其中组合物包含羧酸（B），羧酸（C） 其中与羰基相邻的碳原子是季碳原子; 和/或（II）其中所述组合物包含在其中与羰基相邻的碳原子为季碳原子的碳酸酯和原子量为208以下的金属原子之间形成的金属羧酸盐（D）。
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23.发明授权Curable composition and method for improving recovery properties and creep properties 有权改善回收性能和蠕变性能的组合物和方法公开(公告)号：US08586688B2
公开(公告)日：2013-11-19
申请号：US13053181
申请日：2011-03-21
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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公开(公告)号：US20130217828A1
公开(公告)日：2013-08-22
申请号：US13816346
申请日：2011-08-05
IPC分类号： C08L71/02 , C09J171/02
CPC分类号： C08L71/02 , C08G65/336 , C08L43/04 , C09J143/04 , C09J171/02 , C09K3/10 , C09K2200/0625 , C09K2200/0657 , C08L33/06
摘要： An object of the present invention is to provide a curable composition that can be used as sealing materials, adhesives, and the like, has excellent curing properties, and gives a cured product excellent in elongation properties. The object can be attained by means of a curable composition comprising: a reactive silyl group-containing polyether polymer (A) that contains a reactive silyl group with high activity (e.g., (ClCH2)(CH3O)2Si—, (CH3OCH2)(CH3O)2Si—, or CH3(CH3O)2Si—CH2—NH—C(═O)—); and a reactive silyl group-containing polyether polymer (B) that contains a reactive silyl group (e.g., CH3(CH3O)2Si— or (CH3O)3Si—) different from that mentioned above and/or a (meth)acrylic polymer (C) containing a reactive silyl group that is not particularly limited.
摘要翻译： 本发明的目的是提供可用作密封材料，粘合剂等的固化性组合物，具有优异的固化性能，并得到伸长性优异的固化物。 该目的可以通过一种可固化组合物来实现，该组合物包含：含有活性高的活性甲硅烷基的反应性含甲硅烷基的聚醚聚合物（A）（例如（ClCH 2）（CH 3 O）2 Si 3，（CH 3 OCH 2） ）2Si-或CH 3（CH 3 O）2 Si-CH 2 -NH-C（= O） - ）; 和含有与上述不同的反应性甲硅烷基的聚醚聚合物（B）和/或（甲基）丙烯酸类聚合物（C）的反应性甲硅烷基（例如CH 3（CH 3 O）2 Si-或（CH 3 O） ），其没有特别限定。
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25.发明申请CURABLE COMPOSITION AND METHOD FOR IMPROVING RECOVERY PROPERTIES AND CREEP PROPERTIES 有权可固化组合物和改善回收性能和韧性的方法公开(公告)号：US20110172372A1
公开(公告)日：2011-07-14
申请号：US13053181
申请日：2011-03-21
CPC分类号： C08G65/336 , C08L101/10 , C09K3/1018
摘要： Disclosed are a curable composition characterized by using a curable composition including an organic polymer (A1) having one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds in which the one or more silicon-containing functional groups capable of cross-linking by forming siloxane bonds are silicon-containing functional groups each having three or more hydrolyzable groups on one or more silicon atoms thereof; and a method for controlling the recovery properties, durability and creep resistance of the cured article. Herewith, the present invention provides a curable composition capable of giving a cured article excellent in recovery properties, durability and creep resistance, and a method for controlling the recovery properties, durability and creep resistance of the cured article.
摘要翻译： 公开了一种可固化组合物，其特征在于使用包含具有一个或多个能够通过形成硅氧烷键交联的含硅官能团的有机聚合物（A1）的固化性组合物，其中所述一个或多个能够交叉的含硅官能团 通过形成硅氧烷键的连接是在其一个或多个硅原子上具有三个或更多个可水解基团的含硅官能团; 以及用于控制固化制品的回收性能，耐久性和抗蠕变性的方法。 因此，本发明提供了能够提供回收性，耐久性和抗蠕变性优异的固化物的固化性组合物，以及控制固化物的回收性，耐久性和抗蠕变性的方法。
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公开(公告)号：US07910681B2
公开(公告)日：2011-03-22
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： 通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，其特征在于 在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的 组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时 ，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。
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公开(公告)号：US20080319152A1
公开(公告)日：2008-12-25
申请号：US11579553
申请日：2005-04-25
IPC分类号： C08G77/04
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having good curability and adhesion by use of a non-organotin catalyst.[Means to Solve] A curable composition comprising (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of from 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) in the composition to the total mole (b) of silicon atoms of the component (C) in the composition is more than 0.4.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。 [解决方案]一种可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种 和（C）含有水解性硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b） 组合物中组分（B）的原子与组合物中组分（C）的硅原子的总摩尔数（b）大于0.4。
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公开(公告)号：US20080287636A1
公开(公告)日：2008-11-20
申请号：US11579630
申请日：2005-04-25
IPC分类号： C08G77/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [PROBLEMS] There is provided a curable composition having good curability and adhesiveness. [MEANS FOR SOLVING] A curable composition by comprising (A) an reactive silicon group-containing organic polymer,(B) a titanium chelate represented by the general formula (1) or (2),(C) a high molecular weight plasticizer having a number average molecular weight of 1000 to 15000:General Formula (1): wherein each of n R1's is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2's is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1's and (4-n) A2's is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2, or 3. General Formula wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group havimg 1 to 20 carbon atoms.
摘要翻译： [问题]提供了具有良好的固化性和粘合性的固化性组合物。 [解决方案]一种可固化组合物，其包含（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物，（C）具有 数均分子量为1000〜15000：通式（1）：其中n R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4 -n）R 2独立地为氢原子或取代或未取代的碳原子数1〜20的烃基，（4-n）A 1〜 和（4-n）A 2独立地为-R 3或-OR 3，其中R 3为 是具有1至20个碳原子的取代或未取代的烃基，n为1,2或3.其中R 2，A 1和A 2的通式为 2 与上述定义相同，R 4是取代或未取代的2至20碳a的二价烃基 手铐
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公开(公告)号：US20080076878A1
公开(公告)日：2008-03-27
申请号：US11579551
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好的固化性和粘合性的固化性组合物。 [解决问题的方法]可固化组合物包含（A）具有通过形成硅氧烷键而能够交联的具有反应性硅基团的含硅基团的有机聚合物，（B）选自钛催化剂， 铝催化剂和锆催化剂，和（C）含有可水解硅基并且分子量为100〜1000的低分子量化合物，其特征在于钛的总摩尔（a）的比（a / b） 组分（B）的原子，铝原子和锆原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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公开(公告)号：US20070203297A1
公开(公告)日：2007-08-30
申请号：US11547028
申请日：2005-03-18
IPC分类号： C08L71/02
CPC分类号： C08F293/005 , C08K5/09 , C08L43/04 , C08L53/00 , C08L71/02 , C09D153/00 , C08L83/12 , C08L2666/22 , C08L2666/02
摘要： The present invention has its object to provide a curable composition which has good curability and adhesiveness while containing an organotin-free catalyst. The present invention provides a one package curable composition which comprises (A) a polyoxyalkylene polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a (meth)acrylic ester polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond and compatible with the component (A), and (C) (c1) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and/or (c2) a metal carboxylate of which the carbon atom adjacent to a carbonyl group is a quaternary carbon.
摘要翻译： 本发明的目的是提供一种含有无机锡催化剂的固化性和粘合性优异的固化性组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物，（B）具有含硅基团的（甲基）丙烯酸酯聚合物， 通过形成硅氧烷键并与组分（A）相容的交联，和（C）（c1）与羰基相邻的碳原子为季碳的羧酸和/或（c2）羧酸金属的 其中与羰基相邻的碳原子是季碳。
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