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公开(公告)号：US07960459B2
公开(公告)日：2011-06-14
申请号：US12279466
申请日：2007-02-09
申请人： Noriko Noro , Toshihiko Okamoto , Ayako Yano , Yoshikazu Morii
发明人： Noriko Noro , Toshihiko Okamoto , Ayako Yano , Yoshikazu Morii
IPC分类号： C07C277/08 , C07C279/18 , C08C19/30
CPC分类号： C09K3/1018 , C08G65/336 , C08K5/0016 , C08K5/31 , C08L71/02 , C08L101/10 , C08L2666/22 , C09D201/10 , C09J133/14
摘要： The present invention has its object to provide a curable composition which comprises a reactive silyl group-containing organic polymer, does not contain, as a silanol condensation catalyst, any organotin type curing catalyst currently of concern because of the toxic feature thereof, is excellent in surface curability and depth curability and, further, can provide cured products excellent in adhesiveness; the above object can be achieved by a curable composition which comprises: an organic polymer (A) containing a silicon-containing group capable of crosslinking under siloxane bond formation; and a guanidine compound (B-1), as a silanol condensation catalyst (B), represented by the general formula (1): R1N═C(NR12)2 (1) (wherein one of the five R1s is an aryl group and the other four R1s each independently is a hydrogen atom or a hydrocarbon group in which the carbon atom at position 1 is saturated).
摘要翻译： 本发明的目的是提供一种可固化组合物，其包含含有反应性甲硅烷基的有机聚合物，由于其毒性特征，目前令人关注的任何有机锡型固化催化剂不含硅烷醇缩合催化剂，因此其优异 表面固化性和深度固化性，并且还可以提供粘合性优异的固化物; 上述目的可以通过一种可固化组合物来实现，该组合物包括：含硅氧烷键形成交联的含硅基团的有机聚合物（A） 和由通式（1）表示的硅烷醇缩合催化剂（B）的胍化合物（B-1）：R1N = C（NR12）2（1）（其中5个R 1中的一个为芳基， 另外四个R 1各自独立地为氢原子或第1位的碳原子饱和的烃基）。
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公开(公告)号：US07910681B2
公开(公告)日：2011-03-22
申请号：US11579587
申请日：2005-04-25
IPC分类号： C08G77/08 , C08G77/46 , C08G77/48 , C08L83/14 , C08F283/06
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： There is provided a curable composition having good adhesion by using a non-organotin catalyst.The curable composition comprises (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and is characterized in that a stress at 50% tension is within a range from 0.01 MPa to 0.20 MPa, when determined by adding and mixing 1.5 parts of tin octylate, 0.25 part by weight of laurylamine and 0.6 part by weight of pure water to 100 parts by weight of the component (A), subjecting the mixture to centrifugal defoaming, pouring the mixture carefully into a polyethylene frame not to mix air bubbles thereto, aging the mixture at 23° C. for one hour, and further at 70° C. for 20 hours, punching the obtained 3 mm thick cured sheet according to JIS K6251 to obtain No. 3 dumbbell, and carrying out a tension test (tensile speed: 200 mm/min) at 23° C. at 50% RH.
摘要翻译： 通过使用非有机锡催化剂提供具有良好粘附性的可固化组合物。 可固化组合物包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物和（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种，其特征在于 在50％张力下的应力在0.01MPa至0.20MPa的范围内，当通过将1.5份辛酸锡，0.25重量份的月桂胺和0.6重量份的纯水加入并混合到100重量份的 组分（A），将混合物进行离心脱泡，将混合物小心地注入聚乙烯框架中，不混合气泡，将混合物在23℃下老化1小时，再在70℃下老化20小时 ，根据JIS K6251冲压得到的3mm厚的固化片，得到3号哑铃，在23℃，50％RH下进行拉伸试验（拉伸速度：200mm / min）。
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公开(公告)号：US20080319152A1
公开(公告)日：2008-12-25
申请号：US11579553
申请日：2005-04-25
IPC分类号： C08G77/04
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having good curability and adhesion by use of a non-organotin catalyst.[Means to Solve] A curable composition comprising (A) an organic polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of from 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) in the composition to the total mole (b) of silicon atoms of the component (C) in the composition is more than 0.4.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好固化性和粘合性的可固化组合物。 [解决方案]一种可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的有机聚合物，（B）选自钛催化剂，铝催化剂和锆催化剂中的一种或多种 和（C）含有水解性硅基且分子量为100〜1000的低分子量化合物，其特征在于钛原子，铝原子和锆的总摩尔数（a）的比（a / b） 组合物中组分（B）的原子与组合物中组分（C）的硅原子的总摩尔数（b）大于0.4。
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公开(公告)号：US20080287636A1
公开(公告)日：2008-11-20
申请号：US11579630
申请日：2005-04-25
IPC分类号： C08G77/00
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [PROBLEMS] There is provided a curable composition having good curability and adhesiveness. [MEANS FOR SOLVING] A curable composition by comprising (A) an reactive silicon group-containing organic polymer,(B) a titanium chelate represented by the general formula (1) or (2),(C) a high molecular weight plasticizer having a number average molecular weight of 1000 to 15000:General Formula (1): wherein each of n R1's is independently a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) R2's is independently hydrogen atom or a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, each of (4-n) A1's and (4-n) A2's is independently —R3 or —OR3 where R3 is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, n is 1, 2, or 3. General Formula wherein R2, A1 and A2 are the same as defined above, R4 is a substituted or unsubstituted divalent hydrocarbon group havimg 1 to 20 carbon atoms.
摘要翻译： [问题]提供了具有良好的固化性和粘合性的固化性组合物。 [解决方案]一种可固化组合物，其包含（A）含反应性硅基的有机聚合物，（B）由通式（1）或（2）表示的钛螯合物，（C）具有 数均分子量为1000〜15000：通式（1）：其中n R 1各自独立地为取代或未取代的碳原子数1〜20的烃基，（4 -n）R 2独立地为氢原子或取代或未取代的碳原子数1〜20的烃基，（4-n）A 1〜 和（4-n）A 2独立地为-R 3或-OR 3，其中R 3为 是具有1至20个碳原子的取代或未取代的烃基，n为1,2或3.其中R 2，A 1和A 2的通式为 2 与上述定义相同，R 4是取代或未取代的2至20碳a的二价烃基 手铐
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公开(公告)号：US20080076878A1
公开(公告)日：2008-03-27
申请号：US11579551
申请日：2005-04-25
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problems] There is provided a curable composition having good curability and adhesion by using a non-organotin catalyst.[Means to Solve Problems] The curable composition comprising (A) an organic polymer having a reactive silicon group as a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) one or more kinds selected from a titanium catalyst, an aluminum catalyst and a zirconium catalyst, and (C) a low molecular weight compound containing a hydrolyzable silicon group and having a molecular weight of 100 to 1,000, characterized in that a ratio (a/b) of the total mole (a) of titanium atoms, aluminum atoms and zirconium atoms of the component (B) to the total mole (b) of silicon atoms of the component (c) is larger than 0.08.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有良好的固化性和粘合性的固化性组合物。 [解决问题的方法]可固化组合物包含（A）具有通过形成硅氧烷键而能够交联的具有反应性硅基团的含硅基团的有机聚合物，（B）选自钛催化剂， 铝催化剂和锆催化剂，和（C）含有可水解硅基并且分子量为100〜1000的低分子量化合物，其特征在于钛的总摩尔（a）的比（a / b） 组分（B）的原子，铝原子和锆原子与组分（c）的硅原子的总摩尔数（b）大于0.08。
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公开(公告)号：US20080033087A1
公开(公告)日：2008-02-07
申请号：US11579405
申请日：2005-04-25
申请人： Toshihiko Okamoto , Masato Kusakabe
发明人： Toshihiko Okamoto , Masato Kusakabe
IPC分类号： C08J3/24
CPC分类号： C08G65/336 , C08K3/014 , C08K5/0091 , C08K5/544 , C09D171/02 , C09J171/02 , C09K3/10 , C08L101/10 , C08L71/02
摘要： [Problem] There is provided a curable composition having high thixotropy and satisfactory curability by use of a non-organotin catalyst. [Means to Solve] A curable composition comprising (A) a polyoxyalkylene polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds and/or a (meth)acrylate polymer having a silicon-containing group being capable of crosslinking by forming siloxane bonds, (B) a titanium chelate, and (C) an amide wax type thixotropy-imparting agent.
摘要翻译： [问题]提供了通过使用非有机锡催化剂具有高触变性和令人满意的固化性的可固化组合物。 [解决方案]一种可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物和/或具有含硅基团的（甲基）丙烯酸酯聚合物，其可以通过形成 硅氧烷键，（B）钛螯合物和（C）酰胺蜡型触变性赋予剂。
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公开(公告)号：US20070203297A1
公开(公告)日：2007-08-30
申请号：US11547028
申请日：2005-03-18
IPC分类号： C08L71/02
CPC分类号： C08F293/005 , C08K5/09 , C08L43/04 , C08L53/00 , C08L71/02 , C09D153/00 , C08L83/12 , C08L2666/22 , C08L2666/02
摘要： The present invention has its object to provide a curable composition which has good curability and adhesiveness while containing an organotin-free catalyst. The present invention provides a one package curable composition which comprises (A) a polyoxyalkylene polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond, (B) a (meth)acrylic ester polymer having a silicon-containing group capable of crosslinking by forming a siloxane bond and compatible with the component (A), and (C) (c1) a carboxylic acid of which the carbon atom adjacent to a carbonyl group is a quaternary carbon, and/or (c2) a metal carboxylate of which the carbon atom adjacent to a carbonyl group is a quaternary carbon.
摘要翻译： 本发明的目的是提供一种含有无机锡催化剂的固化性和粘合性优异的固化性组合物。 本发明提供一种包装可固化组合物，其包含（A）具有能够通过形成硅氧烷键交联的含硅基团的聚氧化烯聚合物，（B）具有含硅基团的（甲基）丙烯酸酯聚合物， 通过形成硅氧烷键并与组分（A）相容的交联，和（C）（c1）与羰基相邻的碳原子为季碳的羧酸和/或（c2）羧酸金属的 其中与羰基相邻的碳原子是季碳。
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公开(公告)号：US20060252903A1
公开(公告)日：2006-11-09
申请号：US10555416
申请日：2004-04-23
IPC分类号： C08G77/60
CPC分类号： C08L101/10 , C08K5/09 , C08K5/54 , C08L43/04
摘要： An object of the present invention is to provide a curing composition which is practically curable and highly adhesive even though a non-organotin compound is included as a curing catalyst. Problems involved are solved by a curing composition characterized by including (A) an organic polymer having one or more silicon-containing groups capable of cross linking by forming siloxane bonds, (B) a metal carboxylate and/or carboxylic acid, and (C) a silicon compound having a hetero atom on the carbon atom in the α or β position with respect to the silicon atom.
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29.发明授权Stable preservation method of powdered soft drink preparation and powdered soft drink preparation 失效粉状软饮料制剂和粉末软饮料制剂的稳定保存方法公开(公告)号：US06251457B1
公开(公告)日：2001-06-26
申请号：US08704731
申请日：1996-09-13
IPC分类号： A21D400
CPC分类号： A23L2/39 , A23L2/44 , A23V2002/00 , A23V2250/708 , A23V2250/0606 , A23V2250/1578 , A23V2250/1628
摘要： The present invention provides a stable preservation method of a powdered soft drink preparation, which includes adding 0.2 to 1.0% by weight of a calcium oxide and 0.02 to 2.0% by weight of a particulate silicon dioxide in the powdered soft drink preparation containing a carbohydrate and a sour agent as a main component. The powdered soft drink preparation of the present invention maintains the original powder state, color and taste, which are obtained immediately after the production, for a long period of time without causing comparatively rapid coagulation of powders, discoloration and change in taste at the time of preservation.
摘要翻译： 本发明提供一种粉状软饮料制剂的稳定保存方法，其包括在含有碳水化合物的粉状软饮料制剂中加入0.2至1.0重量％的氧化钙和0.02至2.0重量％的二氧化硅颗粒， 以酸味剂为主要成分。 本发明的粉状软饮料制剂在长时间内保持立即生产后获得的原始粉末状态，颜色和味道，而不会引起粉末相当快速的凝结，变色和变味 保存。
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公开(公告)号：US06037375A
公开(公告)日：2000-03-14
申请号：US878063
申请日：1997-06-18
申请人： Shuichi Sakamoto , Hiroshi Okamatsu , Koji Okamura , Akihisa Takaichi , Toshihiko Okamoto , Tetsuo Fukuda
发明人： Shuichi Sakamoto , Hiroshi Okamatsu , Koji Okamura , Akihisa Takaichi , Toshihiko Okamoto , Tetsuo Fukuda
CPC分类号： A23L33/175
摘要： The invention presents a nutrient composition comprising insulin secretion promoting amino acid and food material having antioxidation action as essential ingredients.The composition of the invention is useful for feeding at the time of physical exhaustion or fatigue due to exercise, suppression of formation of radicals by promotion of respiration during exercise, and supplementing vitamins.
摘要翻译： 本发明提供了包含促胰岛素分泌氨基酸的营养组合物和具有抗氧化作用的食品作为必需成分。 本发明的组合物可用于在运动时身体疲惫或疲劳时进食，抑制运动期间促进呼吸形成自由基以及补充维生素。
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