Methods for preparing transparent articles from hydroquinone polycarbonate copolymers
    22.
    发明申请
    Methods for preparing transparent articles from hydroquinone polycarbonate copolymers 有权
    由氢醌聚碳酸酯共聚物制备透明制品的方法

    公开(公告)号:US20070100118A1

    公开(公告)日:2007-05-03

    申请号:US11261262

    申请日:2005-10-28

    IPC分类号: C08G64/00

    摘要: A method for producing a transparent article comprises the steps of melt transesterifying a monomer mixture in the presence of a transesterification catalyst to produce a hydroquinone polycarbonate copolymer product comprising greater than 45 mole percent of structural units derived from the hydroquinone. The monomer mixture comprises a hydroquinone, at least one aromatic dihydroxy compound other than the hydroquinone, and a carbonic acid diester. The hydroquinone polycarbonate copolymer product is then heated to a highest processing temperature of 5° C. to 20° C. above a maximum melting melt temperature for the hydroquinone copolymer product for a sufficient period of time to render the hydroquinone polycarbonate copolymer product transparent upon cooling to ambient temperature; and cooling the hydroquinone polycarbonate copolymer product to produce the transparent article. The method can also be used for producing transparent hydroquinone polycarbonate copolymers, which can be used for producing the transparent articles.

    摘要翻译: 制备透明制品的方法包括在酯交换催化剂存在下熔融酯交换单体混合物以产生包含大于45摩尔%的衍生自对苯二酚的结构单元的氢醌聚碳酸酯共聚物产物的步骤。 单体混合物包含氢醌,至少一种除氢醌以外的芳族二羟基化合物和碳酸二酯。 然后将对苯二酚聚碳酸酯共聚物产物加热至高于氢醌共聚物产物的最大熔融熔融温度的5℃至20℃的最高加工温度足够的时间以使氢醌聚碳酸酯共聚物产品在冷却时透明 到环境温度; 并冷却氢醌聚碳酸酯共聚物产物以制备透明制品。 该方法也可用于生产可用于生产透明制品的透明氢醌聚碳酸酯共聚物。

    Method for preparing polycarbonates of enhanced crystallinity
    25.
    发明授权
    Method for preparing polycarbonates of enhanced crystallinity 失效
    制备增强结晶度的聚碳酸酯的方法

    公开(公告)号:US6031062A

    公开(公告)日:2000-02-29

    申请号:US239481

    申请日:1999-01-28

    摘要: Crystallinity of amorphous precursor polycarbonates is enhanced by contact with at least on diaryl carbonate such as diphenyl carbonate, followed by pelletization and heating to a temperature above the melting point of the diaryl carbonate and below the glass transition temperature of the amorphous precursor polycarbonate. The crystallinity enhancement operation may be conducted in the presence of dihydroxyorganic monomers and may be followed by a solid state polymerization operation.

    摘要翻译: 无定形前体聚碳酸酯的结晶度通过与至少在碳酸二芳基酯如碳酸二苯酯接触,然后造粒并加热到高于碳酸二芳基酯的熔点并低于无定形前体聚碳酸酯的玻璃化转变温度的温度来增强。 结晶度增强操作可以在二羟基有机单体的存在下进行,然后进行固态聚合操作。

    Methods for preparing transparent articles from hydroquinone polycarbonate copolymers
    27.
    发明授权
    Methods for preparing transparent articles from hydroquinone polycarbonate copolymers 有权
    由氢醌聚碳酸酯共聚物制备透明制品的方法

    公开(公告)号:US07528214B2

    公开(公告)日:2009-05-05

    申请号:US11261262

    申请日:2005-10-28

    IPC分类号: C08G63/02 C08G63/00

    摘要: A method for producing a transparent article comprises the steps of melt transesterifying a monomer mixture in the presence of a transesterification catalyst to produce a hydroquinone polycarbonate copolymer product comprising greater than 45 mole percent of structural units derived from the hydroquinone. The monomer mixture comprises a hydroquinone, at least one aromatic dihydroxy compound other than the hydroquinone, and a carbonic acid diester. The hydroquinone polycarbonate copolymer product is then heated to a highest processing temperature of 5° C. to 20° C. above a maximum melting melt temperature for the hydroquinone copolymer product for a sufficient period of time to render the hydroquinone polycarbonate copolymer product transparent upon cooling to ambient temperature; and cooling the hydroquinone polycarbonate copolymer product to produce the transparent article. The method can also be used for producing transparent hydroquinone polycarbonate copolymers, which can be used for producing the transparent articles.

    摘要翻译: 制备透明制品的方法包括在酯交换催化剂存在下熔融酯交换单体混合物以产生包含大于45摩尔%的衍生自对苯二酚的结构单元的氢醌聚碳酸酯共聚物产物的步骤。 单体混合物包含氢醌,至少一种除氢醌以外的芳族二羟基化合物和碳酸二酯。 然后将对苯二酚聚碳酸酯共聚物产物加热至高于氢醌共聚物产物的最大熔融熔融温度的5℃至20℃的最高加工温度足够的时间以使氢醌聚碳酸酯共聚物产品在冷却时透明 到环境温度; 并冷却氢醌聚碳酸酯共聚物产物以制备透明制品。 该方法也可用于生产可用于生产透明制品的透明氢醌聚碳酸酯共聚物。