Modified polymers prepared with lanthanide-based catalysts

    公开(公告)号:US20060025539A1

    公开(公告)日:2006-02-02

    申请号:US11243874

    申请日:2005-10-05

    IPC分类号: C08C19/22 C08F8/30

    摘要: A method for preparing a functionalized polymer comprising the steps of preparing a pseudo-living polymer by polymerizing conjugated diene monomer with a lanthanide-based catalyst, where said pseudo-living polymer is characterized by having greater than about 85 percent of the polymer in the cis microstructure and less than about 3 percent of the polymer is in the 1,2- or 3,4-microstructure, and reacting the pseudo-living polymer with at least one functionalizing agent defined by the formula (I) or (II) where Z is a substituent that will react or interact with organic or inorganic fillers; R1 is a single bond or a divalent organic group; R2 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R13 or R14; R3 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R4 or R5; R13 is a single bond, a divalent organic group, or a trivalent organic group that forms a cyclic organic group with R2 or R14; R4 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R5; R14 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R2 or R13; and R5 is a monovalent organic group or a divalent organic group that forms a cyclic organic group with R3 or R4; with the proviso that each group attached to the imino carbon is attached via a carbon atom and R1, R2 R3, R4, R5, R13, R14 and Z are substituents that will not protonate a pseudo-living polymer.

    RUBBER COMPOSTION AND PNEUMATIC TIRE USING THE SAME
    22.
    发明申请
    RUBBER COMPOSTION AND PNEUMATIC TIRE USING THE SAME 有权
    橡胶组合物和使用它的气动轮胎

    公开(公告)号:US20110190440A1

    公开(公告)日:2011-08-04

    申请号:US12529979

    申请日:2008-03-05

    摘要: This invention provides a rubber composition being excellent in the workability during production and the heat resistance and high in the storage elastic modulus (G′) and small in the loss tangent (tan δ), which is formed by compounding 1-60 parts by mass of a low-molecular weight conjugated diene-based polymer (B) having a weight average molecular weight as measured through a gel permeation chromatography and converted to polystyrene of 10,000-200,000 and a vinyl bond content in a conjugated diene compound portion of not less than 40% based on 100 parts by mass of a rubber component (A) comprised of at least one selected from the group consisting of natural rubber, polyisoprene rubber, styrene-butadiene copolymer rubber, polybutadiene rubber and isobutylene isoprene rubber, wherein the rubber component (A) comprises natural rubber and/or polyisoprene rubber and a proportion of styrene units in total of the low-molecular weight conjugated diene-based polymer (B) is less than 5% by mass.

    摘要翻译: 本发明提供一种橡胶组合物,其制造中的加工性和耐热性优异,储存弹性模量(G')高,损耗角正切(tanδ)小,通过将1-60质量份 的通过凝胶渗透色谱法测定的重均分子量为10,000〜200000的聚苯乙烯的低分子量共轭二烯类聚合物(B),共轭二烯化合物部分中的乙烯基含量不小于 基于100质量份由选自天然橡胶,聚异戊二烯橡胶,苯乙烯 - 丁二烯共聚物橡胶,聚丁二烯橡胶和异丁烯异戊二烯橡胶中的至少一种组成的橡胶组分(A)为100重量%,其中橡胶组分 A)包含天然橡胶和/或聚异戊二烯橡胶,并且低分子量共轭二烯系聚合物(B)的总量中苯乙烯单元的比例小于5质量% 屁股。

    RUBBER COMPOSITION AND PNEUMATIC TIRE USING THE SAME
    23.
    发明申请
    RUBBER COMPOSITION AND PNEUMATIC TIRE USING THE SAME 有权
    橡胶组合物和使用其的气动轮胎

    公开(公告)号:US20100006199A1

    公开(公告)日:2010-01-14

    申请号:US12439769

    申请日:2007-09-04

    摘要: This invention provides a rubber composition highly balancing flexibility at a low temperature and a low rolling resistance, which is formed by compounding a low-molecular weight conjugated diene-based polymer (B) having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a high-molecular weight rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000.

    摘要翻译: 本发明提供了通过将具有至少一个官能团的低分子量共轭二烯系聚合物(B),芳香族乙烯基化合物含量 小于5质量%,并且通过凝胶渗透色谱法改性而不是通过将不小于2,000但小于150,000的聚苯乙烯换算成高分子量橡胶组分的填充剂(C)而不是终止测量的重均分子量 (A)的重均分子量,通过凝胶渗透色谱法进行改性而不终止,转化为不小于15万的聚苯乙烯。

    Rubber composition and pneumatic tire using the same in tread
    24.
    发明授权
    Rubber composition and pneumatic tire using the same in tread 有权
    橡胶组合物和充气轮胎在胎面上使用相同

    公开(公告)号:US07211630B2

    公开(公告)日:2007-05-01

    申请号:US10522381

    申请日:2003-07-28

    IPC分类号: C08L9/06 C08L15/00

    摘要: A rubber composition comprising as a rubber component a specified styrene-butadiene copolymer (A) and a styrene-isoprene copolymer of a specified hydrogenation ratio (B) wherein a bound styrene content of the copolymer (B) is larger by a given value than a bound styrene content of the copolymer (A) is good in the wear resistance and fracture property and further excellent in the wet-skid resistance and dry gripping property.

    摘要翻译: 一种橡胶组合物,其特征在于,将特定的苯乙烯 - 丁二烯共聚物(A)和特定氢化比(B)的苯乙烯 - 异戊二烯共聚物作为橡胶成分,其中共聚物(B)的结合苯乙烯含量比 共聚物(A)的结合苯乙烯含量的耐磨损性和断裂性良好,耐湿滑性和干燥抓持性也优异。

    Rubber compostion and pneumatic tire using the same

    公开(公告)号:US09879129B2

    公开(公告)日:2018-01-30

    申请号:US12529979

    申请日:2008-03-05

    摘要: This invention provides a rubber composition being excellent in the workability during production and the heat resistance and high in the storage elastic modulus (G′) and small in the loss tangent (tan δ), which is formed by compounding 1-60 parts by mass of a low-molecular weight conjugated diene-based polymer (B) having a weight average molecular weight as measured through a gel permeation chromatography and converted to polystyrene of 10,000-200,000 and a vinyl bond content in a conjugated diene compound portion of not less than 40% based on 100 parts by mass of a rubber component (A) comprised of at least one selected from the group consisting of natural rubber, polyisoprene rubber, styrene-butadiene copolymer rubber, polybutadiene rubber and isobutylene isoprene rubber, wherein the rubber component (A) comprises natural rubber and/or polyisoprene rubber and a proportion of styrene units in total of the low-molecular weight conjugated diene-based polymer (B) is less than 5% by mass.

    Run-flat tire
    26.
    发明授权
    Run-flat tire 有权
    润滑轮胎

    公开(公告)号:US09493041B2

    公开(公告)日:2016-11-15

    申请号:US13395391

    申请日:2009-09-10

    摘要: The present invention relates to a run-flat tire employing a rubber composition capable of improving processability without reducing the durability during run-flat traveling. More specifically, the present invention relates to a run-flat tire comprising a bead filler 7 and a pair of side-reinforcing rubber layers 8. At least one of the bead filler 7 and the side-reinforcing rubber layer 8 employs a rubber composition obtained by adding 3 to 10 parts by mass of sulfur and 0.1 to 30 parts by mass of a low-molecular-weight conjugated diene-based polymer (B) having a weight average molecular weight in the range of 2,000 to 10,000, to 100 parts by mass of a rubber component (A) containing at least a natural rubber or polyisoprene rubber and having a weight average molecular weight in the range of 150,000 to 2,000,000.

    摘要翻译: 本发明涉及一种使用橡胶组合物的防滑型轮胎,该橡胶组合物能够改善加工性能,而不会降低跑平行驶期间的耐久性。 更具体地说,本发明涉及包括胎圈填料7和一对侧面加强橡胶层8的缺气保用轮胎。胎圈填料7和侧面增强橡胶层8中的至少一个使用得到的橡胶组合物 通过将3〜10质量份的硫和0.1〜30质量份的重均分子量为2,000〜10,000的低分子量共轭二烯系聚合物(B)添加至100份 含有至少天然橡胶或聚异戊二烯橡胶并且重均分子量在15万至200万范围内的橡胶组分(A)的质量。

    Display and electronic unit
    27.
    发明授权
    Display and electronic unit 失效
    显示和电子单位

    公开(公告)号:US08699229B2

    公开(公告)日:2014-04-15

    申请号:US13346928

    申请日:2012-01-10

    申请人: Koji Masaki

    发明人: Koji Masaki

    IPC分类号: H05K7/20 H05K7/00

    摘要: A display capable of inhibiting deformation of a component during transport or the like and an electronic unit including the display are provided. A display includes: a main section; and a board-mounting plate disposed on one surface of the main section, and having a board-mounting region on a main surface on a side opposite to a side facing the main section, in which the board-mounting plate includes, at corners at both ends of a side of the mounting region, hook sections allowing corners of a board to be hooked thereto, and the hook sections each are fixed to the main surface on two sides of the corner of the mounting region.

    摘要翻译: 提供能够抑制运输等期间的部件变形的显示器和包括显示器的电子单元。 显示器包括:主要部分; 以及设置在所述主体部分的一个表面上的板安装板,并且在与所述主板部分相对的一侧的主表面上的板安装区域中,所述板安装板包括在所述主板部分的拐角处 安装区域的一侧的两端,允许板的角部钩挂的钩部,并且钩部各自固定在安装区域的角部的两侧的主表面上。

    Rubber composition and pneumatic tire using the same
    28.
    发明授权
    Rubber composition and pneumatic tire using the same 有权
    橡胶组合物和使用其的充气轮胎

    公开(公告)号:US08580885B2

    公开(公告)日:2013-11-12

    申请号:US12439769

    申请日:2007-09-04

    摘要: This invention provides a rubber composition highly balancing flexibility at a low temperature and a low rolling resistance, which is formed by compounding a low-molecular weight conjugated diene-based polymer (B) having at least one functional group, an aromatic vinyl compound content of less than 5% by mass and a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 2,000 but less than 150,000 and a filler (C) into a high-molecular weight rubber component (A) having a weight average molecular weight as measured without terminating by modification through a gel permeation chromatography and converted to polystyrene of not less than 150,000.

    摘要翻译: 本发明提供了通过将具有至少一个官能团的低分子量共轭二烯系聚合物(B),芳香族乙烯基化合物含量 小于5质量%,并且通过凝胶渗透色谱法改性而不是通过将不小于2,000但小于150,000的聚苯乙烯换算成高分子量橡胶组分的填充剂(C)而不是终止测量的重均分子量 (A)的重均分子量,通过凝胶渗透色谱法进行改性而不终止,转化为不小于15万的聚苯乙烯。

    RUN-FLAT TIRE
    29.
    发明申请
    RUN-FLAT TIRE 有权
    跑平轮胎

    公开(公告)号:US20120168051A1

    公开(公告)日:2012-07-05

    申请号:US13395391

    申请日:2009-09-10

    IPC分类号: B60C15/06 B60C17/00

    摘要: The present invention relates to a run-flat tire employing a rubber composition capable of improving processability without reducing the durability during run-flat traveling. More specifically, the present invention relates to a run-flat tire comprising a bead filler 7 and a pair of side-reinforcing rubber layers 8. At least one of the bead filler 7 and the side-reinforcing rubber layer 8 employs a rubber composition obtained by adding 3 to 10 parts by mass of sulfur and 0.1 to 30 parts by mass of a low-molecular-weight conjugated diene-based polymer (B) having a weight average molecular weight in the range of 2,000 to 10,000, to 100 parts by mass of a rubber component (A) containing at least a natural rubber or polyisoprene rubber and having a weight average molecular weight in the range of 150,000 to 2,000,000.

    摘要翻译: 本发明涉及一种使用橡胶组合物的防滑型轮胎,该橡胶组合物能够改善加工性能,而不会降低跑平行驶期间的耐久性。 更具体地说,本发明涉及包括胎圈填料7和一对侧面加强橡胶层8的缺气保用轮胎。胎圈填料7和侧面增强橡胶层8中的至少一个使用得到的橡胶组合物 通过将3〜10质量份的硫和0.1〜30质量份的重均分子量为2,000〜10,000的低分子量共轭二烯系聚合物(B)添加至100份 含有至少天然橡胶或聚异戊二烯橡胶并且重均分子量在15万至200万范围内的橡胶组分(A)的质量。

    Reduced Oil Rubber Compositions Including N-Substituted Polyalkylene Succinimide Derivates and Methods For Preparing Such Compositions
    30.
    发明申请
    Reduced Oil Rubber Compositions Including N-Substituted Polyalkylene Succinimide Derivates and Methods For Preparing Such Compositions 有权
    包含N-取代的聚亚烷基琥珀酰亚胺衍生物的降低油橡胶组合物和制备这种组合物的方法

    公开(公告)号:US20080153972A1

    公开(公告)日:2008-06-26

    申请号:US11615659

    申请日:2006-12-22

    IPC分类号: C08K3/36

    摘要: A reduced oil rubber composition includes (a) a silica filler, (b) a N-substituted polyalkylene succinimide derivative, and (c) a rubber matrix. In certain embodiments, the composition may comprise a reduced amount of oil, especially a reduced amount of aromatic oil or even no aromatic oil. Rubber articles manufactured from such composition, such as tires and power belts, have improved properties such as reduced rolling resistance, improved wet/snow traction and winter softness, improved dynamic stiffness, improved tensile strength, easy handling, and/or compatibility with higher environmental standard, among others.

    摘要翻译: 还原油橡胶组合物包括(a)二氧化硅填料,(b)N-取代的聚亚烷基琥珀酰亚胺衍生物和(c)橡胶基质。 在某些实施方案中,组合物可以包含减少量的油,特别是减少量的芳香油或甚至不含芳香油。 由这种组合物制成的橡胶制品,例如轮胎和动力带,具有改进的性能,例如降低的滚动阻力,改善的湿/雪牵引力和冬季柔软度,改善的动态刚度,改善的拉伸强度,易于处理和/或与较高环境的兼容性 标准等。