摘要:
A vertical, fixed-bed ammonia converter wherein a fixed-bed catalyst zone is configured into two mechanically separated catalyst volumes and two gas streams that operate in parallel. The design maintains the ratio of gas flow to catalyst volume so that there is no catalyst effectiveness penalty. The catalyst beds and gas flow paths are configured so that gas flow is downward through each catalyst volume. Each fixed-bed catalyst zone in the present invention can hold the catalyst in an annular space formed between two concentric shrouds arranged around a shell and tube heat exchanger. The two catalyst beds associated with each zone are situated above one another along the length of an interstage heat exchanger. Pipes or conduits are disposed through the beds to effect the parallel gas flow configuration, or alternatively, annular flows are created via passages through the internal shrouds that contain the catalyst beds.
摘要:
A vertical, fixed-bed ammonia converter wherein a fixed-bed catalyst zone is configured into two mechanically separated catalyst volumes and two gas streams that operate in parallel. The design maintains the ratio of gas flow to catalyst volume so that there is no catalyst effectiveness penalty. The catalyst beds and gas flow paths are configured so that gas flow is downward through each catalyst volume. Each fixed-bed catalyst zone in the present invention can hold the catalyst in an annular space formed between two concentric shrouds arranged around a shell and tube heat exchanger. The two catalyst beds associated with each zone are situated above one another along the length of an interstage heat exchanger. Pipes or conduits are disposed through the beds to effect the parallel gas flow configuration, or alternatively, annular flows are created via passages through the internal shrouds that contain the catalyst beds.
摘要:
A system for modernizing exothermic heterogeneous reactors used in the synthesis of ammonia, methanol and the like, which include a pressure shell, a wall for forming an airspace, a wall or cartridge for containing a catalyst bed, and catalyst-containing basket. An airspace-forming wall is formed of a single piece substantially the whole axial length of the reactor. A bed forming wall is distinct from, and unconnected to, the airspace forming wall, and it constitutes independent modules, each module containing at least one catalyst bed and each module resting either on an underlying module or on an extension of an inside gas distribution collector. The bed forming walls contain the catalyst and distribute gas therethrough. A portion of the catalyst contacts the airspace-forming wall.
摘要:
The invention concerns a process and an apparatus for performing chemical reactions under pressure in the presence of a solid catalyst in a multi-stage reaction zone, after external intermediary thermal conditioning. This process may be used for the synthesis of ammonia or methanol or for gasoline reforming. It is characterized in that at least one reaction fluid is introduced into at least one compartment, a first reaction effluent is recovered, a heat exchange takes place, outside the reaction zone, between a first effluent and an external heat exchange medium, then said first effluent is introduced into at least one subsequent compartment and a second reaction effluent is recovered from said subsequent compartment. The reaction fluid or reaction effluent circulates cross-wise in the compartments substantially perpendicularly to the reaction zone, the compartments being tight and of elongate shape, each compartment being adjacent to one or two other compartments, each group of two adjacent compartments comprising a common partition, wall, either substantially parallel to said generatrix or substantially oblique with respect thereto.
摘要:
The general conditions of the thermal exchange are improved by ameliorating the mixing of reacted gases together with quench gases, in order to increase in the yields and to reduce the energy consumption in reactors used for heterogeneous synthesis (ammonia, methanol, etc.), consisting of an external shell, of an internal cartridge with catalytic baskets lying one above the other, at least one of such baskets being traversed axially by the reaction gas, and of means to feed the quench gas between the bottom of one basket and the top of the following basket, said gas mixing being carried out in a peripheral zone near the internal cartridge wall.
摘要:
A reactor suitable for synthesis of ammonia or methanol comprises a catalyst bed 36 equipped with heat exchange tubes 32 supported by means 28-31 or 40, 42 providing catalyst fillable space between the tubes over substantially their whole length. Preferably catalyst particles between the tubes and in an uncooled bed 36 downstream thereof constitute a single body of catalyst. The reactor is especially suitable for synthesis at low pressures such that the heat transfer area provided by the tubes is relatively low.
摘要:
The present invention is generally directed to an improved process and apparatus for the production of gaseous products such as ammonia by catalytic, exothermic gaseous reactions and is specifically directed to an improved process which utilizes a gas-phase catalytic reaction of nitrogen and hydrogen for the synthesis of ammonia. This improved process for the production of ammonia utilizes an ammonia converter apparatus designed to comprise at least two catalyst stages and a reheat exchanger so arranged as to provide indirect heat exchange of the gaseous effluent from the last reactor catalyst stage with the effluent from at least one other reactor catalyst stage having a higher temperature level in order to reheat the effluent from the last reactor catalyst stage prior to exiting the reactor vessel, thereby facilitating higher level heat recovery from the reactor effluent.