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1.发明授权Process for regenerating a catalyst for the production of aromatic hydrocarbons or for reforming 失效用于再生用于生产芳烃或用于重整的催化剂的方法
公开(公告)号：US5034117A
公开(公告)日：1991-07-23
申请号：US464507
申请日：1990-01-12
摘要： The invention concerns a regeneration process and the corresponding apparatus for regeneration of a reforming catalyst, the reforming operation being carried out in at least two reactors in series, through which the catalyst and the charge successively flow, the pressure in the first reactor through which the catalyst and the charge pass being under a pressure of between 3 and 8 bars.The regeneration process is characterized in that the exhausted catalyst successively meets a first radial moving bed combustion zone 101, a second radial moving bed combustion zone 105, an axial oxychlorination moving bed zone 107 and an axial calcination moving bed zone 116, and that in the combustion zones the catalyst is treated under a pressure substantially equal to that which obtains in said first reactor, the burning gases are discharged from the second burning zone and are passed to a washing loop after having been previously mixed with the gases withdrawn from the oxychlorination zone and the calcination zone, that in the oxychlorination zone the catalyst is treated in co-flow relationship by a mixture of a gas from the calcination zone and a gas based on a chlorinated compound, and that in the calcination zone the catalyst is treated in counter-flow relationship by at least a part of the gases from the washing loop.
摘要翻译： 本发明涉及一种再生方法和用于再生重整催化剂的相应装置，重整操作在至少两个串联的反应器中进行，催化剂和电荷通过该反应器依次流动，第一反应器中的压力 催化剂和电荷通过在3和8巴之间的压力下。 再生方法的特征在于，排出的催化剂连续地遇到第一径向移动床燃烧区101，第二径向移动床燃烧区105，轴向氧氯化移动床区107和轴向煅烧移动床区116，并且在 燃烧区域在与所述第一反应器中获得的压力基本相同的压力下处理催化剂，燃烧气体从第二燃烧区域排出，并且在预先与从氧氯化物区域排出的气体混合之后通入洗涤回路 和煅烧区，在氧氯化区中，催化剂通过来自煅烧区的气体和基于氯化化合物的气体的混合物以共流关系处理，并且在煅烧区中，催化剂在反应器中处理 通过来自洗涤回路的至少一部分气体的流动关系。
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2.发明授权Apparatus for performing chemical reactions under pressure in a multi-stage reaction zone with external intermediary thermal conditioning 失效用于在具有外部中间热调节的多级反应区中进行压力下的化学反应的装置
公开(公告)号：US5192512A
公开(公告)日：1993-03-09
申请号：US709932
申请日：1991-06-04
申请人： Dang V. Quang , Pierre Ham , Daniel Gelas , Christian Legrand
发明人： Dang V. Quang , Pierre Ham , Daniel Gelas , Christian Legrand
IPC分类号： B01J8/00 , B01J8/04 , C01C1/04 , C07C29/152
CPC分类号： C01C1/0423 , B01J8/0005 , B01J8/0403 , C07C29/152 , Y02P20/52
摘要： The invention concerns a process and an apparatus for performing chemical reactions under pressure in the presence of a solid catalyst in a multi-stage reaction zone, after external intermediary thermal conditioning. This process may be used for the synthesis of ammonia or methanol or for gasoline reforming. It is characterized in that at least one reaction fluid is introduced into at least one compartment, a first reaction effluent is recovered, a heat exchange takes place, outside the reaction zone, between a first effluent and an external heat exchange medium, then the first effluent is introduced into at least one subsequent compartment and a second reaction effluent is recovered from the subsequent compartment. The reaction fluid or reaction effluent circulates cross-wise in the compartments substantially perpendicularly to the reaction zone, the compartments being tight and of elongate shape, each compartment being adjacent to one or two other compartments, each group of two adjacent compartments comprising a common partition wall, either substantially parallel to generatrix or substantially oblique with respect thereto.
摘要翻译： 本发明涉及在外部中间热调节之后，在多级反应区中的固体催化剂存在下，在压力下进行化学反应的方法和装置。 该方法可用于氨或甲醇的合成或用于汽油重整。 其特征在于，将至少一个反应流体引入至少一个隔室中，回收第一反应流出物，在反应区外部，在第一流出物和外部热交换介质之间进行热交换，然后将第一反应流出物 将流出物引入至少一个随后的隔室中，并从随后的室回收第二反应流出物。 反应流体或反应流出物在基本上垂直于反应区的隔室中交叉循环，隔室是紧密和细长的形状，每个隔室与一个或两个其它隔室相邻，每组两个相邻隔室包括公共隔板 基本上平行于母线或相对于母线基本倾斜。
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3.发明授权Heat exchanger for heating the charge of a catalytic reforming unit operating under low pressure 失效用于加热在低压下操作的催化重整单元的加料的热交换器
公开(公告)号：US4973400A
公开(公告)日：1990-11-27
申请号：US365259
申请日：1989-10-12
申请人： Pierre Ham , Jean de Bonneville
发明人： Pierre Ham , Jean de Bonneville
CPC分类号： C10G35/04
摘要： The invention relates to a means for heating the charge of a catalytic reforming unit operating under low pressure.The invention more particularly relates to an apparatus having in combination a first heat exchanger (6), in which the gaseous recycling-liquid charge mixture introduced by pipe (5) is completely vaporized and a second exchanger (9) in which the charge is heated to an adequate temperature by indirect contact with the reforming effluent arriving by pipe (17), which successively passes through the two heat exchangers.
摘要翻译： 本发明涉及一种用于加热在低压下运行的催化重整单元的装料的装置。 本发明更具体地涉及一种组合有第一热交换器（6）的设备，其中通过管道（5）引入的气体循环 - 液体加料混合物被完全蒸发，并且其中加料的第二交换器（9） 通过与通过管道（17）到达的重整流出物间接接触而连续通过两个热交换器达到足够的温度。
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4.发明授权
公开(公告)号：US5045568A
公开(公告)日：1991-09-03
申请号：US146665
申请日：1988-01-21
申请人： Dang V. Quang , Pierre Ham , Daniel Gelas , Christian Legrand
发明人： Dang V. Quang , Pierre Ham , Daniel Gelas , Christian Legrand
CPC分类号： C01C1/0423 , B01J8/0005 , B01J8/0403 , C01C1/0417 , C07C29/152 , Y02P20/52
摘要： The invention concerns a process and an apparatus for performing chemical reactions under pressure in the presence of a solid catalyst in a multi-stage reaction zone, after external intermediary thermal conditioning. This process may be used for the synthesis of ammonia or methanol or for gasoline reforming. It is characterized in that at least one reaction fluid is introduced into at least one compartment, a first reaction effluent is recovered, a heat exchange takes place, outside the reaction zone, between a first effluent and an external heat exchange medium, then said first effluent is introduced into at least one subsequent compartment and a second reaction effluent is recovered from said subsequent compartment. The reaction fluid or reaction effluent circulates cross-wise in the compartments substantially perpendicularly to the reaction zone, the compartments being tight and of elongate shape, each compartment being adjacent to one or two other compartments, each group of two adjacent compartments comprising a common partition, wall, either substantially parallel to said generatrix or substantially oblique with respect thereto.
摘要翻译： 本发明涉及在外部中间热调节之后，在多级反应区中的固体催化剂存在下，在压力下进行化学反应的方法和装置。 该方法可用于氨或甲醇的合成或用于汽油重整。 其特征在于，将至少一个反应流体引入至少一个隔室中，回收第一反应流出物，发生热交换，反应区外，第一流出物和外部热交换介质之间，然后所述第一反应流 将流出物引入至少一个随后的隔室中，并且从所述后续隔室回收第二反应流出物。 反应流体或反应流出物在基本上垂直于反应区的隔室中交叉循环，隔室是紧密和细长的形状，每个隔室与一个或两个其它隔室相邻，每组两个相邻隔室包括公共隔板 ，基本上平行于所述母线或相对于其基本上倾斜的壁。
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公开(公告)号：US4172027A
公开(公告)日：1979-10-23
申请号：US873989
申请日：1978-01-31
申请人： Pierre Ham , Roland Huin
发明人： Pierre Ham , Roland Huin
IPC分类号： B01J27/13 , B01J23/46 , B01J23/48 , B01J23/56 , B01J23/89 , B01J23/90 , B01J27/135 , B01J27/32 , B01J37/18 , B01J37/20 , B01J38/10 , C07B61/00 , C10G35/09 , C10G35/10 , C10G35/12 , C10G35/14 , C10G59/02 , C10G35/08
摘要： Catalytic process for reforming or production of aromatic hydrocarbons at a temperature from 480.degree. to 600.degree. C., wherein a charge of hydrocarbons and hydrogen is passed through two reaction zones, of the moving bed type, whose catalyst continuously flows downwardly and is withdrawn at the bottom thereof, is regenerated, treated with hydrogen and then with a sulfur compound, at respective temperatures lower than the reaction temperature, and thereafter fed back continuously to the reaction zone.
摘要翻译： 在480℃至600℃的温度下重整或生产芳烃的催化方法，其中烃和氢气的进料通过移动床型的两个反应区，其催化剂连续向下流动并且在 其底部在低于反应温度的相应温度下再生，然后用硫化合物处理，然后反复反馈回反应区。
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6.发明授权Heat exchanger for heating the charge of a catalytic reforming unit operating under low pressure 失效用于加热在低压下操作的催化改性单元的充电的热交换器
公开(公告)号：US5073350A
公开(公告)日：1991-12-17
申请号：US572584
申请日：1990-08-27
申请人： Pierre Ham , Jean de Bonneville
发明人： Pierre Ham , Jean de Bonneville
CPC分类号： C10G35/04
摘要： The invention relates to a means for heating the charge of a catalytic reforming unit operating under low pressure.The invention more particularly relates to an apparatus having in combination a first heat exchanger (6), in which a recycling gas/liquid charge mixture introduced by pipe (5) is completely vaporized, and a second exchanger (9) in which the charge is heated to an adequate temperature by indirect contact with reforming effluent delivered by pipe (17), which successively passes through the two heat exchangers.
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公开(公告)号：US4849092A
公开(公告)日：1989-07-18
申请号：US89106
申请日：1987-08-25
CPC分类号： B01J38/20 , B01J23/96 , B01J27/32 , C10G35/085
摘要： The invention concerns a process for regenerating a hydrocarbon hydroconversion catalyst containing a carrier, at least one group VIII noble metal and a halogen or halogenated compound.It is characterized by an operation in two regeneration zones (1) and (2). The gas effluent from the first regeneration zone (1) is used to feed the second regeneration zone. During the step of burning coke deposited onto the catalyst in the first zone, the heat amount generated during the combustion is used for preheating the feed of said first zone. The temperature of the effluent of said first zone is reduced, through said exchanger, to a value adapted to perform the burning step in the second zone. Additional air is supplied before introducing the gas into said second zone (2) in order to obtain a suitable oxygen concentration.
摘要翻译： 本发明涉及一种再生含有载体，至少一种VIII族贵金属和卤素或卤代化合物的烃加氢转化催化剂的方法。 其特征在于在两个再生区（1）和（2）中进行操作。 来自第一再生区（1）的气体流出物用于进料第二再生区。 在燃烧沉积在第一区域中的催化剂上的焦炭的步骤期间，在燃烧期间产生的热量用于预热所述第一区域的进料。 所述第一区域的流出物的温度通过所述交换器减小到适于在第二区域中执行燃烧步骤的值。 在将气体引入所述第二区域（2）之前提供额外的空气，以获得合适的氧气浓度。
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