Abstract:
Systems and methods for recovering and purifying water from a gas stream, comprising a gas stream purification unit for purifying the gas stream, a water separation unit for separating water from the purified gas stream, and a water purification unit for purifying the water separated by the water separation unit. The gas stream purification unit may comprise at least one of a soot reactor and a catalytic oxidation reactor, the water separation unit may comprise at least one of a condenser and a water extractor, and the water purification unit may comprise a cyclic reverse osmosis system.
Abstract:
For mixing and distributing a gas phase and a liquid phase over a granular bed, employing an annular peripheral zone inside a reactor via which liquid is introduced and which acts as a buffer zone against fluctuations in the flow of the liquid phase. The device is applicable to catalytic bed chemical reactors especially for the hydrotreatment of hydrocarbons.
Abstract:
Apparatus for rapidly heating one or more reactants for use in a fuel reformer. The apparatus includes a combustion section having an outer wall enclosing a combustion chamber and a catalyst disposed within the combustion chamber. The catalyst provides a non-diffused flow path through the combustion chamber for the combustion of gases and generation of heat and passage of such gases and heat from the combustion chamber. A heat recovery section is in fluid communication with the combustion section and has an outer wall defining a heat recovery chamber. At least one heat exchanging element is located within the heat recovery chamber having an inlet for receiving a fuel reforming reactant and an outlet for directing a heated reactant out of the heat recovery section. The combustion section is elevated relative to the heat recovery section such that heated combustion gases are displaced down into the heat recovery section. The combustion and heat recovery sections have outer walls that are continuous with one another to form a housing that is preferably cylindrical. The housing has an internal diameter of less than about 10 inches, or alternatively, has a length and a diameter in a ratio of between about 7:1 and about 4:1. Methods for the rapid start-up of a fuel processor using such a pre-reformer are also provided, as are integrated fuel processors comprising a fuel reformer and the disclosed pre-reformer.
Abstract:
According to this process: (a) air is distilled in at least one air distillation apparatus (8) so as to produce a stream of liquid oxygen containing most of the krypton and xenon from the air, and this stream of liquid oxygen is vaporized; (b) a partial oxidation of at least one hydrocarbon is carried out with at least one portion of the gaseous oxygen obtained in step (a), so as to produce a syngas containing at most 0.1 ppm mol of oxygen; and (c) constituents other than krypton and xenon are removed from the syngas.
Abstract:
A fuel conversion reactor includes a shell-and-tube heat exchanger for controlling the temperature of a hot gaseous mixture produced by catalytic or non-catalytic reaction of a fuel with a gaseous fluid, and for controlling the temperature of the gaseous fluid and/or the fuel prior to the reaction. The reactor is either a catalytic or non-catalytic burner, or a fuel reformer for converting a fuel to hydrogen. A preferred reactor includes an outer shell having first and second ends and an inner surface, a primary inner shell extending into the outer shell, the primary inner shell defining a heat exchanging chamber and having primary and secondary ends, and a secondary inner shell having a first end located adjacent the secondary end of the primary inner shell. One or more outlet apertures are formed between the two inner shells for passage of the gaseous fluid out of the heat exchanging chamber. There are also a plurality of heat exchange tubes extending through the heat exchanging chamber between first and second tube sheets and connected to same. The first tube sheet is mounted in the primary inner shell while the second tube sheet is connected to the secondary inner shell. The tubes form passages for flow of the hot gaseous mixture in heat exchange contact with the gaseous fluid through the heat exchanging chamber, thereby preheating the gaseous fluid prior to reaction with the fuel. The adjacent ends of the inner shells form a disconnected joint and the secondary inner shell is free to move relative to the primary inner shell upon thermal expansion of the tubes.
Abstract:
Method and apparatus for making composite particles, such as supported metallic catalyst particles, that involve providing a vapor of a metallic catalyst material in a carrier gas flow, providing an aerosol of support particles wherein the support particles are at a lower temperature than said vapor, and contacting the aerosol and the vapor in the carrier gas flow to form particles of the metallic catalyst material on individual support particles.
Abstract:
Apparatus for producing molybdenum carbide from a precursor material includes a supply of process gas and a furnace defining at least a first heating zone and a second heating zone. The furnace heats the first heating zone to a first temperature and the second heating zone to a second temperature. The second temperature is at least about 100null C. hotter than the first temperature. A transfer system operatively associated with the furnace and the supply of process gas moves the precursor material through the first and second heating zones and in the presence of the process gas to form molybdenum carbide (MoC and MO2C).
Abstract:
A method for reducing NOx in a gas stream by sequentially exposing the gas stream to a first and a second catalyst. The first catalyst converts at least a portion of the gas stream to a reducing gas, it reduces at least a portion of the NOx in a first temperature range, and it absorbs at least a portion of the NOx in the first temperature range. The second catalyst reduces at least a portion of the NOx in a second temperature range utilizing the reducing gas produced by the second catalyst. The reducing gas produced by the first catalyst is typically a partially oxidized hydrocarbon, preferably an aldehyde, and more preferably acetaldehyde or formaldehyde. In addition to the first and second catalysts, the gas stream may be exposed to a plasma. Preferably, the first catalyst is selected as a zeolite, and more preferably a zeolite impregnated with a cation. The cation is preferably selected from the group consisting of an alkaline cation, an alkaline earth cation, and combinations thereof and preferably exhibits pores sizes of greater than 4 angstroms, and more preferably exhibits pores sizes of greater than 7 angstroms. The second catalyst is preferably a null-alumina catalyst, and more preferably a null-alumina catalyst impregnated with transition metals, including, but not limited to, Ag, In and Sn.
Abstract:
Installation for the gas-phase polymerisation of at least one olefinic monomer, comprising a horizontal stirred reactor consisting of an undivided space, provided with a number of gas feeds (13a-13) in the bottom section of the reactor (1) and a number of liquid feeds (7a-7) in the top section of the reactor (1) and at least two gas outlets (9, 11) at the top of the reactor (1), the installation being provided with means (43, 45) to regulate the discharge capacities of the gas outlets.
Abstract:
Methods and apparatus for the production of low sodium lithium carbonate and lithium chloride from a brine concentrated to about 6.0 wt % lithium are disclosed. Methods and apparatus for direct recovery of technical grade lithium chloride from the concentrated brine are also disclosed.