-
公开(公告)号：US3466340A
公开(公告)日：1969-09-09
申请号：US3466340D
申请日：1967-05-29
申请人： MONSANTO CO
发明人： LEACH HARRY S , SLATE JOHNNY L
-
公开(公告)号：US3445356A
公开(公告)日：1969-05-20
申请号：US3445356D
申请日：1966-08-25
申请人： INT NICKEL CO
CPC分类号： C01G49/16
-
23.发明授权
公开(公告)号：US3297768A
公开(公告)日：1967-01-10
申请号：US44791865
申请日：1965-04-13
申请人： BASF AG
IPC分类号： C01G49/16 , C07C209/60 , C07D295/023 , C07F15/02
CPC分类号： C07D295/023 , C01G49/16 , C07C209/60 , C07F15/025
-
24.发明授权Process for continuously reacting finely divided solids with liquids and/or gases 失效使细碎固体与液体和/或气体连续反应的方法
公开(公告)号：US2930808A
公开(公告)日：1960-03-29
申请号：US64737957
申请日：1957-03-20
发明人： KURT ZOSEL
CPC分类号： B01J8/20 , B01J8/22 , B01J10/002 , B01J19/242 , B01J2219/0011 , B01J2219/0015 , B01J2219/00166 , B01J2219/00186 , B01J2219/00777 , B01J2219/185 , B01J2219/1943 , C01G49/16 , C07F3/02 , C07F5/063
摘要： A reaction between solids and liquids and/or gases is conducted in the liquid phase in a reactor A full of liquid wherein the reactor is divided by means of screening plates X with perforations of such a size that at any given speed of gas stream, gas-buffers are formed underneath the screening plates, resulting in the liquid being impeded in its path from the solid/liquid inleg g through the reactor, maintaining a uniformly distributed solid in the reaction space. An inert gas or an inert liquid may be used to provide the liquid/gas buffer in reactions in which the phase would normally be absent. A solution of iron pentacarbonyl in petroleum, free from iron particles, can be produced by circulating carbon monoxide through the reactor with finely divided iron suspended in petroleum.ALSO: Aluminium is reacted with olefins and hydrogen to produce aluminium trialkyls, the reaction being conducted in the liquid phase in a reactor (A) full of liquid wherein the reactor is divided by means of screening plates (X) having perforations of such a size that at any given speed of gas stream, gas-buffers are formed underneath the screening plates, resulting in the liquid being impeded in its path from the solid/liquid inlet (g) through the reactor and maintaining a uniformly distributed solid in the reaction space. An inert gas or an inert liquid may be used to provide the liquid/gas buffer in reactions in which the liquid phase would normally be absent. Exemplified products are aluminium tri-isohexyl, aluminium triethyl, aluminium di-ethyl hydride. In Example (4) finely divided magnesium in di-isobutyl ether is reacted with bromobenzene to yield phenyl magnesium bromide.
-
-
-
公开(公告)号：US6153167A
公开(公告)日：2000-11-28
申请号：US264309
申请日：1999-03-08
申请人： Tracey Jacksier , Reha Tepe , David N. Vassallo
发明人： Tracey Jacksier , Reha Tepe , David N. Vassallo
IPC分类号： G01N21/73 , C01G1/04 , C01G49/16 , C01G53/02 , G01N1/00 , G01N21/01 , G01N21/27 , C09K3/00 , B01J31/00 , B22F1/00 , C21B15/04
CPC分类号： C01G49/16 , C01G1/04 , C01G53/02 , G01N21/278
摘要： Methods and apparatus for preparing gaseous compositions comprising a metal carbonyl, preferably at ppm concentration, are disclosed. The methods comprise placing metal, preferably in the form of filings, of the metal carbonyl to be produced into a first test vessel at a first temperature, and then pressurizing the first test vessel with a gas comprising carbon monoxide from a carbon monoxide source vessel. The contents of the first vessel are then heated to a second temperature and at a rate sufficient to initiate metal carbonyl formation, thereby forming a gas composition comprising a metal carbonyl. The reaction is then quenched by transferring some of the gas composition comprising a metal carbonyl from the first test vessel to a second test vessel which is at a third temperature, the third temperature being lower than the second temperature. Finally, the gas composition is diluted in the second test vessel with an inert gas (preferably argon) from an inert gas source container.
-
公开(公告)号：US4579722A
公开(公告)日：1986-04-01
申请号：US715703
申请日：1985-03-25
申请人： Rezso Csikos , Jozsef Bathory , Istvan Farkas
发明人： Rezso Csikos , Jozsef Bathory , Istvan Farkas
摘要： The invention relates to a process for deironing red mud and bauxite and for the preparation of a raw material for alumina industry and of iron pentacarbonyl which comprises(a) activating the red mud or bauxite starting material at 150.degree.-800.degree. C. under a pressure of 0.1-100 bars in a reducing gas stream in the presence of one or more promoter(s) and thereafter(b) carbonylating at 50.degree.-300.degree. C. under a pressure of 25-300 bars with carbon monoxide or a gas containing carbon monoxide and removing the iron pentacarbonyl formed from the system.The advantage of the present invention is that it provides a process for the effective removal of the iron content of red mud or bauxite and moreover it enables the utilization of the removed iron in the valuable form of iron pentacarbonyl which is suitable for use in iron metallurgy.
摘要翻译： 本发明涉及一种脱氧赤泥和铝土矿的方法，用于制备氧化铝工业和五羰基铁的原料，该方法包括：（a）在150℃-800℃下活化红泥或铝土矿原料， 在一种或多种助催化剂存在下，在还原气流中压力为0.1-100巴，此后（b）在25-300巴的压力下在一氧化碳或气体下在50-300℃下羰基化 含有一氧化碳并除去由该体系形成的五羰基铁。 本发明的优点是提供了有效去除红泥或铝土矿的铁含量的方法，此外，它可以利用适用于铁冶金的五价铁的有价值形式的去除的铁 。
-
29.发明授权
公开(公告)号：US4310490A
公开(公告)日：1982-01-12
申请号：US192415
申请日：1980-09-29
摘要： A method and apparatus for enriching the iron carbonyl content of a recycle gas stream produced in an iron carbonyl decomposition or reaction process to enable reuse of the recycle gas stream in the iron carbonyl decomposition or reaction process by cooling the recycle gas stream, adding carbon monoxide to the recycle gas stream, compressing the recycle gas stream to a pressure of about 20 to about 38 atmospheres under conditions suitable to prevent substantial decomposition of residual iron carbonyl, and contacting the compressed gas stream at a temperature of about 65.degree. to about 160.degree. C. with a reduced iron containing material in the presence of hydrogen sulfide under conditions suitable to produce substantially condensed iron carbonyl. In a particularly preferred embodiment, the recycle gas stream is initially split into first and second portions, the first portion of the recycle gas stream is cooled, enriched with carbon monoxide, compressed and contacted with the reduced iron containing material to produce substantially condensed iron carbonyl, and at least a portion of the condensed iron carbonyl is vaporized and then combined with the second portion of the recycle gas stream to produce an iron carbonyl enriched gas stream. The iron carbonyl enriched gas stream may then be reintroduced into the iron carbonyl decomposition or reaction process.
摘要翻译： 一种用于富集在羰基铁分解或反应过程中产生的再循环气流的羰基羰基含量的方法和装置，以便通过冷却循环气流，再循环气流在羰基铁分解或反应过程中，加入一氧化碳 到循环气流，在适于防止残余铁羰基的实质分解的条件下将循环气流压缩至约20至约38大气压的压力，并在约65°至约160°的温度下使压缩气流接触。 在适于产生基本上冷凝的羰基铁的条件下，在硫化氢存在下，还原的含铁材料。 在特别优选的实施方案中，循环气流最初分为第一和第二部分，再循环气流的第一部分被冷却，富含一氧化碳，压缩并与还原铁含有物接触以产生基本上浓缩的羰基羰基 ，并将至少一部分浓缩的羰基羰基蒸发，然后与再循环气体流的第二部分组合以产生富含羰基铁的气流。 然后可以将富含铁羰基的气流重新引入羰基铁分解或反应过程。
-
公开(公告)号：US3767378A
公开(公告)日：1973-10-23
申请号：US3767378D
申请日：1972-01-05
申请人： US INTERIOR
发明人： COCHRAN A , STARLIPER A
CPC分类号： C21B13/006 , C01G49/16 , C22B34/1204 , Y02P10/136
摘要： Ilmenite is treated with a reducing agent to selectively reduce iron oxide to metallic iron. The product is then treated with carbon monoxide in the presence of ammonium polysulfide solution to form iron carbonyl, which is removed by volatilization leaving rutile. The iron carbonyl is then decomposed to produce metallic iron.
摘要翻译： 用还原剂处理钛铁矿以选择性还原氧化铁至金属铁。 然后在多硫化铵溶液存在下用一氧化碳处理该产物以形成羰基铁，通过挥发而除去金红石。 然后将羰基羰基分解产生金属铁。
-
-
-
-
-
-
-
-
-
搜索结果
36 条记录 (耗时 0.011 秒)
