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    Process for preparing cellular polyurethanes
    21.
    发明授权
    Process for preparing cellular polyurethanes 失效
    制备细胞聚氨酯的方法

    公开(公告)号：US3723492A

    公开(公告)日：1973-03-27

    申请号：US3723492D

    申请日：1971-06-28

    申请人： BAYER AG

    发明人： SIMMLER W ,  DE MONTIGNY A ,  MOLLER F ,  ROEGLER M

    IPC分类号： C07F7/18 ,  C08G18/20

    CPC分类号： C08G18/209 ,  C07F7/1844

    摘要： IN WHICH N IS AN INTEGER OF FROM ONE TO THREE AND R is an alkyl radical having one or two carbon atoms with the proviso that when R1 is a dialkyl amino alkyl group, R2 is hydrogen.

    IN WHICH N IS AN INTEGER OF FROM ONE TO THREE AND R is an alkyl radical having one ro two carbon atoms, and R2 is a dialkylaminoalkyl group having the formula

    IN WHICH R is an alkyl radical having one or two carbon atoms, R1 is an alkyl radical having one or two carbon atoms or a dialkylaminoalkyl group having the formula

    A method is provided for preparing cellular polyurethanes which comprises reacting in the presence of a blowing agent an organic polyisocyanate with a polyether or polyester containing at least two hydroxyl groups in the presence of a catalytic amount of a catalyst having the formula

    摘要翻译： 提供用于制备细胞聚氨酯的方法，其包括在催化量的催化剂存在下，在发泡剂存在下将有机多异氰酸酯与含有至少两个羟基的聚醚或聚酯反应，其中R是 具有一个或两个碳原子的烷基，R 1是具有一个或两个碳原子的烷基或具有下式的二烷基氨基烷基：其中N是从一个到三的整数，R是具有一个两个碳原子的烷基 并且R 2是具有下式的二烷基氨基烷基：其中N是从一个到三的整数，R是具有一个或两个碳原子的烷基，条件是当R 1是二烷基氨基烷基时，R 2是氢。

    Organosilicon compounds
    22.
    发明授权
    Organosilicon compounds 失效
    有机硅化合物

    公开(公告)号：US3699140A

    公开(公告)日：1972-10-17

    申请号：US3699140D

    申请日：1970-07-30

    申请人： MIDLAND SILICONES LTD

    发明人： CHANDRA GRISH ,  OWEN WILLIAM J ,  LLOYD NORMAN C ,  COOPER BRYAN E

    IPC分类号： C07F7/08 ,  C07F7/10 ,  C07F7/12 ,  C07F7/18 ,  C08G77/50

    CPC分类号： C07F7/0841 ,  C07F7/0834 ,  C07F7/0836 ,  C07F7/0896 ,  C07F7/10 ,  C07F7/12 ,  C07F7/1804 ,  C07F7/1844 ,  C07F7/1864 ,  C08G77/50

    摘要： Organosilicon compounds, polymers and copolymers have been prepared containing acetylenic linkages between adjacent silicon atoms. The basic compounds are defined by the general formula R''(R2Si)m(C*C)- (C*C)-(SiR2)nR'''' where R'' and R'''' are each H, halogen, hydrocarbonoxy or -NQ2 as above defined, monovalent hydrocarbon or monovalent halogenohydrocarbon, m is 1 to 4, n is 0 to 4, R'''' being H, alkyl, aryl or trihydrocarbylsilyl when n is 0. The polymers can be defined by the unit formula (OSiR2-C*CC*C-SiR2-) and may be copolymers containing units of the formula QaSiO(4 a)/2 where Q is monovalent hydrocarbon or halogenohydrocarbon and a is 0 to 3. The novel compounds are useful as cross-linkers.

    摘要翻译： 已经制备了在相邻硅原子之间含有炔键的有机硅化合物，聚合物和共聚物。 碱性化合物由通式R'（R 2 Si）m（C 3 B C） - （C 3 F 3） - （SiR 2）n R“定义，其中R'和R”各自为H，卤素，烃氧基或-NQ 2 如上所定义，单价烃或一价卤代烃，m为1至4，n为0至4，当n为0时，R“为H，烷基，芳基或三烃基甲硅烷基。聚合物可以由单元式（OSiR2- 可以是含有QaSiO（4-a）/ 2单元的共聚物，其中Q是一价烃或卤代烃，a是0-3。新化合物可用作交联剂。

    Silacyclopentane thiols and thiolates
    24.
    发明授权
    Silacyclopentane thiols and thiolates 失效
    十六烷基硫醇和十六烷基硫醇

    公开(公告)号：US3655713A

    公开(公告)日：1972-04-11

    申请号：US3655713D

    申请日：1970-07-13

    申请人： DOW CORNING

    发明人： GROW GARY E LE

    IPC分类号： C07F7/08 ,  C07F7/12 ,  C07F7/18 ,  C08G77/28 ,  C07F7/10

    CPC分类号： C10M1/08 ,  C07F7/0847 ,  C07F7/12 ,  C07F7/184 ,  C07F7/1844 ,  C10M2227/04 ,  C10M2229/053

    摘要： SILACYCLOPENTANE MERCAPTANS AND THIOLATES OF THE FORMULA

    1-(O(2-N-M/2)-XM-RN-),3-(Y-S-),3,4-DI(R''-)SILACYCLOPENTANE

    IN WHICH Y IS HYDROGEN OR AN ACYL GROUP, N IS 0 OR 1, M IS 0 TO 2, ARE PREPARED BY THE ADDITION OF H2S OR ACYL-SH TO THE CORRESPONDING SILACYCLOPENTENE IN THE PRESENCE OF FREE RADICAL GENERATORS SUCH AS PEROXIDES, AZOBIS-NITRILES OR ULTRAVIOLET LIGHT. SPECIFIC COMPOUNDS WHERE Z IS

    3,4-DI(R'')-1,3-SILACYCLOPENTYLENE

    ARE HSZ(CH3)C1, (CH3COSZ(CH3))2O AND (HSZO)NTHE NOVEL COMPOUNDS ARE USEFUL AS LUBRICANTS, LUBRICANT ADDITIVES, AND CHEMICAL INTERMEDIATES.

    New organosilicon compounds,their preparation and their use
    28.
    发明授权
    New organosilicon compounds,their preparation and their use 失效
    新的有机硅化合物，其制备及其使用

    公开(公告)号：US3529007A

    公开(公告)日：1970-09-15

    申请号：US3529007D

    申请日：1967-08-28

    申请人： RHONE POULENC SA

    发明人： BRISON PIERRE ,  LEFORT MARCEL

    IPC分类号： C07F7/02 ,  C07F7/08 ,  C07F7/18

    CPC分类号： C10M3/00 ,  C07F7/0852 ,  C07F7/1844 ,  C10M2227/04 ,  C10N2250/10 ,  C10N2250/121

    摘要： 1,156,257. Organosilicon compounds. RHONE-POULENC S.A. 6 Sept., 1967 [8 Sept., 1966], No. 40798/67. Headings C3S and C3T. [Also in Division C5] Organosilicon compounds containing the radical where R 1 , R 11 and R 111 each represent hydrogen atoms or inert organic radicals and each R 1 is a saturated or aromatic hydrocarbon radical or an alkoxy, cycloalkoxy, aryloxy or aralkoxy group, may be hydrolysed or alcoholysed to form #-hydroxyalkyl silicon compounds. The compounds of Formula I are prepared by reacting a compound containing a silicon-hydrogen bond with a vinyloxysilane in the presence of a catalyst. The compound containing Si-H may be a mono- or poly-silane, polysilylalkane, polysiloxane or cyclopolysiloxane. Suitable catalysts are organic peroxides, ultra-violet light, nickel compounds and, preferably, platinum compounds. The #- siloxyalkyl silicon compound may be isolated or directly converted to the hydroxyalkyl compound. Where the original compound containing Si-H bonds also contain hydrolysable groups, the product will contain siloxane units. The hydrolysis may also take place in the presence of other hydrolysable silanes. The #-hydroxyalkyl compounds may be used as lubricants or in coating compositions or for the production of polycondensates by reaction with polyacids or polyisocyanates. The siloxyalkyl compounds of Formula 1 may also be used in impregnating compositions. Specification 1,060,910 is referred to.