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    Production of 4-fluorobenzaldehyde
    21.
    发明授权
    Production of 4-fluorobenzaldehyde 失效
    生产4-氟苯甲醛

    公开(公告)号：US06455739B1

    公开(公告)日：2002-09-24

    申请号：US09949380

    申请日：2001-09-07

    Applicant: Steven G. Karseboom ,  Michael J. Turpie ,  Phillip R. Devrou ,  John F. Balhoff

    Inventor： Steven G. Karseboom ,  Michael J. Turpie ,  Phillip R. Devrou ,  John F. Balhoff

    IPC: C07C4550

    CPC classification number: C07C29/124 ,  C07C45/49 ,  C12C11/02 ,  C07C33/46 ,  C07C47/55

    Abstract: 4-Fluorobenzaldehyde is produced by a commercially feasible process. The process comprises heating a mixture of fluorobenzene and a strong Lewis acid with dissolved hydrogen halide in an atmosphere of carbon monoxide at about 45 to about 100° C. and at a total pressure of about 150 psig up to the maximum pressure rating of the reactor. Formed is a reaction mass containing a Lewis acid complex of 4-fluorobenzaldehyde and at least a halobis(fluorophenyl)methane by-product. The complex is broken by quenching the reaction mass with a Lewis acid-solvating liquid to liberate 4-fluorobenzaldehyde. By-product halobis(fluorophenyl)methane is converted to di(fluorophenyl)methanol to avoid potential corrosion problems and formation of light sensitive color bodies in the recovered 4-fluorobenzaldehyde.

    Abstract translation: 4-氟苯甲醛是通过商业可行的方法生产的。 该方法包括在约45至约100℃的一氧化碳气氛中，在溶解的卤化氢气氛下加热氟苯和强路易斯酸的混合物，总压力为约150psig，直到反应器的最高额定压力 。 形成含有4-氟苯甲醛和至少一个卤代双（氟苯基）甲烷副产物的路易斯酸络合物的反应物质。 通过用路易斯酸溶剂化液体淬灭反应物质以释放4-氟苯甲醛来破坏络合物。 将副产物卤代（氟苯基）甲烷转化为二（氟苯基）甲醇，以避免在回收的4-氟苯甲醛中潜在的腐蚀问题和光敏颜料的形成。

    Method for producing aldehydes by hydroformylation in the presence of crown ether
    22.
    发明授权
    Method for producing aldehydes by hydroformylation in the presence of crown ether 失效
    在冠醚存在下通过加氢甲酰化生产醛的方法

    公开(公告)号：US06388142B1

    公开(公告)日：2002-05-14

    申请号：US09509143

    申请日：2000-05-16

    Applicant: Sandra Bogdanovic ,  Klaus Kuhlein

    Inventor： Sandra Bogdanovic ,  Klaus Kuhlein

    IPC: C07C4550

    CPC classification number: C07C45/50 ,  C07C47/02

    Abstract: The invention relates to a method for producing aldehydes by reacting one olefine containing 3 to 12 carbon atoms with hydrogen and carbon monoxide in the presence of one rhodium catalyst. The invention is characterized in that (a) the rhodium catalyst is present in an aqueous phase, whereby the aqueous phase contains i) rhodium in an elemental or bonded form, ii) one trisulfonated triaryl phosphine, and iii) one crown etherl (b) the olefine is present in the reaction conditions in a liquid organic phase which cannot be mixed with the aqueous phase.

    Abstract translation: 本发明涉及通过在一种铑催化剂存在下使含有3至12个碳原子的烯烃与氢气和一氧化碳反应来生产醛的方法。 本发明的特征在于（a）铑催化剂存在于水相中，其中水相含有i）元素或键合形式的铑，ii）一种三磺化三芳基膦，和iii）一种冠醚（b） 烯烃在反应条件下存在于不能与水相混合的液体有机相中。

    Metal-ligand complex catalyzed processes
    24.
    发明授权
    Metal-ligand complex catalyzed processes 有权
    金属 - 配体络合物催化方法

    公开(公告)号：US06303830B1

    公开(公告)日：2001-10-16

    申请号：US09526638

    申请日：2000-03-15

    Applicant: John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    Inventor： John Nicholas Argyropoulos ,  Jeffrey Scott Kanel ,  Michael Leo Tulchinsky ,  David James Miller ,  Donald Lee Morrison ,  Paul Foley ,  David Robert Bryant

    IPC: C07C4550

    CPC classification number: C07B63/00 ,  C07C67/58 ,  Y02P20/582 ,  C07C69/716

    Abstract: This invention relates to a process for separating one or more organophosphorus ligand degradation products, one or more reaction byproducts and one or more formylester products from a reaction product fluid comprising one or more unreacted unsaturated ester reactants, a metal-organophosphorus ligand complex catalyst, optionally free organophosphorus ligand, said one or more organophosphorus ligand degradation products, said one or more reaction byproducts, said one or more products, a polar solvent and a nonpolar solvent by phase separation wherein(i) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more products is expressed by a partition coefficient ratio Ef1 which is a value greater than about 2.5, (ii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more organophosphorus ligand degradation products is expressed by a partition coefficient ratio Ef2 which is a value greater than about 2.5, and (iii) the selectivity of the polar phase for the organophosphorus ligand with respect to the one or more reaction byproducts is expressed by a partition coefficient ratio Ef3 which is a value greater than about 2.5.

    Abstract translation: 本发明涉及一种从包含一种或多种未反应的不饱和酯反应物，金属 - 有机磷配位体配合物催化剂，任选的一种或多种反应产物流体的反应产物流体中分离一种或多种有机磷配体降解产物，一种或多种反应副产物和一种或多种甲酰酯产物的方法 所述一种或多种有机磷配体降解产物，所述一种或多种反应副产物，所述一种或多种产物，极性溶剂和非极性溶剂通过相分离，其中（i）极性相对于有机磷配体的选择性 对于一种或多种产物，由分配系数比Ef1表示，该分配系数比Ef1大于约2.5，（ii）极性相对于一种或多种有机磷配体降解产物的有机磷配体的选择性为 由大于约2.5的值的分配系数比Ef2表示，a d（iii）极性相对于一种或多种反应副产物的有机磷配体的选择性由分配系数比Ef3表示，该分配系数比Ef3是大于约2.5的值。

    Method for producing alkanals using a rhodium-tri-polyethylene glycolate
    26.
    发明授权
    Method for producing alkanals using a rhodium-tri-polyethylene glycolate 失效
    使用三聚乙酸铑生产链烷烃的方法

    公开(公告)号：US06225508B1

    公开(公告)日：2001-05-01

    申请号：US09462399

    申请日：2000-02-15

    Applicant: Sandra Bogdanovic ,  Herbert Roesky ,  Uwe Ritter ,  Thomas Borrmann

    Inventor： Sandra Bogdanovic ,  Herbert Roesky ,  Uwe Ritter ,  Thomas Borrmann

    IPC: C07C4550

    CPC classification number: C07C45/50 ,  B01J31/068 ,  B01J31/165 ,  B01J31/223 ,  B01J2231/321 ,  B01J2531/822 ,  C07C47/02

    Abstract: According to the invention, branched and straight chain alkenes and cycloalkenes with five and more C-atoms are by means of hydroformylation using a novel rhodium-tri-polyethylene glycolate of a polyethylene glycol with an average molecular weight of 320 to 650 as a catalyst with at hydrogen/carbon monoxide pressure of 60 to 200 bar and at a temperature of between 50 and 150° C. converted into branched and straight chain alkanals and cycloalkanals with six and more C-atoms. The reaction is preferably carried out in water or polyethylene glycol or a mixture of the same as a solvent in the heterogeneous phase. The aldehydes obtained are easy to separate from the catalyst in the reaction preparation. Said aldehydes are also obtained with a high level of purity and a high yield.

    Abstract translation: 根据本发明，具有五个以上C原子的支链和直链烯烃和环烯烃通过使用新型的平均分子量为320至650的聚乙二醇铑 - 三聚乙二醇酸作为催化剂进行加氢甲酰化， 在氢气/一氧化碳压力为60至200巴，温度为50至150℃之间，转化成支链和直链链烷烃和具有六个或更多个C原子的环烷烃。 该反应优选在水或聚乙二醇或与异相的溶剂相同的混合物中进行。 所得的醛在反应制备中容易与催化剂分离。 也可以获得高纯度和高产率的所述醛。

    Process for preparing aldehydes by hydroformylation
    27.
    发明授权
    Process for preparing aldehydes by hydroformylation 失效
    通过加氢甲酰化制备醛的方法

    公开(公告)号：US06211414B1

    公开(公告)日：2001-04-03

    申请号：US09341835

    申请日：1999-08-31

    Applicant: Sandra Bogdanovic ,  Helmut Bahrmann ,  Carl-Dieter Frohning ,  Ernst Wiebus

    Inventor： Sandra Bogdanovic ,  Helmut Bahrmann ,  Carl-Dieter Frohning ,  Ernst Wiebus

    IPC: C07C4550

    CPC classification number: C07C45/50 ,  C07C47/02

    Abstract: The invention concerns a process for preparing aldehydes by reacting with hydrogen and carbon monoxide at a temperature of between 20 and 170° C. and a pressure of between 1 and 300 bar an olefinically unsaturated C3-C5 compound in the presence of an aqueous phase containing rhodium and sulphonated triarylphosphines as catalyst and between 1 and 35 wt % of a compound of formula (1), R(OCH2CH2)nOR1, R standing for hydrogen, a straight-chain or branched C1-C4 alkyl group or a C1-C4 hydroxyalkyl group, R1 standing for hydrogen or a methyl group, and n standing for an integer from 3 to 50.

    Abstract translation: 本发明涉及一种通过在氢和一氧化碳的温度为20至170℃之间以及1-300巴之间的压力下在含有水相的存在下使烯属不饱和C 3 -C 5化合物反应来制备醛的方法 铑和磺化三芳基膦作为催化剂，和1-35重量％的式（1）化合物，R（OCH 2 CH 2）nOR 1，R代表氢，直链或支链C 1 -C 4烷基或C 1 -C 4羟基烷基 基团，R 1表示氢或甲基，n表示3〜50的整数。

    Production of oxygenated products
    28.
    发明授权
    Production of oxygenated products 有权
    生产含氧产品

    公开(公告)号：US06717018B2

    公开(公告)日：2004-04-06

    申请号：US10358998

    申请日：2003-02-05

    Applicant: Jan Petrus Steynberg ,  Khedaren Govender ,  Petrus Johannes Steynberg

    Inventor： Jan Petrus Steynberg ,  Khedaren Govender ,  Petrus Johannes Steynberg

    IPC: C07C4550

    CPC classification number: B01J31/248 ,  B01J2231/321 ,  B01J2531/821 ,  B01J2531/822 ,  B01J2531/824 ,  B01J2531/845 ,  C07B41/00 ,  C07C27/22

    Abstract: A process for producing oxygenated products from an olefinic feedstock, which process includes reacting, in a hydroformylation reaction stage, an olefin feedstock with carbon monoxide and hydrogen at elevated temperature and superatmospheric pressure in the presence of a hydroformylation catalyst. The hydroformylation catalyst comprises a mixture of a metal, M, where M is cobalt (Co), rhodium (Rh), ruthenium (Ru) or palladium (Pd); carbon monoxide; and a bicyclic tertiary phosphine having a ligating phosphorus atom. The ligating phosphorus atom is neither in a bridgehead position nor a member of a bridge linkage. The process produces oxygenated products comprising aldehydes and/or alcohols.

    Abstract translation: 一种从烯烃原料生产含氧产物的方法，该方法包括在加氢甲酰化反应阶段，在加氢甲酰化催化剂存在下，在升高的温度和超大气压下使烯烃原料与一氧化碳和氢气反应。 加氢甲酰化催化剂包括金属M的混合物，其中M是钴（Co），铑（Rh），钌（Ru）或钯（Pd）; 一氧化碳; 和具有连接磷原子的双环叔膦。 连接磷原子既不在桥头位置也不是桥连接件。 该方法产生包含醛和/或醇的含氧产物。

    Process for the hydroformylation of olefinically unsaturated compounds in a non-aqueous ionic solvent
    29.
    发明授权
    Process for the hydroformylation of olefinically unsaturated compounds in a non-aqueous ionic solvent 有权
    烯属不饱和化合物在非水离子溶剂中加氢甲酰化的方法

    公开(公告)号：US06617474B2

    公开(公告)日：2003-09-09

    申请号：US10053706

    申请日：2002-01-24

    Applicant: Frédéric Favre ,  Dominique Commereuc ,  Hélène Olivier-Bourbigou

    Inventor： Frédéric Favre ,  Dominique Commereuc ,  Hélène Olivier-Bourbigou

    IPC: C07C4550

    CPC classification number: C07C45/80 ,  C07C45/50 ,  C07C47/02

    Abstract: A process for the hydroformylation of an olefinically unsaturated compound in the liquid phase by reaction, in a reaction section, with carbon monoxide and hydrogen in the presence of a polar phase comprising: a non-aqueous ionic liquid which is at least partly miscible with the reaction products and comprises a salt of general formula Q+A−, in which Q+ represents a quaternary ammonium and/or phosphonium and A− represents an anion; and a catalyst comprising a compound or a complex of a transition metal of groups 8, 9 and 10, optionally co-ordinated with a ligand containing at least one atom of phosphorus, arsenic, antimony or nitrogen, comprises addition to the medium, after the reaction section, of an organic solvent in a manner such as to improve the separation by demixing of the crude reaction products from the said polar phase, which is recycled to the reaction section.

    Abstract translation: 在极性相存在下，通过在反应段中与一氧化碳和氢气反应，在液相中加氢甲酰化烯属不饱和化合物的方法，该方法包括：非水离子液体，其至少部分地与 反应产物并包含通式Q + A-的盐，其中Q +表示季铵和/或鏻，而A-代表阴离子;和催化剂，其包含化合物或第8,9族过渡金属的络合物 和10，任选地与含有至少一个磷，砷，锑或氮原子的配体配位，包括在反应段之后向介质中加入有机溶剂，以便通过分层改进分离 的来自所述极性相的粗反应产物，其被再循环到反应段。

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