公开(公告)号：US4376784A

公开(公告)日：1983-03-15

申请号：US246931

申请日：1981-03-24

申请人： Donald W. G. Harney ,  Peter G. Lehman ,  Joseph C. Rundle

发明人： Donald W. G. Harney ,  Peter G. Lehman ,  Joseph C. Rundle

IPC分类号： C07C69/007 ,  A01N37/06 ,  A01N37/10 ,  A01N37/14 ,  A01N37/38 ,  A01N53/00 ,  A01N53/02 ,  A01N53/08 ,  A01N53/10 ,  C07C43/29 ,  C07C67/00 ,  C07C69/612 ,  C07C69/74 ,  C07C69/743 ,  C07C253/00 ,  C07C255/38 ,  C07D209/48 ,  C07D209/49 ,  C07D307/45 ,  C07D307/83 ,  C07D333/32 ,  C07C69/614

CPC分类号： C07D209/48 ,  A01N37/14 ,  A01N37/38 ,  A01N53/00 ,  C07C255/00 ,  C07C43/29 ,  C07D209/49 ,  C07D307/42 ,  C07D333/32

摘要： The invention concerns novel pesticidal esters of the pyrethrin or pyrethroid type in which the methylene group bonded to the ester carbonyl and/or ester oxygen bears a fluorine substituent. The compounds of the invention are active against insect pests including flies, moths, aphids and beetles and acarina pests including ticks.

公开(公告)号：US4356187A

公开(公告)日：1982-10-26

申请号：US141201

申请日：1980-04-17

申请人： Jacques Martel ,  Jean Tessier ,  Andre Teche

发明人： Jacques Martel ,  Jean Tessier ,  Andre Teche

IPC分类号： C07C69/013 ,  A01N37/10 ,  A01N37/18 ,  A01N37/34 ,  A01N53/00 ,  A01N53/02 ,  A01N53/10 ,  A23K1/16 ,  C07C29/09 ,  C07C29/32 ,  C07C45/66 ,  C07C45/72 ,  C07C49/24 ,  C07C61/35 ,  C07C62/38 ,  C07C67/00 ,  C07C231/00 ,  C07C231/02 ,  C07C231/12 ,  C07C235/30 ,  C07C235/34 ,  C07C253/00 ,  C07C255/31 ,  C07C313/00 ,  C07C323/62 ,  C07D307/58 ,  C07D333/32 ,  C07F9/54 ,  C07C121/48 ,  A01N37/08 ,  C07C69/743 ,  C07C121/66

CPC分类号： C07D333/32 ,  A01N53/00 ,  C07C29/095 ,  C07C29/32 ,  C07C45/66 ,  C07C45/72 ,  C07C49/24 ,  C07C61/35 ,  C07C62/38 ,  C07D307/58 ,  C07F9/5407 ,  C07B2200/07 ,  C07B2200/09 ,  C07C2101/10

摘要： Novel esters of the formula ##STR1## wherein R.sub.1 and R.sub.2 are individually selected from the group consisting of carbamoyl and R.sub.1 ' and R.sub.2 ', R.sub.1 ' and R.sub.2 ' are individually selected from the group consisting of hydrogen, halogen, alkyl of 1 to 6 carbon atoms, aryl of 6 to 10 carbon atoms, aralkyl of 7 to 13 carbon atoms, alkoxycarbonyl of 2 to 5 carbon atoms and --CN, R.sub.3 and R.sub.3 ' are individually selected from the group consisting of hydrogen, halogen, alkenyl of 2 to 3 carbon atoms and alkyl of 1 to 3 carbon atoms, Y' is selected from the group consisting of ##STR2## R.sub.4 ' and R.sub.5 ' are individually selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms, fluorine, bromine, chlorine and R.sub.4 ' and R.sub.5 ' together with the carbon atom to which they are attached form an optionally unsaturated hydrocarbon ring or heterocycle of 3 to 7 chain members and a heterocycle of the formula X is selected from the group consisting of sulfur and oxygen or R.sub.4 ' is cyano and R.sub.5 ' is phenyl or R.sub.4 ' is hydrogen and R.sub.5 ' is selected from the group consisting of cyano, ##STR3## AlK is alkyl of 1 to 4 carbon atoms, the double bond in the 1- position of the vinyl side chain of formula (A) having (E) or (Z) configuration, R.sub.6 is selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms and alkoxycarbonyl of 2 to 5 carbon atoms, the substituents on the cyclopropane ring of formula (A) and (C) have the cis or trans, racemic or optically active configuration, Z.sub.1 is alkyl of 1 to 4 carbon atoms, Z.sub.2, Z.sub.3 and Z.sub.4 are individually selected from the group consisting of hydrogen, alkyl of 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms and halogen and the asymetric carbon of formula (D) may be (S) or (R) configuration or a racemic mixture thereof and the carbon atom in the 1- position of the alcohol moiety may have (R), (S) or racemic configuration having insecticidal properties and their preparations.

公开(公告)号：US4309350A

公开(公告)日：1982-01-05

申请号：US115044

申请日：1980-01-24

申请人： George Holan ,  Reimund Walser

发明人： George Holan ,  Reimund Walser

IPC分类号： C07C69/007 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/08 ,  A01N53/10 ,  A01N57/00 ,  C07C51/00 ,  C07C51/353 ,  C07C61/28 ,  C07C61/39 ,  C07C61/40 ,  C07C62/34 ,  C07C67/00 ,  C07C69/612 ,  C07C69/618 ,  C07C69/73 ,  C07C69/734 ,  C07C69/74 ,  C07C69/747 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C205/56 ,  C07C227/00 ,  C07C227/16 ,  C07C227/18 ,  C07C229/46 ,  C07C253/00 ,  C07C255/38 ,  C07C255/39 ,  C07C255/42 ,  C07C313/00 ,  C07C323/62 ,  C07D307/36 ,  C07D307/42 ,  C07D307/45 ,  C07D307/54 ,  C07D317/06 ,  C07D317/46 ,  C07D317/54 ,  C07D317/60 ,  C07C69/76 ,  C07C79/46 ,  C07C101/00

CPC分类号： C07D307/42 ,  A01N53/00 ,  C07C255/00 ,  C07D307/54 ,  C07D317/60 ,  Y10S514/919

摘要： The (+), (-) and (.+-.) forms of the compounds of formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, nitro or amino group, andR.sup.2 is a hydrogen or methyl group or R.sup.1 and R.sup.2 together form a methylenedioxy group;R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (d):(a) m-phenoxybenzyl,(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-m-phenoxybenzyl(d) 3-4-methylenedioxy-benzyl,and R.sup.4 and R.sup.5 are the same or different groups and each is a fluoro, bromo, chloro or methyl group.The compounds of formula I in which R.sup.3 is one of groups (a) to (d) are extremely active as insecticides (except when R.sup.1 is an amino group). The compounds also possess the property of contact repellency to insects.

摘要翻译： 式I化合物的（+），（ - ）和（+/-）形式其中R 1是氢或甲氧基，乙氧基，丙氧基，甲硫基，乙硫基，丙硫基，氟，氯，溴，甲基 ，乙基，硝基或氨基，R2是氢或甲基，或者R1和R2一起形成亚甲二氧基; R3是氢或低级烷基，或下列基团之一（a）至（d）：（a）间苯氧基苄基，（b）2-苄基-4-呋喃基甲基（c）α-氰基 - 苯氧基苄基（d）3-4-亚甲二氧基 - 苄基，R 4和R 5是相同或不同的基团，并且各自是氟，溴，氯或甲基。 其中R3是基团（a）至（d）之一的式I化合物作为杀虫剂是非常有活性的（除了当R1是氨基时）。 该化合物还具有与昆虫接触排斥性的性质。

公开(公告)号：US4296091A

公开(公告)日：1981-10-20

申请号：US128461

申请日：1980-03-10

申请人： Robert Joly ,  Charles Pavan ,  Pierre R. Carle

发明人： Robert Joly ,  Charles Pavan ,  Pierre R. Carle

IPC分类号： A01N53/00 ,  A01N53/02 ,  A01N53/10 ,  A01N25/00 ,  A01N25/06 ,  A01N37/00 ,  A01N37/08

CPC分类号： A01N53/00

摘要： Novel synergistic insecticidal compositions comprising as the active ingredient an insecticidally effective amount of a synergistic mixture of 90 to 60% by weight of (S) 1-oxo-2-allyl-3-methyl-cyclopent-2-en-4-yl d trans chrysanthemate and 10 to 40% by weight of (R) 1-oxo-2-allyl-3-methyl-cyclopent-2-en-4-yl d trans chrysanthemate and to a novel method of combatting arthropodes.

摘要翻译： 包含作为活性成分的杀虫有效量的90至60重量％的（S）1-氧代-2-烯丙基-3-甲基 - 环戊-2-烯-4-基d的协同混合物的新型协同杀虫组合物 （R）1-氧代-2-烯丙基-3-甲基 - 环戊-2-烯-4-基d反式菊酸的10〜40重量％，以及一种新型的对抗节肢动物的方法。

公开(公告)号：US4229469A

公开(公告)日：1980-10-21

申请号：US642920

申请日：1975-12-22

申请人： Toshio Mizutani ,  Nobushige Itaya ,  Nobuo Ohno ,  Takashi Matsuo ,  Shigeyoshi Kitamura ,  Yositosi Okuno

发明人： Toshio Mizutani ,  Nobushige Itaya ,  Nobuo Ohno ,  Takashi Matsuo ,  Shigeyoshi Kitamura ,  Yositosi Okuno

IPC分类号： C07C69/74 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  C07D207/44 ,  C07D207/452 ,  C07D209/46 ,  C07D209/48 ,  C07D307/45 ,  C07D307/58 ,  C07D307/80 ,  C07D333/16 ,  C07D333/78 ,  C07D493/04 ,  A01N9/20 ,  C07C121/75

CPC分类号： C07D207/452 ,  A01N53/00 ,  C07D209/46 ,  C07D209/48 ,  C07D209/49 ,  C07D307/42 ,  C07D307/58 ,  C07D307/80 ,  C07D333/16 ,  C07D333/78 ,  C07D493/04

摘要： A compound of the formula, ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are respectively hydrogen atom or methyl, R.sub.5 is a member of ##STR2## wherein R.sub.6 is hydrogen atom or methyl, R.sub.7 is alkenyl, alkadienyl, alkynyl or benzyl, R.sub.8 is hydrogen atom, ethynyl or cyano, R.sub.9 is hydrogen atom, a halogen atom or alkyl, R.sub.10 is a halogen atom, alkyl, alkenyl, alkynyl, benzyl, thenyl, furylmethyl, phenoxy, substituted phenoxy or phenylthio, or R.sub.9 and R.sub.10 are bonded at the ends to form polymethylene chain containing or not containing oxygen or sulfur atom, Y is oxygen atom, sulfur atom or --CH.dbd.CH--, n is 1 or 2, Z is phthalimido, thiophthalimido, di- or tetra-hydrophthalimido or dialkylmaleimido, R.sub.11 is phenyl, thienyl or furyl and X is a halogen atom, which is useful as an active ingredient of insecticides.

摘要翻译： 下式化合物，其中R 1，R 2，R 3和R 4分别是氢原子或甲基，R 5是其中R 6是氢原子或甲基，R 7是链烯基， ，炔基或苄基，R8是氢原子，乙炔基或氰基，R9是氢原子，卤原子或烷基，R10是卤素原子，烷基，烯基，炔基，苄基，噻吩基，呋喃基甲基，苯氧基，取代的苯氧基或苯硫基， 或R 9和R 10在末端键合以形成含有或不含氧原子或硫原子的多亚甲基链，Y为氧原子，硫原子或-CH = CH-，n为1或2，Z为苯二甲酰亚氨基，硫代邻苯二甲酰亚氨基， 或四邻苯二甲酰亚胺基或二烷基马来酰亚胺基，R 11为苯基，噻吩基或呋喃基，X为卤素原子，其可用作杀虫剂的活性成分。

公开(公告)号：US4225612A

公开(公告)日：1980-09-30

申请号：US76022

申请日：1979-09-17

申请人： James E. Powell

发明人： James E. Powell

IPC分类号： A01N53/00 ,  A01N53/02 ,  C07D317/30 ,  A01N9/12 ,  A01N9/28 ,  C07D339/06

CPC分类号： A01N53/00 ,  C07D317/30

摘要： New cyclopropane compounds have the formula ##STR1## wherein Y and Z each independently is oxygen or sulfur and X is chlorine, bromine or OR in which R is hydrogen, a salt-forming cation, an alkyl group or residues of certain other alcohols. The compounds are pesticides or intermediates therefore.

摘要翻译： 新的环丙烷化合物具有式“IMAGE”，其中Y和Z各自独立地是氧或硫，X是氯，溴或OR，其中R是氢，成盐阳离子，烷基或某些其它醇的残基。 因此，化合物是农药或中间体。

公开(公告)号：US4224227A

公开(公告)日：1980-09-23

申请号：US18166

申请日：1979-03-07

申请人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

发明人： Jacques Martel ,  Jean Tessier ,  Jean-Pierre Demoute

IPC分类号： C07C69/74 ,  A01N33/00 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/08 ,  A01P3/00 ,  A23K1/16 ,  A61K31/215 ,  A61K31/34 ,  A61K31/40 ,  A61K35/14 ,  A61P31/04 ,  C07C20060101 ,  C07C51/00 ,  C07C51/363 ,  C07C53/50 ,  C07C61/04 ,  C07C61/15 ,  C07C67/00 ,  C07C69/743 ,  C07C253/00 ,  C07C255/39 ,  C07D209/48 ,  C07D209/49 ,  C07D307/42 ,  C07D307/45 ,  C07D307/54 ,  C07D317/54 ,  G01G13/295 ,  A01N9/28

CPC分类号： C07D209/49 ,  A01N53/00 ,  C07C255/00 ,  C07C61/15 ,  C07D307/42 ,  Y10S514/949

摘要： Novel cyclopropane carboxylic acid esters of the formula ##STR1## wherein X.sub.1 is selected from the group consisting of hydrogen, fluorine, chlorine and bromine, X.sub.2 is selected from the group consisting of fluorine, chlorine and bromine, X.sub.3 is selected from the group consisting of chlorine, bromine and iodine and R is selected from the group consisting of ##STR2## and benzyl optionally substituted with at least one member of the group consisting of alkyl of 1 to 4 carbon atoms, alkenyl of 2 to 6 carbon atoms, alkenyloxy of 2 to 6 carbon atoms, alkadienyl of 4 to 8 carbon atoms, methylenedioxy, benzyl and halogens, R.sub.1 is selected from the group consisting of hydrogen and methyl, R.sub.2 is selected from the group consisting of monocyclic aryl and --CH.sub.2 --C.tbd.CH,R.sub.3 is an aliphatic of 2 to 6 carbon atoms having at least one double bond, R.sub.4 is selected from the group consisting of hydrogen, --CN and --C.tbd.CH, R.sub.5 is selected from the group consisting of chlorine and methyl, n is 0, 1 or 2, R.sub.6, R.sub.7, R.sub.8 and R.sub.9 are individually selected from the group consisting of hydrogen, chlorine and methyl and S/I indicates that the ring may be aromatic, dihydro or tetrahydro having pesticidal properties, and a process for their preparation.

摘要翻译： 新的式（I）的环丙烷羧酸酯，其中X 1选自氢，氟，氯和溴，X 2选自氟，氯和溴，X 3选自 的氯，溴和碘，R选自 和任选被至少一个由1至4个碳原子的烷基取代的苄基， 2至6个碳原子的烯氧基，2至6个碳原子的链烯氧基，4至8个碳原子的链二烯基，亚甲二氧基，苄基和卤素，R1选自氢和甲基，R2选自单环 芳基和-CH 2 -C 3 CH 3，R 3是具有至少一个双键的2至6个碳原子的脂族基，R 4选自氢，-CN和-C 3位CH，R 5选自 由氯和甲基组成 n为0,1或2，R6，R7，R8和R9分别选自氢，氯和甲基，S / I表示该环可为具有杀虫性质的芳香族二氢或四氢，以及 一个他们准备的过程。

公开(公告)号：US4220591A

公开(公告)日：1980-09-02

申请号：US742575

申请日：1976-11-17

申请人： George Holan ,  Reimund A. Walser

发明人： George Holan ,  Reimund A. Walser

IPC分类号： C07C69/007 ,  A01N53/00 ,  A01N53/02 ,  A01N53/04 ,  A01N53/08 ,  A01N53/10 ,  A01N57/00 ,  C07C51/00 ,  C07C51/353 ,  C07C61/28 ,  C07C61/39 ,  C07C61/40 ,  C07C62/34 ,  C07C67/00 ,  C07C69/612 ,  C07C69/618 ,  C07C69/73 ,  C07C69/734 ,  C07C69/74 ,  C07C69/747 ,  C07C69/753 ,  C07C69/757 ,  C07C201/00 ,  C07C205/55 ,  C07C205/56 ,  C07C227/00 ,  C07C227/16 ,  C07C227/18 ,  C07C229/46 ,  C07C253/00 ,  C07C255/38 ,  C07C255/39 ,  C07C255/42 ,  C07C313/00 ,  C07C323/62 ,  C07D307/36 ,  C07D307/42 ,  C07D307/45 ,  C07D307/54 ,  C07D317/06 ,  C07D317/46 ,  C07D317/54 ,  C07D317/60 ,  C07C69/76

CPC分类号： C07D307/42 ,  A01N53/00 ,  C07C255/00 ,  C07D307/54 ,  C07D317/60 ,  Y10S514/919

摘要： The (+), (-) and (.+-.) forms of the compounds of formula I ##STR1## wherein R.sup.1 is hydrogen or a methoxy, ethoxy, propoxy, methylthio, ethylthio, propylthio, fluoro, chloro, bromo, methyl, ethyl, nitro or amino group, andR.sup.2 is a hydrogen or methyl group or R.sup.1 and R.sup.2 together form a methylenedioxy group;R.sup.3 is hydrogen, or a lower alkyl group, or one of the following groups (a) to (d):(a) m-phenoxybenzyl(b) 2-benzyl-4-furylmethyl(c) .alpha.-cyano-m-phenoxybenzyl(d) 3,4-methylenedioxy-benzyl, andR.sup.4 and R.sup.5 are the same or different groups and each is a fluoro, bromo, chloro or methyl group.The compounds of formula I in which R.sup.3 is one of group (a) to (d) are extremely active as insecticides (except when R.sup.1 is an amino group). The compounds also possess the property of contact repellency to insects.

摘要翻译： 其中R 1是氢或甲氧基，乙氧基，丙氧基，甲硫基，乙硫基，丙硫基，氟，氯，溴，甲基，或它们的（+），（ - ）和（+/-） 乙基，硝基或氨基，R 2为氢或甲基，或者R 1和R 2一起形成亚甲二氧基; R3是氢或低级烷基，或以下基团之一（a）至（d）：（a）间苯氧基苄基（b）2-苄基-4-呋喃基甲基（c）α-氰基间苯氧基苄基 （d）3,4-亚甲二氧基 - 苄基，R 4和R 5是相同或不同的基团，各自是氟，溴，氯或甲基。 其中R 3为（a）至（d）中的一种的式I化合物作为杀虫剂是非常有活性的（除了当R1为氨基时）。 该化合物还具有与昆虫接触排斥性的性质。

公开(公告)号：US4219563A

公开(公告)日：1980-08-26

申请号：US50735

申请日：1979-06-21

申请人： James E. Powell

发明人： James E. Powell

IPC分类号： A01N53/00 ,  A01N53/02 ,  A01N9/20 ,  C07C131/02

CPC分类号： A01N53/00

摘要： Compounds of the formula ##STR1## wherein R.sup.1 is a hydrocarbyl group, W is a chlorine or bromine atom or --OR in which R is H, a salt-forming cation, an alkyl group or the residue of a pyrethroid alcohol are new pesticides or intermediates therefore. The compounds are prepared using a multi-step synthesis starting from the natural terpene, 3-carene.

公开(公告)号：US4211792A

公开(公告)日：1980-07-08

申请号：US13778

申请日：1979-02-21

申请人： Steven A. Roman ,  Samuel B. Soloway

发明人： Steven A. Roman ,  Samuel B. Soloway

IPC分类号： A01N53/00 ,  A01N53/02 ,  C07D307/45 ,  A01N9/24 ,  C07C131/02 ,  C07C131/04

CPC分类号： C07D307/42 ,  A01N53/00

摘要： (1R,trans)-cyclopropane compounds, substantially free of other stereoisomers, and having the formula ##STR1## wherein X is chlorine, bromine or OR in whichR is hydrogen, a salt-forming cation, an alkyl group or residues of certain other alcohols; andR.sup.1 is certain optionally halogenated hydrocarbyl groups, are highly active pesticides or intermediates therefore.

摘要翻译： （1R，反式）环丙烷化合物，基本上不含其它立体异构体，并具有下式的化合物：其中X是氯，溴或OR，其中R是氢，成盐阳离子，烷基或某些其它的残基 醇类 因此，R 1是任选卤代烃基，因此是高活性的农药或中间体。