Styrene-assisted depolymerization of polyolefins

    公开(公告)号:US12173124B2

    公开(公告)日:2024-12-24

    申请号:US17450234

    申请日:2021-10-07

    Abstract: Methods of depolymerizing polyolefin-based material into useful petrochemical products using styrene oligomers or polymers, and heat are described. The styrene oligomers or polymers improve the depolymerization reaction by decreasing the halftime for the depolymerization, which results in a higher depolymerization rate and a shorter residence time in the depolymerization unit, allowing for a predictable depolymerization reaction, and decreasing the branching or aromatic formations in the product.

    Polymer compositions suitable for producing plated products

    公开(公告)号:US12037688B2

    公开(公告)日:2024-07-16

    申请号:US17602369

    申请日:2020-03-23

    CPC classification number: C23C18/1641 C08L23/12 C23C18/1653 C23C18/31 C25D5/14

    Abstract: A method for the production of metal-plated articles, including the step of



    depositing an electrically-conductive metallic layer on a surface of an article comprising a polymer composition comprising by weight:

    a) 40-60% of a propylene homopolymer, or propylene copolymer containing up to 5% by weight of ethylene and/or another C4-C10 α-olefin, and having a melting temperature of 155° C. or higher and/or a fraction soluble in xylene at 25° C. of 10% by weight or less;
    b) 10-20% of an ethylene-based elastoplastic copolymer, optionally, a copolymer of ethylene with C4-C10 α-olefin;
    c) 2-6% of a styrene block copolymer;
    d) optionally, up to 3% of a propylene homopolymer having a Melt Flow Rate (230° C./2.16 kg) of 500 g/10 min. or more;
    e) 15-50% of a filler; and
    f) optionally, up to 6% of a color pigment.

    PRE-POLYMERIZED CATALYST COMPONENTS FOR THE POLYMERIZATION OF OLEFINS

    公开(公告)号:US20240218091A1

    公开(公告)日:2024-07-04

    申请号:US18285835

    申请日:2022-03-24

    CPC classification number: C08F10/02

    Abstract: A pre-polymerized catalyst component for the polymerization of olefins made from or containing (a) a solid catalyst component made from or containing Ti, Mg, and a halogen and optionally, a bidentate electron donor compound (BE) in an amount such that the molar ratio (BE)/Ti ranges from 0 to 0.3, and (b) an ethylene (co)polymer in an amount ranging from 0.1 g up to less than 30 g per g of the solid catalyst component, and having an intrinsic viscosity, measured in tetraline at 135° C., of at least 3.0 dL/g, wherein the pre-polymerized catalyst component has a porosity measured by mercury method in the range 0.1 to 1 cm3/g.

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