公开(公告)号：US4299929A

公开(公告)日：1981-11-10

申请号：US169090

申请日：1980-07-15

申请人： Hajime Sakano ,  Mikio Kodama ,  Akitoshi Ito ,  Miyuki Terada

发明人： Hajime Sakano ,  Mikio Kodama ,  Akitoshi Ito ,  Miyuki Terada

IPC分类号： C08K3/24 ,  C08K5/09 ,  C08L7/00 ,  C08L21/00 ,  C08L51/00 ,  C08L51/02 ,  C08L51/04 ,  C08L53/02 ,  C08L55/00 ,  C08L55/02 ,  C08L69/00

CPC分类号： C08L51/04 ,  C08K5/09 ,  C08L53/02 ,  C08L69/00

摘要： A thermoplastic resin composition with excellent dwelling thermal stability which comprises 100 parts by weight of a resin composition comprising a polymer (A) obtained by polymerization of at least two kinds of monomers selected from the group consisting of aromatic vinyl compounds, vinyl cyanide compounds and carboxylic acid alkyl esters in the presence of a conjugated diene rubber and a polycarbonate resin (B) in a weight proportion of from 10:90 to 90:10 and 0.05 to 5.0 parts by weight of at least one acid compound (C) chosen from inorganic acids, organic acids and organic acid anhydrides.

摘要翻译： 一种具有优异的住宅热稳定性的热塑性树脂组合物，其包含100重量份的树脂组合物，所述树脂组合物包含通过聚合选自芳族乙烯基化合物，乙烯基氰化合物和羧酸中的至少两种单体获得的聚合物（A） 在共轭二烯橡胶和聚碳酸酯树脂（B）的存在下，以10:90至90:10的重量比和0.05至5.0重量份的至少一种选自无机的酸性化合物（C）的酸性烷基酯 酸，有机酸和有机酸酐。

公开(公告)号：US4296216A

公开(公告)日：1981-10-20

申请号：US127287

申请日：1980-03-05

申请人： Hajime Sakano ,  Mikio Kodama ,  Koichi Nakayama ,  Isao Yoshida ,  Atsunori Inoue

发明人： Hajime Sakano ,  Mikio Kodama ,  Koichi Nakayama ,  Isao Yoshida ,  Atsunori Inoue

IPC分类号： C08L25/12 ,  C08L51/04 ,  C08L59/02 ,  C08L77/00 ,  C09D159/02 ,  C09J177/00 ,  C08L55/02 ,  C08L59/04

CPC分类号： C08L77/00 ,  C08L25/12 ,  C08L51/04 ,  C09D159/02 ,  C09J177/00 ,  C08L59/02

摘要： A thermoplastic resin composition excellent in coating property which comprises (A) at least one of polyamide resins and polyacetal resins, (B) at least one of aromatic monovinyl compound/vinyl cyanide copolymers comprising units of aromatic monovinyl compounds and units of vinyl cyanides in a weight ratio of 60:40 to 80:20 and having an intrinsic viscosity of 0.3 to 1.1 and (C) at least one of conjugated diene rubber/vinyl cyanide graft copolymers comprising units of conjugated diene rubbers in an amount of 5 to 45% by weight based on the weight of the graft copolymers in a weight proportion of the components (A), (B) and (C) being 0.1-10: 5-90: 5-94.9.

摘要翻译： 一种涂料性能优异的热塑性树脂组合物，其包含（A）至少一种聚酰胺树脂和聚缩醛树脂，（B）至少一种芳族单乙烯基化合物/乙烯基氰共聚物，其包含芳族单乙烯基化合物单元和乙烯基氰化物单元 重量比为60:40至80:20，特性粘度为0.3至1.1，（C）至少一种共轭二烯橡胶/乙烯基氰接枝共聚物，其包含共轭二烯橡胶单元的量为5至45％ 基于组分（A），（B）和（C）的重量比例的接枝共聚物的重量的重量为0.1-10:5-90:5-94.9。

公开(公告)号：US3970629A

公开(公告)日：1976-07-20

申请号：US531199

申请日：1974-12-09

申请人： Nobujiro Izaki ,  Masashi Nakayama ,  Saburo Mishiba ,  Sadao Sekiguchi

发明人： Nobujiro Izaki ,  Masashi Nakayama ,  Saburo Mishiba ,  Sadao Sekiguchi

IPC分类号： C08F236/04 ,  D21H19/58 ,  C08L1/02 ,  C08L3/04 ,  C08L9/08

CPC分类号： D21H19/58 ,  C08F236/04 ,  Y10T428/31993

摘要： A composition for paper coating which comprises a pigment and, as a pigment binder, a synthetic copolymer latex comprising about 24.5 to 50 parts by weight of at least one aliphatic conjugated diolefin, about 0.5 to 10 parts by weight of at least one ethylenically unsaturated carboxylic acid and about 40 to 75 parts by weight of at least one monoolefinic monomer copolymerizable with the aliphatic conjugated diolefin and the ethylenically unsaturated carboxylic acid, the synthetic copolymer having a gel content of not more than about 60 % by weight based on the weight of the synthetic copolymer.

摘要翻译： 一种用于纸涂层的组合物，其包含颜料和作为颜料粘合剂的合成共聚物胶乳，其包含约24.5至50重量份的至少一种脂族共轭二烯烃，约0.5至10重量份的至少一种烯键式不饱和羧酸 和约40至75重量份的至少一种可与脂族共轭二烯烃和烯属不饱和羧酸共聚的单烯属单体，该合成共聚物的凝胶含量不超过约60重量％，基于 合成共聚物。

公开(公告)号：US5266634A

公开(公告)日：1993-11-30

申请号：US793726

申请日：1991-11-20

申请人： Akitoshi Ito ,  Yutaka Yoshida

发明人： Akitoshi Ito ,  Yutaka Yoshida

IPC分类号： C08L51/04 ,  C08L69/00 ,  C08L51/06 ,  C08L55/02

CPC分类号： C08L51/04 ,  C08L69/00

摘要： A resin composition containing a mixture of a polycarbonate resin and a rubber-reinforced styrene base resin which is prepared by polymerizing, in the presence of a rubbery polymer, a monomer mixture of an aromatic vinyl monomer, at least one of cyanated vinyl monomers and alkyl esters of unsaturated carboxylic acids and at least one other vinyl monomer; a polyolefin graft polymer which is prepared by polymerizing, in the presence of a crystalline polyolefin, a monomer of an aromatic vinyl monomer and at least one of cyanated vinyl monomers and alkyl esters of unsaturated carboxylic acids; and optionally a terpolymer of an olefin, an unsaturated dicarboxylic anhydride and an alkyl ester of an unsaturated carboxylic acid or an epoxy group-containing olefin copolymer of an unsaturated epoxy compound, an olefin and optionally an ethylenically unsaturated compound, which composition has good coating properties.

公开(公告)号：US4880874A

公开(公告)日：1989-11-14

申请号：US246817

申请日：1988-09-07

申请人： Mikio Hirai ,  Tokuo Tatsuda ,  Tomio Yoshida

发明人： Mikio Hirai ,  Tokuo Tatsuda ,  Tomio Yoshida

IPC分类号： C08L51/06 ,  C08L69/00

CPC分类号： C08L51/06 ,  C08L69/00

摘要： A resin composition comprising(A) 10 to 99% by weight of a polycarbonate resin and(B) 90 to 1% by weight of a resin which comprises(b-1) 100 to 10% by weight of a copolymer which is obtainable by polymerizing 1 to 800 parts by weight of an unsaturated epoxy monomer and 0 to 2,000 parts by weight of other copolymerizable monomer in the presence of 100 parts by weight of an ethylene-.alpha.-olefin base rubber, and(b-2) 0 to 90% by weight of a copolymer which is obtainable by polymerizing at least one monomer selected from the group consisting of aromatic vinyl compounds, cyanated vinyl compounds and alkyl unsaturated carboxylates.

摘要翻译： PCT No.PCT / JP88 / 00074 Sec。 371日期：1988年9月7日 102（e）1988年9月7日PCT PCT 1月29日，PCT PCT。 第WO88 / 05800号公报 日本1988年8月11日。一种树脂组合物，其包含（A）10至99重量％的聚碳酸酯树脂和（B）90至1重量％的树脂，其包含（b-1）100至10重量％ 的共聚物，其通过在100重量份的乙烯-α-烯烃基础橡胶的存在下聚合1至800重量份的不饱和环氧单体和0至2,000重量份的其它可共聚单体，和（ b-2）0〜90重量％的共聚物，其通过聚合选自芳族乙烯基化合物，氰化乙烯基化合物和烷基不饱和羧酸酯中的至少一种单体而获得。

公开(公告)号：US4855355A

公开(公告)日：1989-08-08

申请号：US174166

申请日：1988-03-28

申请人： Mikio Hirai ,  Tokuo Tatsuda ,  Tomio Yoshida

发明人： Mikio Hirai ,  Tokuo Tatsuda ,  Tomio Yoshida

IPC分类号： C08L21/00 ,  C08L51/04 ,  C08L51/06 ,  C08L63/00 ,  C08L63/08 ,  C08L67/00 ,  C08L67/02

CPC分类号： C08L67/02

摘要： A molding resin composition comprising (A) a saturated polyester resin, (B) a graft copolymer and (C) a rubber-reinforced resin, wherein a weight ratio of the saturated polyester resin (A) to a total weight of the graft copolymer (B) and the rubber-reinforced resin (C) is from 95:5 to 5:95, a weight ratio of the graft copolymer (B) to the rubber-reinforced resin is from 100:0 to 5:95, and the graft copolymer (B) is one prepared by copolymerizing an unsaturated epoxide monomer and at least one monomer selected from the group consisting of aromatic vinyl monomers, cyanated vinyl monomers and alkyl unsaturated carboxylates in the presence of an ethylene-.alpha.-olefin base rubber, which can provide a molded article having improved impact strength, weld strength, stiffness and mold shrinkage factor.

公开(公告)号：US4381365A

公开(公告)日：1983-04-26

申请号：US316519

申请日：1981-10-29

申请人： Saburo Mishiba ,  Junkoh Hyoda ,  Akira Uchida ,  Hisao Usami ,  Akira Watanabe

发明人： Saburo Mishiba ,  Junkoh Hyoda ,  Akira Uchida ,  Hisao Usami ,  Akira Watanabe

IPC分类号： C08F2/22 ,  C08F236/04 ,  D21H19/58 ,  C08F279/02

CPC分类号： D21H19/58 ,  C08F236/04 ,  Y10S525/902 ,  Y10T428/31895

摘要： A process for preparing a copolymer latex by polymerization of at least one aliphatic conjugated diene monomer, at least one ethylenically unsaturated carboxylic acid monomer and at least one monoolefinic monomer copolymerizable with them in a weight proportion of 19.5-80:0.5-10:10-80, characterized in that (a) a mixture of the whole amount of the aliphatic conjugated diene monomer, the whole amount of the ethylenically unsaturated carboxylic acid monomer and a portion of the monoolefinic monomer, the combined amount of them being from 45 to 99% by weight on the basis of the total amount of the starting monomers, is subjected to emulsion polymerization, and (b) after or while the remainder of the monoolefinic monomer in an amount of from 1 to 55% by weight on the basis of the total amount of the starting monomers is added to the reaction mixture, the further emulsion polymerization is carried out.

摘要翻译： 通过使至少一种脂族共轭二烯单体，至少一种烯键式不饱和羧酸单体和至少一种可与它们共聚的至少一种脂族共轭二烯单体，重量比例为19.5-80:0.5-10-10的聚合制备共聚物胶乳的方法。 80，其特征在于，（a）全部量的脂族共轭二烯单体，全部量的烯键式不饱和羧酸单体和一部分单烯烃单体的混合物的总量为45〜99％ 基于起始单体的总量计，进行乳液聚合，和（b）剩余的单烯烃单体之后或之后，其量为1至55重量％，基于总计 将起始单体的量加入到反应混合物中，进行进一步的乳液聚合。

公开(公告)号：US4112021A

公开(公告)日：1978-09-05

申请号：US750766

申请日：1976-12-15

申请人： Takesaburo Shima ,  Hiroshi Kozima ,  Tomio Yoshida ,  Joji Nakamura

发明人： Takesaburo Shima ,  Hiroshi Kozima ,  Tomio Yoshida ,  Joji Nakamura

IPC分类号： C08F285/00 ,  C08F2/16 ,  C08F279/04

CPC分类号： C08F279/04

摘要： A process for producing a thermoplastic resin having excellent impact resistance and processability, which comprises polymerizing an aromatic monovinyl monomer and a vinyl cyanide monomer in the presence of an aqueous elastomeric latex, mixing with agitation the resulting copolymer latex with an aromatic monovinyl monomer and a vinyl cyanide monomer in the presence of a polyalkylene oxide and a coagulant to give a stable suspension phase, and polymerizing the mixture, and said thermoplastic resin thus produced, and a composition comprising said thermoplastic resin and a copolymer produced from an aromatic monovinyl monomer and a vinyl cyanide monomer.

摘要翻译： 一种制备具有优异的耐冲击性和加工性的热塑性树脂的方法，其包括在水性弹性体胶乳的存在下使芳族单乙烯基单体和乙烯基氰单体聚合，将所得共聚物胶乳与芳族单乙烯基单体和乙烯基 氰化物单体在聚环氧烷和凝结剂的存在下反应，得到稳定的悬浮相，并使混合物和所制得的所述热塑性树脂聚合，以及包含所述热塑性树脂的组合物和由芳族单乙烯基单体和乙烯基 氰化物单体。

公开(公告)号：US3941912A

公开(公告)日：1976-03-02

申请号：US396923

申请日：1973-09-13

申请人： Shigeru Tajima ,  Takeshi Shimamura ,  Kojiro Matsumoto ,  Sadao Sekiguchi ,  Tanoshi Yamagoshi ,  Kazumasa Fjieda

发明人： Shigeru Tajima ,  Takeshi Shimamura ,  Kojiro Matsumoto ,  Sadao Sekiguchi ,  Tanoshi Yamagoshi ,  Kazumasa Fjieda

IPC分类号： C08F212/04 ,  C08F212/06 ,  C08F220/12 ,  C08F236/04 ,  C08F236/10 ,  C08K3/34 ,  D21H19/58 ,  C08L9/08 ,  C08L25/14 ,  C08L29/08 ,  C08L33/00

CPC分类号： D21H19/58 ,  C08F212/04 ,  C08F212/06 ,  C08F220/12 ,  C08F236/04 ,  C08F236/10 ,  C08K3/0033 ,  C08K3/346 ,  Y10T428/31906

摘要： A copolymer latex comprising 25 to 45 percent by weight of a conjugated diolefinic monomer, 3 to 40 percent by weight of an alkyl ester of unsaturated carboxylic acid, 1 to 5 percent by weight of a hydroxyalkyl-containing unsaturated monomer, 0.5 to 4 percent by weight of an unsaturated carboxylic acid monomer and the remaining percent of an alkenyl aromatic monomer, and a pigmented paper coating composition, which can give a coated paper having excellent properties, such as water resistance, "transferability of multicolor offset printing ink" and blister resistance in case of web offset printing.

摘要翻译： 包含25至45重量％的共轭二烯烃单体，3至40重量％的不饱和羧酸烷基酯，1至5重量％的含羟烷基的不饱和单体，0.5至4重量％ 不饱和羧酸单体的重量和链烯基芳族单体的剩余百分比，以及着色纸涂料组合物，其可以得到具有优异性能的涂布纸，例如耐水性，“多色胶印油墨的转印性”和起泡电阻 在卷筒纸胶版印刷的情况下。