公开(公告)号：US5428173A

公开(公告)日：1995-06-27

申请号：US129322

申请日：1993-09-30

Applicant: Takeo Kanai ,  Akio Imai ,  Katsuhiko Sato ,  Homare Shinohara ,  Kazumi Oishi

Inventor： Takeo Kanai ,  Akio Imai ,  Katsuhiko Sato ,  Homare Shinohara ,  Kazumi Oishi

IPC: C07D285/08

CPC classification number: C07D285/08 ,  Y02P20/55

Abstract: A process is provided for the preparation of an aminothiadiazolylacetyl halide derivative represented by the following formula (II): ##STR1## wherein R.sup.1 represents a lower alkyl, cycloalkyl or halogenated lower alkyl group; and R.sup.2 represents an amino-protecting group or a hydrogen atom, or a salt thereof, which process uses as the starting material a compound represented by the following formula (I): ##STR2## wherein R.sup.1 and R.sup.2 have the same meanings as defined above, or a salt thereof.

Abstract translation: 提供了制备由下式（II）表示的氨基噻二唑基乙酰卤衍生物的方法：其中R 1表示低级烷基，环烷基或卤代低级烷基; R2表示作为起始原料的下式（I）表示的化合物的氨基保护基或氢原子或其盐：其中R 1和R 2具有相同的含义 如上所定义，或其盐。

公开(公告)号：US5189108A

公开(公告)日：1993-02-23

申请号：US625924

申请日：1990-12-14

Applicant: Akio Imai ,  Mitsuji Tsuji ,  Takashi Sanada ,  Keisaku Yamamoto

Inventor： Akio Imai ,  Mitsuji Tsuji ,  Takashi Sanada ,  Keisaku Yamamoto

IPC: C08F255/04 ,  C08F255/06 ,  C08F279/02 ,  C08F291/00 ,  C08F291/02

CPC classification number: C08F255/04 ,  C08F255/06 ,  C08F279/02

Abstract: A modified polymer rubber is obtained by(1) graft-polymerizing at least one grafting monomer to a shreaded rubbery polymer (A) in an aqueous suspension at a temperature of 30.degree.-130.degree. C. to obtain a graft polymer, and(2) kneading the graft polymer with at least one polymerizable monomer in the presence of a free radical initiator at a temperature of 180.degree.-280.degree. C. This process does not cause gel formation and is advantageous in manufacturing cost.The modified polymer rubber thus obtained is excellent in processability and storage stability, and highly useful as a compatibilizer for various resins.

公开(公告)号：US5128416A

公开(公告)日：1992-07-07

申请号：US581163

申请日：1990-09-05

Applicant: Akio Imai ,  Tomoaki Seki ,  Keisaku Yamamoto

Inventor： Akio Imai ,  Tomoaki Seki ,  Keisaku Yamamoto

IPC: B60C1/00 ,  C08C19/42

CPC classification number: C08C19/42 ,  B60C1/0016

Abstract: A process for preparing modified diene polymer rubbers having an increased impact resilience, a reduced hardness at low temperatures and an improved processability, and useful as rubber materials for automobile tires and other industries which comprises producing a conjugated diene polymer having alkali metal end or ends, and reacting the alkali metal-containing polymer with (a) a silicon or tin compound of the formula: R.sub.a MX.sub.b wherein R is an alkyl group, an alkenyl group, a cycloalkenyl group or an aromatic hydrocarbon group, M is silicon atom or tin atom, X is a halogen atom, a is 0, 1 or 2 and b is 2, 3 or 4, and (b) at least one member selected from the group consisting of a nitro compound; a phosphoryl chloride compound of the formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are an alkyl group; an aminosilane compound of the formula (2): ##STR2## wherein R.sup.5, R.sup.6 and R.sup.7 are an alkyl group or an alkoxyl group, R.sup.8 and R.sup.9 are an alkyl group, and n is an integer; an acrylamide compound of the formula (3): ##STR3## wherein R.sup.10 is hydrogen atom or methyl group, R.sup.11 and R.sup.12 are an alkyl group, and m is an integer; and an aminovinylsilane compound of the formula (4): ##STR4## wherein R.sup.13, R.sup.14, R.sup.15, R.sup.16 and R.sup.17 are an alkyl group.

Abstract translation: 一种制备具有增加的冲击弹性，在低温下降低的硬度和改进加工性能的改性二烯聚合物橡胶的方法，并且可用作汽车轮胎和其它工业的橡胶材料，其包括制备具有碱金属末端或末端的共轭二烯聚合物， 使含碱金属的聚合物与（a）下式的硅或锡化合物反应：其中R是烷基，烯基，环烯基或芳族烃基，M是硅原子或锡原子， X是卤素原子，a是0,1或2，b是2,3或4，和（b）至少一种选自硝基化合物; 式（1）的磷酰氯化合物：其中R1，R2，R3和R4是烷基; （2）的氨基硅烷化合物：其中R5，R6和R7是烷基或烷氧基，R8和R9是烷基，n是整数; 式（3）的丙烯酰胺化合物：其中R 10是氢原子或甲基，R 11和R 12是烷基，m是整数; 和式（4）的氨基乙烯基硅烷化合物：其中R 13，R 14，R 15，R 16和R 17是烷基。

公开(公告)号：US4737535A

公开(公告)日：1988-04-12

申请号：US817949

申请日：1985-12-17

Applicant: Hiroshi Furukawa ,  Yuichi Saito ,  Akio Imai ,  Nobuyuki Yoshida

Inventor： Hiroshi Furukawa ,  Yuichi Saito ,  Akio Imai ,  Nobuyuki Yoshida

IPC: C08L7/00 ,  B60C1/00 ,  C08K3/04 ,  C08K5/04 ,  C08K5/10 ,  C08K5/11 ,  C08K13/02 ,  C08L9/06 ,  C08L21/00

CPC classification number: C08K5/10 ,  B60C1/0016 ,  C08L21/00

Abstract: A tire tread rubber composition which is improved in grip characteristic, steering stability characteristics and low-temperature characteristics, containing 15 to 50 parts by weight of a particular styrene-butadiene rubber obtained by solution polymerization containing polymer chains modified with trifunctional and/or tetrafunctional coupling agents, 50 to 85 parts by weight of at least one rubber selected from the group consisting of emulsion-polymerized styrene-butadiene rubber, natural rubber, synthetic polyisoprene rubber and butadiene rubber, at least one compound as plasticizer selected from the group consisting of a sebacic acid ester, an adipic acid ester and a fatty acid ester, and carbon black having an average particle size of not more than 30 m.mu..

Abstract translation: PCT No.PCT / JP85 / 00217 Sec。 371日期1985年12月17日第 102（e）日期1985年12月17日PCT申请1985年4月18日PCT公布。 公开号WO85 / 04888 日期：1985年11月7日。一种改进了抓地性能，操纵稳定特性和低温特性的胎面橡胶组合物，其含有15〜50重量份通过溶液聚合得到的特定苯乙烯 - 丁二烯橡胶， 使用三官能和/或四官能偶联剂，50至85重量份的选自乳液聚合的丁苯橡胶，天然橡胶，合成聚异戊二烯橡胶和丁二烯橡胶中的至少一种橡胶，至少一种化合物作为增塑剂 选自癸二酸酯，己二酸酯和脂肪酸酯，平均粒径不大于30μm的碳黑。

公开(公告)号：US4639494A

公开(公告)日：1987-01-27

申请号：US704856

申请日：1985-02-25

Applicant: Akio Imai ,  Yasushi Okamoto ,  Masatoshi Saito

Inventor： Akio Imai ,  Yasushi Okamoto ,  Masatoshi Saito

IPC: C08F279/00 ,  C08C19/32 ,  C08F2/02 ,  C08F4/08 ,  C08F4/48 ,  C08F279/02

CPC classification number: C08F279/02

Abstract: In a process for producing a high impact polystyrene comprising the radical polymerization of styrene in the presence of a butadiene rubber, the improvement which comprises, the butadiene rubber being a highly branched polymer prepared by homopolymerizing 1,3-butadiene or copolymerizing 1,3-butadiene and styrene in the presence of an organolithium compound and a Lewis base compound, followed by further reacting the resulting polymer with a multifunctional halogen compound; in the butadiene rubber, the average content of 1,2-bonds being 18 to 32 mole % based on the total bonded butadiene, the content of bonded styrene being up to 10% by weight, and the content of branched polymer chains being at least 60% by weight; the butadiene rubber exhibiting a Mooney viscosity of 40 to 90 at 100.degree. C. and a solution viscosity in styrene of 60 to 90 cps at 25.degree. C. and at a concentration of 5% by weight; and the styrene polymerization being carried out so that the content of the butadiene rubber in the product polystyrene lies between 3 and 20% by weight.

Abstract translation: 在丁二烯橡胶存在下，制造苯乙烯自由基聚合的高抗冲聚苯乙烯的制造方法，其改进在于丁二烯橡胶是通过均聚1,3-丁二烯或共聚1,3-丙二醇制备的高支化聚合物， 丁二烯和苯乙烯在有机锂化合物和路易斯碱化合物的存在下进一步使所得聚合物与多官能卤素化合物反应; 在丁二烯橡胶中，基于总键合丁二烯，1,2-键的平均含量为18〜32摩尔％，结合苯乙烯的含量高达10重量％，支链聚合物链的含量至少为 60重量％ 丁二烯橡胶在100℃下的门尼粘度为40〜90℃，苯乙烯溶液粘度在25℃下为60〜90cps，浓度为5重量％。 进行苯乙烯聚合，使得产品聚苯乙烯中的丁二烯橡胶的含量为3〜20重量％。

公开(公告)号：US4523618A

公开(公告)日：1985-06-18

申请号：US480348

申请日：1983-03-30

Applicant: Keisaku Yamamoto ,  Nobuyuki Yoshida ,  Yasushi Okamoto ,  Akio Imai ,  Tomoaki Seki ,  Hiroshi Furukawa ,  Yuichi Saito

Inventor： Keisaku Yamamoto ,  Nobuyuki Yoshida ,  Yasushi Okamoto ,  Akio Imai ,  Tomoaki Seki ,  Hiroshi Furukawa ,  Yuichi Saito

IPC: C08F4/00 ,  B60C1/00 ,  C08C19/44 ,  C08F4/42 ,  C08F236/00 ,  C08F236/10 ,  C08L9/00 ,  B60C11/00

CPC classification number: C08C19/44 ,  B60C1/0016 ,  C08L9/00 ,  Y10S152/905 ,  Y10T152/10495

Abstract: A branched polymer which is a butadiene homopolymer or a copolymer of an aromatic vinyl compound and butadiene and has a glass transition temperature of not less than -50.degree. C. and of which at least 70% by weight of the polymer chains has a branched structure in which high molecules are coupled by a trifunctional or tetrafunctional coupling agent, has an excellent roll processability as required in mixing a rubber component with additives and provides a rubber component for tire tread showing a low rolling resistance and an excellent wet skid resistance characteristic.

Abstract translation: 作为丁二烯均聚物或芳族乙烯基化合物与丁二烯的共聚物的分支聚合物，其玻璃化转变温度不低于-50℃，其中至少70重量％的聚合物链具有支链结构 其中高分子通过三官能或四官能偶联剂偶联，根据需要在橡胶组分与添加剂混合时具有优异的辊加工性，并提供了具有低滚动阻力和优异的抗湿滑性能的轮胎胎面用橡胶组分。

公开(公告)号：US4087484A

公开(公告)日：1978-05-02

申请号：US649729

申请日：1976-01-16

Applicant: Tamotsu Miki ,  Akio Imai ,  Yuji Kobayashi

Inventor： Tamotsu Miki ,  Akio Imai ,  Yuji Kobayashi

IPC: C08L53/02 ,  C08F297/04

CPC classification number: C08L53/02

Abstract: An aromatic vinyl compound and a conjugated diene are block-copolymerized in a hydrocarbon solvent using an organolithium compound as an initiator to form a hydrocarbon solution of a block copolymer resin which is then steam-stripped off the solvent in the presence of a specified block polyether type dispersing agent to yield a granular polymer. The block copolymer thus obtained has favorable properties as granules and can be fabricated into articles being highly transparent and having excellent mechanical properties.

Abstract translation: 芳族乙烯基化合物和共轭二烯在烃溶剂中使用有机锂化合物作为引发剂进行嵌段共聚，以形成嵌段共聚物树脂的烃溶液，然后在指定的嵌段聚醚存在下将其蒸去溶剂 型分散剂，得到粒状聚合物。 由此获得的嵌段共聚物作为颗粒具有有利的性质，并且可以制成高度透明且机械性能优异的制品。

公开(公告)号：US08127729B2

公开(公告)日：2012-03-06

申请号：US12781336

申请日：2010-05-17

Applicant: Hiroki Takahashi ,  Akio Imai

Inventor： Hiroki Takahashi ,  Akio Imai

IPC: F01L1/34

CPC classification number: F01L1/352 ,  F01L2001/3443

Abstract: A driven-side rotator is rotatable synchronously with a camshaft and is supported between a gear member and a sprocket member of the driving-side rotator in an axial direction. A stopper portion of the driven-side rotator is adapted to contact the driving-side rotator in a rotational direction to limit a change in a relative phase between the crankshaft and the camshaft. The stopper portion radially outwardly projects from a small diameter portion provided at one end part of the driven-side rotator. A large diameter portion is provided at the other end part of the driven-side rotator and has a radial size that is measured from a rotational axis to a radially outer peripheral surface of the large diameter portion and is equal to or larger than that of the stopper portion.

Abstract translation: 从动侧旋转体可与凸轮轴同步旋转，并且沿轴向支撑在驱动侧旋转体的齿轮构件和链轮构件之间。 从动侧旋转体的止动部适于在驱动侧旋转体的旋转方向上接触以限制曲轴与凸轮轴之间的相对相位的变化。 止动件部分从设置在从动侧转子的一个端部处的小直径部分径向向外突出。 在从动侧转子的另一端部设有大直径部，其径向尺寸从大直径部的旋转轴向径向外周面测定，并且等于或大于 止动部分。

公开(公告)号：US20090199801A1

公开(公告)日：2009-08-13

申请号：US12367694

申请日：2009-02-09

Applicant: Akio Imai ,  Yasushi Morii

Inventor： Akio Imai ,  Yasushi Morii

IPC: F01L1/34

CPC classification number: F01L1/352 ,  F01L1/022 ,  F01L1/024 ,  F01L2820/032

Abstract: A valve timing adjusting apparatus includes a driving-side rotor, a driven-side rotor, a sun gear, and a planet gear. The driving-side rotor is rotatable synchronously with the crankshaft. The driven-side rotor is received in the driving-side rotor and rotatable synchronously with a camshaft. The sun gear is rotatable integrally with the driving-side rotor. The planet gear moves epicyclically relative to the sun gear. The driving-side rotor includes a peripheral wall member and a bottom wall member. One of the sun gear and the bottom wall member is fitted with an inner peripheral side of one axial end portion of the peripheral wall member. The other one is fitted with an outer peripheral side of the other axial end portion of the peripheral wall member.

Abstract translation: 气门正时调节装置包括驱动侧转子，从动侧转子，太阳齿轮和行星齿轮。 驱动侧转子可与曲轴同步旋转。 从动侧转子被容纳在驱动侧转子中并与凸轮轴同步旋转。 太阳齿轮与驱动侧转子一体旋转。 行星齿轮相对于太阳齿轮行星运动。 驱动侧转子包括周壁部件和底壁部件。 太阳齿轮和底壁构件中的一个装配有周壁构件的一个轴向端部的内周侧。 另一个装配有周壁构件的另一轴向端部的外周侧。

公开(公告)号：US20080234485A1

公开(公告)日：2008-09-25

申请号：US11995975

申请日：2007-02-01

Applicant: Kazuhide Ashizawa ,  Takashi Hasebe ,  Akio Imai

Inventor： Kazuhide Ashizawa ,  Takashi Hasebe ,  Akio Imai

IPC: C07D211/10

CPC classification number: C07D211/32

Abstract: 1-Benzyl-4-[(5,6-dimethoxy-1-indanon)-2-yl]methylpiperidine hydrobromide or a solvate thereof.

Abstract translation: 1-苄基-4 - [（5,6-二甲氧基-1-茚满酮）-2-基]甲基哌啶氢溴酸盐或其溶剂合物。