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31.发明授权Thermoplastic fluoropolymer containing elastomer and production process therefor 失效含有弹性体的热塑性含氟聚合物及其制备方法
公开(公告)号：US6124403A
公开(公告)日：2000-09-26
申请号：US138511
申请日：1998-08-24
IPC: C08L51/04 , C08F2/44 , C08F255/02 , C08F259/00 , C08F259/02 , C08F259/08 , C08F291/02 , C08J7/16 , C08L51/00 , C08L51/06 , C09J151/00 , C09J151/06 , C08F253/00
CPC classification number: C08J7/16 , C08F255/02 , C08F259/00 , C08F259/02 , C08F259/08 , C08L51/003 , C08L51/06 , C09J151/003 , C09J151/06 , C08J2321/00 , Y10S525/903
Abstract: Polymer compositions containing a mixture of an elastomer and a fluoropolymer can be made by diffusing fluorinated olefins and free radical initiators in preferably swollen elastomers and polymerizing the fluorinated olefins. The resulting compositions have useful properties, such as reduced sliding friction, which makes them useful for seals in contact with moving surfaces, and for other uses.
Abstract translation: 包含弹性体和含氟聚合物的混合物的聚合物组合物可以通过将氟化烯烃和自由基引发剂在优选的溶胀弹性体中扩散和聚合氟化烯烃来制备。 所得组合物具有有用的性质，例如降低的滑动摩擦，这使得它们可用于与移动表面接触的密封件以及用于其它用途。
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公开(公告)号：US5639837A
公开(公告)日：1997-06-17
申请号：US658676
申请日：1996-06-04
Applicant: William Brown Farnham , Andrew Edward Feiring , Bruce Edmund Smart , Robert Clayton Wheland
Inventor： William Brown Farnham , Andrew Edward Feiring , Bruce Edmund Smart , Robert Clayton Wheland
CPC classification number: C08F14/18
Abstract: Disclosed herein is a process in which fluorine containing olefins are polymerized using an initiation system which is a combination of a fluoroaliphatic sulfinate or sulfinic acid and chlorate, bromate or hypochlorite ions. The resulting polymer contains fewer deleterious end groups and is more stable and/or easier to process. The polymers produced are useful as thermoplastics and elastomers.
Abstract translation: 本文公开的是使用作为氟代脂族亚磺酸盐或亚磺酸与氯酸盐，溴酸盐或次氯酸盐离子的组合的引发体系聚合含氟烯烃的方法。 所得聚合物含有较少有害的末端基团并且更稳定和/或更容易加工。 所生产的聚合物可用作热塑性塑料和弹性体。
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33.发明授权Photocrosslinkable fluoropolymers, UV processes and photocrosslinked polymers 有权可光交联的含氟聚合物，UV工艺和光交联聚合物公开(公告)号：US09169338B2
公开(公告)日：2015-10-27
申请号：US13809926
申请日：2011-07-13
Applicant: Robert Clayton Wheland , Roger Harquail French
Inventor： Robert Clayton Wheland , Roger Harquail French
IPC: C08F214/18 , C08F214/26 , C08F14/18
CPC classification number: C08F14/185 , C08F214/18 , C08F214/186 , C08F214/188 , C08F214/26 , C08F214/262
Abstract: This invention relates to certain photocrosslinkable fluoropolymers, processes for crosslinking the fluoropolymers using UV radiation, and the photocrosslinked fluoropolymers produced.
Abstract translation: 本发明涉及某些可光交联的含氟聚合物，使用紫外线辐射交联含氟聚合物的方法和所生产的光交联的含氟聚合物。
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34.发明授权Processes for preparing low molecular weight hexafluoropropylene-olefin cotelomers 有权制备低分子量六氟丙烯 - 烯烃共聚物的方法公开(公告)号：US08895681B2
公开(公告)日：2014-11-25
申请号：US11614554
申请日：2006-12-21
Applicant: Jon Lee Howell , Clay Woodward Jones , Robert Clayton Wheland
Inventor： Jon Lee Howell , Clay Woodward Jones , Robert Clayton Wheland
IPC: C08F214/28
CPC classification number: C08F214/28 , C08F2/38
Abstract: Amorphous hydrofluoroolefin telomers are prepared by a free-radical polymerization process conducted at high temperature and pressure in the presence of non-monomeric chain transfer agent.
Abstract translation: 无定形氢氟烯烃调聚物通过在非单体链转移剂存在下在高温和高压下进行的自由基聚合方法制备。
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公开(公告)号：US08765876B2
公开(公告)日：2014-07-01
申请号：US13420719
申请日：2012-03-15
Applicant: Christopher J Bish , Peter A Morken , Robert Clayton Wheland
Inventor： Christopher J Bish , Peter A Morken , Robert Clayton Wheland
CPC classification number: C08F224/00 , C08F220/42 , C08G65/007 , C08L27/12 , C08L71/00
Abstract: Fluoroelastomer compositions comprising fluoroelastomers having copolymerized units of a nitrile-containing cure site monomer are cured with certain hydrazide curatives. The hydrazide is of the general formula R1(C(O))nNHNHR2, wherein n is 1 or 2; R1 is NH2, NHNH2, NHR3, NR32, NHNHC(O)NH2, NHNHC(O)NHNH2, NHNHR2, or NHC(O)NHNH2; R2 is H, alkyl, aryl, heterocycle, CO2R3, C(O)R3, CH2R4, or C(O)R4; R3 is alkyl, aryl, heterocycle, or CH2R4; and R4 is a fluoroalkyl group.
Abstract translation: 包含具有含腈固化部位单体的共聚单元的含氟弹性体的含氟弹性体组合物用某些酰肼固化剂固化。 酰肼为通式R 1（C（O））nNHNHR 2，其中n为1或2; R1是NH2，NHNH2，NHR3，NR32，NHNHC（O）NH2，NHNHC（O）NHNH2，NHNHR2或NHC（O）NHNH2; R 2是H，烷基，芳基，杂环，CO 2 R 3，C（O）R 3，CH 2 R 4或C（O） R3是烷基，芳基，杂环或CH2R4; R4为氟代烷基。
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Patent Agency Ranking
公开(公告)号：US20130245219A1
公开(公告)日：2013-09-19
申请号：US13989149
申请日：2011-12-20
Applicant: Randal L. Perry , Mark Gerrit Roelofs , Robert Clayton Wheland , Ralph Munson Aten
Inventor： Randal L. Perry , Mark Gerrit Roelofs , Robert Clayton Wheland , Ralph Munson Aten
IPC: C08F14/18
CPC classification number: C08F14/18 , C08F214/18 , C08F214/182 , C08F216/1408 , C08F216/1466 , C08J5/2237 , C08J2327/18 , C08L23/0876 , H01G11/58 , H01M8/1004 , H01M8/1025 , H01M8/1039 , H01M8/1044
Abstract: This invention relates to ionomers and to ionically conductive compositions formed therefrom. The ionomers comprise polymerized units of monomers A and monomers B, wherein monomers A are perfluoro dioxole or perfluoro dioxolane monomers, and the monomers B are functionalized perfluoro olefins having fluoroalkyl sulfonyl, fluoroalkyl sulfonate or fluoroalkyl sulfonic acid pendant groups, CF2═CF(O)[CF2]nSO2X. The ionically conductive compositions of the invention are useful in fuel cells, electrolysis cells, ion exchange membranes, sensors, electrochemical capacitors, and modified electrodes.
Abstract translation: 本发明涉及离聚物和由其形成的离子导电组合物。 离聚物包括单体A和单体B的聚合单元，其中单体A是全氟二氧杂环戊烯或全氟二氧戊环单体，单体B是具有氟代烷基磺酰基，氟烷基磺酸酯或氟烷基磺酸侧基的全氟烯烃官能化的CF 2 = CF（O） [CF2] nSO2X。 本发明的离子导电组合物可用于燃料电池，电解槽，离子交换膜，传感器，电化学电容器和改性电极。
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37.发明申请PHOTOCROSSLINKABLE FLUOROPOLYMERS, UV PROCESSES AND PHOTOCROSSLINKED POLYMERS 有权光致变色荧光体，UV工艺和光致交联聚合物公开(公告)号：US20130131213A1
公开(公告)日：2013-05-23
申请号：US13809926
申请日：2011-07-13
Applicant: Robert Clayton Wheland , Roger Harquail French
Inventor： Robert Clayton Wheland , Roger Harquail French
IPC: C08F14/18
CPC classification number: C08F14/185 , C08F214/18 , C08F214/186 , C08F214/188 , C08F214/26 , C08F214/262
Abstract: This invention relates to certain photocrosslinkable fluoropolymers, processes for crosslinking the fluoropolymers using UV radiation, and the photocrosslinked fluoropolymers produced.
Abstract translation: 本发明涉及某些可光交联的含氟聚合物，使用紫外线辐射交联含氟聚合物的方法和所生产的光交联的含氟聚合物。
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公开(公告)号：US08372486B2
公开(公告)日：2013-02-12
申请号：US11958171
申请日：2007-12-17
Applicant: Gregory A. Bell , Jon Lee Howell , Clay Woodward Jones , Robert Clayton Wheland
Inventor： Gregory A. Bell , Jon Lee Howell , Clay Woodward Jones , Robert Clayton Wheland
CPC classification number: C10M105/52 , C10M105/54 , C10M107/38 , C10M2201/0416 , C10M2201/0666 , C10M2201/1056 , C10M2211/0225 , C10M2211/0425 , C10M2213/023 , C10M2213/043 , C10M2213/0626 , C10N2230/08 , C10N2230/12 , C10N2240/02 , C10N2270/00 , Y10T428/3154 , Y10T428/31544 , Y10T428/8305
Abstract: Liquid hydrofluorocarbons provide low corrosivity lubrication of metallic surfaces especially at elevated temperatures.
Abstract translation: 液态氢氟碳化合物对金属表面的腐蚀性较低，特别是在高温下。
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公开(公告)号：US08343630B2
公开(公告)日：2013-01-01
申请号：US13309778
申请日：2011-12-02
Applicant: Che-Hsiung Hsu , Hjalti Skulason , Daniel David Lecloux , Eric Maurice Smith , Shawn Yeisley , Robert Clayton Wheland
Inventor： Che-Hsiung Hsu , Hjalti Skulason , Daniel David Lecloux , Eric Maurice Smith , Shawn Yeisley , Robert Clayton Wheland
CPC classification number: H01B1/08 , H01B1/124 , H01B1/125 , Y10T428/12569 , Y10T428/265 , Y10T428/3154 , Y10T428/31544 , Y10T428/31678 , Y10T428/31721
Abstract: There is provided a transparent composite conductor. The composite conductor has a first layer that includes a transparent conductive material and a second layer that includes a fluorinated acid polymer.
Abstract translation: 提供透明复合导体。 复合导体具有包括透明导电材料的第一层和包含氟化酸聚合物的第二层。
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40.发明申请Fluorosulfates of Hexafluoroisobutylene and Its Higher Homologs and Their Derivatives 审中-公开六氟异丁烯的氟代硫酸盐及其高同系物及其衍生物公开(公告)号：US20090203865A1
公开(公告)日：2009-08-13
申请号：US12428041
申请日：2009-04-22
Applicant: RICHARD E. FERNANDEZ , WEIMING QIU , PAUL R. RESNICK , ROBERT CLAYTON WHELAND
Inventor： RICHARD E. FERNANDEZ , WEIMING QIU , PAUL R. RESNICK , ROBERT CLAYTON WHELAND
IPC: C08F16/24 , C08F214/18
CPC classification number: C07C303/22 , C07C17/093 , C07C21/18 , C07C43/17 , C07C253/16 , C07C255/10 , C07C305/26 , C08F14/28 , C08F214/18 , C07C309/82
Abstract: Hexafluoroisobutylene and its higher homologs are easily reacted with SO3 to give fluorosulfates of the formula CH2═C(R)CF2OSO2F, wherein R is a linear, branched or cyclic fluoroalkyl group comprised of 1 to 10 carbon atoms and may contain ether oxygen. These compounds react under mild conditions with many nucleophiles to give CH2═C(R)CF2X, where X is derived from the nucleophile. This reaction provides a route to many substituted hexafluoroisobutylenes, which copolymerize easily with other fluoro- and hydrocarbon monomers such as vinylidene fluoride and ethylene.
Abstract translation: 六氟异丁烯及其较高的同系物容易与SO 3反应，得到式CH 2 -C（R）CF 2 OSO 2 F的氟代硫酸盐，其中R是由1-10个碳原子组成的直链，支链或环状的氟代烷基，并且可以含有醚氧。 这些化合物在温和条件下与许多亲核试剂反应得到CH2-C（R）CF2X，其中X衍生自亲核试剂。 该反应提供了许多取代的六氟异丁烯的路线，其容易与其它氟代和烃单体如偏二氟乙烯和乙烯共聚。
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