公开(公告)号：US10737973B2

公开(公告)日：2020-08-11

申请号：US15153295

申请日：2016-05-12

Applicant: CORNING INCORPORATED

Inventor： John Frederick Bayne ,  Dana Craig Bookbinder ,  Theresa Chang ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Kyle Christopher Hoff ,  Jamie Lynne Morley ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Christopher Lee Timmons

IPC: A61J1/14 ,  C03C17/30 ,  B65D1/09 ,  B65D23/08 ,  A61J1/00 ,  B65D65/42 ,  B65D25/14 ,  C03C17/00 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08 ,  C09D183/08 ,  C08L77/02 ,  C08G73/10 ,  C08G77/26 ,  C09D4/00

Abstract: Embodiments of the present disclosure are directed to coated glass articles which reduce glass particle formation caused by glass to glass contact in pharmaceutical glass filling lines.

公开(公告)号：US20190210768A1

公开(公告)日：2019-07-11

申请号：US16355797

申请日：2019-03-17

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Andrei Gennadyevich Fadeev ,  James Patrick Hamilton ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Robert Anthony Schaut ,  Susan Lee Schiefelbein ,  Christopher Lee Timmons

IPC: B65D23/08 ,  B65D1/40 ,  A61J1/14 ,  C03C3/087 ,  B65D25/14 ,  B32B17/06 ,  C03C17/34 ,  C03C17/00 ,  C03C17/32 ,  C03C17/30 ,  C08G73/10 ,  C09D179/08 ,  C03C21/00 ,  C03C17/42

CPC classification number: B65D23/0814 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/40 ,  B65D25/14 ,  C03C3/087 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C08G73/105 ,  C08G73/1071 ,  C09D179/08 ,  C08K5/544

Abstract: Disclosed herein are delamination resistant glass pharmaceutical containers which may include a glass body having a Class HGA1 hydrolytic resistance when tested according to the ISO 720:1985 testing standard. The glass body may have an interior surface and an exterior surface. The interior surface of the glass body does not comprise a boron-rich layer when the glass body is in an as-formed condition. A heat-tolerant coating may be bonded to at least a portion of the exterior surface of the glass body. The heat-tolerant coating may have a coefficient of friction of less than about 0.7 and is thermally stable at a temperature of at least 250° C. for 30 minutes.

公开(公告)号：US10034816B2

公开(公告)日：2018-07-31

申请号：US15374338

申请日：2016-12-09

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/14 ,  C03C17/00 ,  C03C17/42 ,  C03C17/30 ,  C03C17/32 ,  C03C21/00 ,  B65D25/34 ,  B65D65/42 ,  B65D23/08 ,  C09D179/08

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: A pharmaceutical package may include a glass body enclosing an inner volume and having an exterior surface. The glass body may be formed from a borosilicate glass that meets the Type 1 criteria according to USP or an alkali aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to the ISO 720-1985 testing standard. A coupling agent layer having a first thickness less than or equal to 100 nm may be disposed on the exterior surface of the glass body. A polymer layer having a second thickness of less than 50 nm may be positioned over the coupling agent layer. The exterior surface of the glass body with the coupling agent layer and the polymer layer may have a coefficient of friction less than or equal to 0.7.

公开(公告)号：US20180067091A1

公开(公告)日：2018-03-08

申请号：US15693693

申请日：2017-09-01

Applicant: CORNING INCORPORATED

Inventor： Robert Scott Burkhalter ,  Andrei Gennadyevich Fadeev ,  John Stephen Peanasky ,  David Charles Sauer

IPC: G01N33/00

Abstract: A method for measuring volatile organic compounds includes loading glass containers into an oven, heating the oven, purging the oven with dry clean air, collecting a volumetric portion of an oven exhaust, trapping volatile organic compounds from the volumetric portion, and measuring the volatile organic compounds trapped in the trap. The one or more glass containers are in-tact while measuring the VOCs of the coated glass container. An apparatus includes an oven having an interior volume that is capable of holding one or more in-tact glass containers, a flow meter fluidly connected to the first trap, and a pump fluidly connected to the flow meter. The first trap collects volatile organic compounds from a volumetric portion of the oven exhaust gas. The pump controls a flow rate of the volumetric portion of the oven exhaust gas across the first trap.

公开(公告)号：US20170334604A1

公开(公告)日：2017-11-23

申请号：US15656721

申请日：2017-07-21

Applicant: CORNING INCORPORATED

Inventor： Kaveh Adib ,  Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Melinda Ann Drake ,  Andrei Gennadyevich Fadeev ,  James Patrick Hamilton ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Chandan Kumar Saha ,  Robert Anthony Schaut ,  Susan Lee Schiefelbein ,  Christopher Lee Timmons

IPC: B65D23/08 ,  B32B17/06 ,  C08G73/10 ,  B65D1/40 ,  C03C21/00 ,  B65D25/14 ,  C03C17/34 ,  C03C17/32 ,  C03C17/30 ,  C03C17/00 ,  C03C3/087 ,  C09D179/08 ,  C03C17/42

Abstract: Disclosed herein are delamination resistant glass pharmaceutical containers which may include an aluminosilicate glass having a Class HGA 1 hydrolytic resistance when tested according to ISO 720-1985 testing standard. The glass containers may also have a compressive stress layer with a depth of layer of greater than 25 μm. A surface compressive stress of the glass containers may be greater than or equal to 350 MPa. The delamination resistant glass pharmaceutical containers may be ion exchange strengthened and the ion exchange strengthening may include treating the delamination resistant glass pharmaceutical container in a molten salt bath for a time less than or equal to 5 hours at a temperature less than or equal to 450° C.

公开(公告)号：US20170320773A1

公开(公告)日：2017-11-09

申请号：US15656634

申请日：2017-07-21

Applicant: CORNING INCORPORATED

Inventor： Dana Craig Bookbinder ,  Theresa Chang ,  Paul Stephen Danielson ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  Robert Michael Morena ,  Santona Pal ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Christopher Lee Timmons ,  Natesan Venkataraman ,  Ronald Luce Verkleeren

IPC: C03C17/42 ,  B65D1/02 ,  C09D179/08 ,  A61J1/14 ,  B32B17/06 ,  C03C17/32 ,  C03C17/30 ,  C03C17/00 ,  C03C15/02 ,  B65D65/42 ,  B65D25/34 ,  B65D25/14 ,  B65D23/08 ,  B65D23/02 ,  B65D1/40 ,  C03C21/00 ,  C03C17/34

CPC classification number: C03C17/42 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/0207 ,  B65D1/0215 ,  B65D1/40 ,  B65D23/02 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C15/02 ,  C03C17/00 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/13 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/315

Abstract: In embodiments, a delamination resistant glass pharmaceutical package includes a glass body formed from a Type 1 Class glass composition according to ASTM Standard E438-92, the glass body having a wall portion with an inner surface and an outer surface. The glass body may have at least a class A2 base resistance or better according to ISO 695, at least a type HGB2 hydrolytic resistance or better according to ISO 719 and Type 1 chemical durability according to USP . An interior region of the glass body may extend from about 10 nm below the inner surface and having a persistent layer homogeneity. The glass body may also have a surface region extending over the inner surface and having a persistent surface homogeneity such that the glass body is resistant to delamination.

公开(公告)号：US09775775B2

公开(公告)日：2017-10-03

申请号：US14812902

申请日：2015-07-29

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: A61J1/00 ,  B65D65/42 ,  B65D23/08 ,  B65D25/14 ,  C03C17/30 ,  C03C17/32 ,  C09D179/08 ,  C03C17/00 ,  C03C17/42 ,  C03C21/00 ,  A61J1/14

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Coated pharmaceutical packages are disclosed. In embodiments, a coated pharmaceutical package includes a glass body comprising a first surface. A low-friction coating may be positioned on at least a portion of the first surface of the glass body. The low-friction coating may include a polymer chemical composition. A light transmission through the coated pharmaceutical package may be greater than or equal to about 55% of a light transmission through an uncoated pharmaceutical package for wavelengths from about 400 nm to about 700 nm. The low-friction coating may have a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute.

公开(公告)号：US20170036950A1

公开(公告)日：2017-02-09

申请号：US15331113

申请日：2016-10-21

Applicant: Corning Incorporated

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: C03C17/42 ,  C03C17/30 ,  B65D65/42 ,  C03C21/00 ,  A61J1/14 ,  C03C17/00 ,  C03C17/32

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: A coated glass pharmaceutical package may include a body formed from a Type 1 Class glass according to ASTM Standard E438-92. The body may have an interior surface and an exterior surface. The body may also have at least a class A2 base resistance or better according to ISO 695, at least a type HGB2 hydrolytic resistance or better according to ISO 719 and a Type 1 chemical durability according to USP . A coating having a thickness of ≦100 microns may be positioned on at least a portion of the exterior surface. The portion of the exterior surface with the coating may have a coefficient of friction that is at least 20% less than an uncoated glass pharmaceutical package and the coefficient of friction does not increase by more than 30% after undergoing a depyrogenation.

Abstract translation: 涂覆玻璃药物包装可以包括由根据ASTM标准E438-92的1型玻璃制成的主体。 身体可以具有内表面和外表面。 根据ISO 695，本体还可以具有至少A2级耐碱性或更好，根据ISO 719至少一种HGB2型耐水解性或更好，以及根据USP <660>的1型化学耐久性。 厚度≤100微米的涂层可以位于外表面的至少一部分上。 具有涂层的外表面的部分可以具有比未涂覆的玻璃药物包装小至少20％的摩擦系数，并且在进行去热原后摩擦系数不会增加超过30％。

公开(公告)号：US09034442B2

公开(公告)日：2015-05-19

申请号：US14052048

申请日：2013-10-11

Applicant: Corning Incorporated

Inventor： Theresa Chang ,  Steven Edward DeMartino ,  Andrei Gennadyevich Fadeev ,  John Stephen Peanasky ,  Robert Anthony Schaut ,  Christopher Lee Timmons

IPC: C08L83/00 ,  C03C15/02 ,  B65D25/14 ,  B65D23/08 ,  C03C17/00 ,  B65D1/02 ,  B65D25/34 ,  B32B17/06 ,  B65D1/40 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/00 ,  C09D179/08 ,  B65D23/02

CPC classification number: C03C17/42 ,  A61J1/1468 ,  B32B17/06 ,  B65D1/0207 ,  B65D1/0215 ,  B65D1/40 ,  B65D23/02 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C15/02 ,  C03C17/00 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/3405 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/13 ,  Y10T428/131 ,  Y10T428/1317 ,  Y10T428/315

Abstract: According to one embodiment, a glass container may include a body formed from a Type I, Class B glass composition according to ASTM Standard E438-92. The body may have an inner surface, an outer surface and a wall thickness extending between the outer surface and the inner surface. The body may also include a compressively stressed layer extending into the wall thickness from at least one of the outer surface and the inner surface. A lubricous coating may be positioned on at least a portion of the outer surface of the body, wherein the outer surface of the body with the lubricous coating has a coefficient of friction less than or equal to 0.7.

Abstract translation: 根据一个实施例，玻璃容器可以包括由根据ASTM标准E438-92的I型B类玻璃组合物形成的主体。 主体可以具有在外表面和内表面之间延伸的内表面，外表面和壁厚。 主体还可以包括从外表面和内表面中的至少一个延伸到壁厚中的压应力层。 润滑涂层可以位于主体的外表面的至少一部分上，其中具有润滑涂层的主体的外表面具有小于或等于0.7的摩擦系数。

公开(公告)号：US20130224407A1

公开(公告)日：2013-08-29

申请号：US13780754

申请日：2013-02-28

Applicant: CORNING INCORPORATED

Inventor： Andrei Gennadyevich Fadeev ,  Theresa Chang ,  Dana Craig Bookbinder ,  Santona Pal ,  Chandan Kumar Saha ,  Steven Edward DeMartino ,  Christopher Lee Timmons ,  John Stephen Peanasky

IPC: C09D179/08 ,  C03C17/30 ,  C03C17/32 ,  B65D25/14

CPC classification number: A61J1/1468 ,  A61J1/00 ,  B65D23/0814 ,  B65D23/0821 ,  B65D25/14 ,  B65D25/34 ,  B65D65/42 ,  C03C17/005 ,  C03C17/30 ,  C03C17/32 ,  C03C17/42 ,  C03C21/002 ,  C03C2217/78 ,  C03C2218/111 ,  C09D179/08 ,  Y10T428/1321 ,  Y10T428/24942

Abstract: Low-friction coatings and glass articles with low-friction coatings are disclosed. According to one embodiment, a coated glass article may include a glass body comprising a first surface and a low-friction coating positioned on at least a portion of the first surface of the glass body. The low-friction coating may include a polymer chemical composition. The coated glass article may be thermally stable at a temperature of at least about 260° C. for 30 minutes. A light transmission through the coated glass article may be greater than or equal to about 55% of a light transmission through an uncoated glass article for wavelengths from about 400 nm to about 700 nm. The low-friction coating may have a mass loss of less than about 5% of its mass when heated from a temperature of 150° C. to 350° C. at a ramp rate of about 10° C./minute.

Abstract translation: 公开了低摩擦涂层和具有低摩擦涂层的玻璃制品。 根据一个实施例，涂覆的玻璃制品可以包括玻璃体，其包括位于玻璃体的第一表面的至少一部分上的第一表面和低摩擦涂层。 低摩擦涂层可以包括聚合物化学组成。 涂覆的玻璃制品可以在至少约260℃的温度下热稳定30分钟。 通过涂覆的玻璃制品的透光率可以大于或等于用于波长为约400nm至约700nm的未涂覆的玻璃制品的透光率的约55％。 当以约10℃/分钟的升温速度从150℃升温至350℃时，低摩擦涂层的质量损失小于其质量的约5％。