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    Liquid isoprene-butadiene rubber
    33.
    发明授权
    Liquid isoprene-butadiene rubber 有权
    液体异戊二烯 - 丁二烯橡胶

    公开(公告)号：US06204320B1

    公开(公告)日：2001-03-20

    申请号：US09249470

    申请日：1999-02-12

    申请人： Edward John Blok ,  Mark Leslie Kralevich, Jr. ,  Paul Harry Sandstrom ,  Wen-Liang Hsu ,  Adel Farhan Halasa

    发明人： Edward John Blok ,  Mark Leslie Kralevich, Jr. ,  Paul Harry Sandstrom ,  Wen-Liang Hsu ,  Adel Farhan Halasa

    IPC分类号： C08J2700

    CPC分类号： C08F236/08 ,  B60C1/0016 ,  C08F236/06 ,  C08L21/00 ,  Y10T152/10495 ,  C08L2666/08

    摘要： The subject invention discloses a liquid isoprene-butadiene rubber (IBR) which is particularly valuable for use in making treads for high performance automobile tires, including race tires, that exhibit superior dry traction characteristics and durability. The isoprene-butadiene rubber of this invention is a liquid at room temperature and is comprised of repeat units which are derived from about 5 weight percent to about 95 weight percent isoprene and from about 5 weight percent to about 95 weight percent 1,3-butadiene, wherein the repeat units derived from isoprene and 1,3-butadiene are in essentially random order. The IBR of this invention also has a low number average molecular weight which is within the range of about 3,000 to about 50,000 and has a glass transition temperature which is within the range of about −50° C. to about 20° C. This invention more specifically discloses a tire tread compound which is comprised of (a) a rubbery elastomer, (b) about 20 phr to about 80 phr of an aromatic process oil, (c) about 35 phr to about 130 phr of a filler and (d) about 4 phr to about 40 phr of a liquid isoprene-butadiene rubber having a number average molecular weight which is within the range of about 3,000 to about 50,000 and a glass transition temperature which is within the range of about −50° C. to about 20° C.

    摘要翻译： 本发明公开了一种特别有价值的液体异戊二烯 - 丁二烯橡胶（IBR），其用于制造具有优异的干牵引特性和耐久性的高性能汽车轮胎（包括赛车轮胎）的胎面。 本发明的异戊二烯 - 丁二烯橡胶在室温下为液体，并由衍生自约5重量％至约95重量％的异戊二烯和约5重量％至约95重量％的1,3-丁二烯的重复单元 ，其中衍生自异戊二烯和1,3-丁二烯的重复单元基本上是随机的。 本发明的IBR还具有低于约3,000至约50,000的数均分子量，玻璃化转变温度在约-50℃至约20℃的范围内。本发明 更具体地公开了一种轮胎胎面胶，其由（a）橡胶弹性体，（b）约20phr至约80phr的芳族加工油，（c）约35phr至约130phr的填料和（d ）约4phr至约40phr的数均分子量在约3,000至约50,000范围内且玻璃化转变温度在约-50℃至约-50℃范围内的液体异戊二烯 - 丁二烯橡胶 约20℃

    STABILIZED DYNAMICALLY VULCANIZED THERMOPLASTIC ELASTOMER COMPOSITIONS USEFUL IN FLUID BARRIER APPLICATIONS
    39.
    发明申请
    STABILIZED DYNAMICALLY VULCANIZED THERMOPLASTIC ELASTOMER COMPOSITIONS USEFUL IN FLUID BARRIER APPLICATIONS 有权
    稳定的动态弹性体弹性体弹性体组合物在流体阻隔器中的应用

    公开(公告)号：US20120041108A1

    公开(公告)日：2012-02-16

    申请号：US13140080

    申请日：2008-12-17

    申请人： Edward John Blok ,  Bruce Alan Harrington ,  Yuichi Hara ,  Shusaku Tomoi

    发明人： Edward John Blok ,  Bruce Alan Harrington ,  Yuichi Hara ,  Shusaku Tomoi

    IPC分类号： C08K5/3475 ,  C08K5/13 ,  C08K5/134 ,  C08K5/3492 ,  C08K5/07

    CPC分类号： C08L77/00 ,  C08K5/005 ,  C08L9/02 ,  C08L15/00 ,  C08L23/283 ,  C08L51/00 ,  C08L51/04 ,  C08L51/06 ,  C08L51/08 ,  C08L53/02 ,  C08L55/02 ,  C08L2666/02 ,  C08L2666/24 ,  C08L2666/14 ,  C08L2666/04 ,  C08L2666/06

    摘要： A stabilized, dynamically vulcanized thermoplastic elastomer composition comprising dispersed dynamically vulcanized particles of at least one first elastomer or rubber comprising halogenated isobutylene-containing elastomer and dispersed particles of at least one second elastomer or rubber comprising at least one functional group capable of reacting with and grafting to a polyamide, the particles of the at least one first and at least one second elastomers dispersed in a continuous thermoplastic polyamide or nylon resin matrix comprising at least one nylon homopolymer, nylon copolymer or mixture thereof, the composition or the at least one first elastomer further comprising at least one stabilizer against degradation induced by exposure to actinic, particularly ultraviolet, radiation. The compositions are preferably produced in a mixing extruder and are suitable for producing durable, flexible, thermoplastic elastomer fluid barrier films or layers useful in industrial articles such as vehicle tire innerliners and hoses.

    摘要翻译： 一种稳定的，动态硫化的热塑性弹性体组合物，其包含至少一种包含含卤代异丁烯的弹性体的至少一种第一弹性体或橡胶的分散的动态硫化颗粒和至少一种第二弹性体或橡胶的分散颗粒，所述第二弹性体或橡胶包含至少一个能与载体 至少一种第一和至少一种第二弹性体的颗粒分散在包含至少一种尼龙均聚物，尼龙共聚物或其混合物的连续热塑性聚酰胺或尼龙树脂基质中，所述组合物或至少一种第一弹性体 进一步包含至少一种稳定剂，其防止通过暴露于光化特别是紫外线辐射而引起的降解。 组合物优选在混合挤出机中制备，并且适用于生产用于工业制品例如车辆轮胎内衬和软管的耐用的，柔性的，热塑性的弹性体流体屏障膜或层。

    Translucent propylene-based elastomeric compositions
    40.
    发明授权
    Translucent propylene-based elastomeric compositions 有权
    半透明丙烯基弹性体组合物

    公开(公告)号：US07994253B2

    公开(公告)日：2011-08-09

    申请号：US12103346

    申请日：2008-04-15

    申请人： Sunny Jacob ,  Gary K. Lawrence ,  Edward John Blok ,  Ralph E. Raulie

    发明人： Sunny Jacob ,  Gary K. Lawrence ,  Edward John Blok ,  Ralph E. Raulie

    IPC分类号： C08K5/00 ,  B32B27/32

    CPC分类号： C08L23/10 ,  B29C47/0004 ,  B29C47/0021 ,  B29C47/0023 ,  B29C49/0005 ,  B29C51/002 ,  B29K2023/12 ,  C08L23/16 ,  C08L2666/06

    摘要： A composition is described in one aspect as comprising one or more propylene-α-olefin terpolymers; wherein the propylene-α-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other α-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.

    摘要翻译： 组合物在一个方面描述为包含一种或多种丙烯-α-烯烃三元共聚物; 其中所述丙烯-α-烯烃三元共聚物的熔融温度（Tm）在小于105℃的范围内，熔融热（Hf）在小于75J / g的范围内; 一种或多种聚烯烃; 和油; 其中如果有的话，填料的含量维持组合物的雾度值为65％或更低。 在一个实施方案中，三元共聚物是包含至少65重量％的三元共聚物的丙烯衍生的单元，在乙烯或其它α-烯烃的5-35重量％范围内和二烯如亚乙基 降冰片烯，在某些具有门尼粘度（ML（1 + 4）@ 125℃）的实施方案中，在10至50的范围内（ASTM D1646）。 组合物可以固化以形成也是柔性的透明或半透明制品，例如片材。