Process and amine-solvent absorbent for removing acidic gases from
gaseous mixtures
    34.
    发明授权
    Process and amine-solvent absorbent for removing acidic gases from gaseous mixtures 失效
    用于从气体混合物中除去酸性气体的工艺和胺 - 溶剂吸收剂

    公开(公告)号:US4240923A

    公开(公告)日:1980-12-23

    申请号:US911035

    申请日:1978-05-30

    IPC分类号: B01D53/14 B01D53/52 C09K3/00

    CPC分类号: B01D53/526 B01D53/1493

    摘要: Acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an amine-solvent liquid absorbent comprising (i) an amine comprised of at least about 50 mol % of a sterically hindered amine, and (ii) a solvent for said amine mixture which is also a physical absorbent for said acidic gases. The liquid absorbent may also include up to about 35 weight percent water.

    摘要翻译: 通过包括使常规气态混合物与胺溶剂液体吸收剂接触的方法基本上从酸性气体除去酸性气体,所述胺溶剂液体吸收剂包括(i)由至少约50mol%空间位阻胺组成的胺,和(ii) 所述胺混合物的溶剂也是所述酸性气体的物理吸收剂。 液体吸收剂还可包含至多约35重量%的水。

    Process and composition for removing carbon dioxide containing acidic
gases from gaseous mixtures
    35.
    发明授权
    Process and composition for removing carbon dioxide containing acidic gases from gaseous mixtures 失效
    用于从气体混合物中除去含有酸性气体的二氧化碳的方法和组合物

    公开(公告)号:US4217236A

    公开(公告)日:1980-08-12

    申请号:US835773

    申请日:1977-09-22

    CPC分类号: B01D53/1493 Y02C10/06

    摘要: Carbon dioxide containing acidic gases are substantially removed from a normally gaseous mixture by a process comprising contacting the normally gaseous mixture with an aqueous amine solution, wherein the amine consists of at least about 50 mol % of a sterically hindered amino alcohol and at least about 10 mol % of a tertiary amino alcohol, wherein said sterically hindered amino alcohol contains at least one secondary amino group which is part of a ring and is attached to either a secondary or tertiary carbon atom or a primary amino group attached to a tertiary carbon atom. The coaction of the sterically hindered amino alcohol and the tertiary amino alcohol provide an increase in the amount of carbon dioxide containing acidic gases absorbed compared to the use of the sterically hindered amines alone and lowers the heat of reaction.

    摘要翻译: 含有酸性气体的二氧化碳基本上通过包括使常规气态混合物与胺水溶液接触的方法从常规气态混合物除去,其中胺由至少约50mol%的空间位阻氨基醇和至少约10 mol%的叔氨基醇,其中所述空间位阻氨基醇含有至少一个仲氨基,其为环的一部分,并且连接于连接到叔碳原子的仲或叔碳原子或伯氨基。 与单独使用空间位阻胺相比,空间位阻氨基醇和叔氨基醇的共同作用增加了吸收的二氧化碳含量,降低了反应热。

    Crude oil desalting method
    38.
    发明授权
    Crude oil desalting method 失效
    原油脱盐方法

    公开(公告)号:US06228239B1

    公开(公告)日:2001-05-08

    申请号:US09258620

    申请日:1999-02-26

    IPC分类号: B01D1706

    摘要: In one embodiment, the invention is related to a process for desalting crude oil that requires less wash water than conventional desalting methods. In the preferred embodiment of the invention, a chemical demulsifier formulation comprising an emulsion-breaking chemical and a solvent carrier is added to the crude oil. Wash water is then added to the crude oil until the volume of water in the oil ranges from about 0.1 to about 3 vol. %. Subsequently, the mixture of crude oil, wash water, and chemical demulsifier formulation is subjected to opposed-flow mixing. Chemical emulsion-breakers useful in the invention have a hydrophobic tail group and a hydrophilic head group. Preferably, the emulsion breaker has the formula: x ranges from 1 to 5, y ranges from 0 to 2, and R is an alkyl group having 4-9 carbon atoms, and n ranges from 3 to 9.

    摘要翻译: 在一个实施方案中,本发明涉及与常规脱盐方法相比需要较少洗涤水的原油脱盐方法。 在本发明的优选实施方案中,将包含破乳化学品和溶剂载体的化学破乳剂制剂加入到原油中。 然后将洗涤水加入到原油中,直到油中的水的体积为约0.1至约3体积%。 %。 随后,将原油,洗涤水和化学破乳剂制剂的混合物进行相反流混合。 可用于本发明的化学乳液破乳剂具有疏水性尾基和亲水性头基。 优选地,破乳剂具有下式:x为1至5,y为0至2,R为具有4-9个碳原子的烷基,n为3至9。