摘要:
A method of making a reconstructed electrode having a plurality of nanostructured thin catalytic layers is provided. The method includes combining a donor decal comprising at least one nanostructured thin catalytic layer on a substrate with an acceptor decal comprising a porous substrate and at least one nanostructured thin catalytic layer. The donor decal and acceptor decal are bonded together using a temporary adhesive, and the donor substrate is removed. The temporary adhesive is then removed with appropriate solvents. Catalyst coated proton exchange membranes and catalyst coated diffusion media made from the reconstructed electrode decals having a plurality of nanostructured thin catalytic layers are also described.
摘要:
Methods for starting a fuel cell system are provided. In one embodiment, the method includes providing hydrogen to an inlet of an anode of the fuel cell pressurizing the anode to a pressure; determining whether a blocked cell condition exists; if a blocked cell condition exists, if no blocked cell condition exists, initiating a normal start sequence, alternately reducing the pressure of the anode and increasing the pressure of the anode until an exit condition exists, the exit condition selected from a voltage of the fuel cell being stable, or a temperature of the fuel cell being greater than about 0° C., or both, and when the exit condition exists, initiating the normal start sequence.
摘要:
Apparatus for mixing fuel and an oxidant for use in an autothermal reformer that provides hydrogen to a fuel cell. The apparatus includes a mixing vessel (10), a first inlet (4) to the mixing vessel for movement of gaseous fuel or oxidant therethrough, a second inlet for movement of gaseous fuel or oxidant therethrough, and an exit (60) from the vessel adjacent the autothermal reformer. The discharge ends of the inlets are spaced apart from each other and from the exit which is near a POX reactor (61) that combusts the mixture of fuel and oxidant exiting from the mixing vessel. The first inlet is comprised of a plate (26) with a plurality of tubes (24) extending therefrom through which fuel or oxidant passes. The tubes extend into the mixing vessel and towards the exit of the vessel such that the fuel does not come into contact with the oxidant until the gaseous fuel or oxidant discharges from the ends (30) of the tubes thereby mixing the fuel with the oxidant in the gaseous state prior to passing to the POX reactor.
摘要:
The present invention is directed to mitigating overuse of limited membrane regions in electrochemical conversion assemblies, particularly under cold start conditions. In accordance with one embodiment of the present invention, the anode and/or cathode flowfield plates of an electrochemical conversion assembly are configured such that the fluid header region defines an anode fluid header, a cathode fluid header, and a coolant fluid header configured such that a feed region of the plate defines an array of substantially linear fluid channels extending from an acutely angled header/feed interface defined on the plate to a feed/active interface defined across the entire active area of the plate.
摘要:
A fuel cell stack that includes straight cathode flow channels and straight anode flow channels through a seal area between bipolar plates in the stack. The fuel cell stack includes a seal that extends around the active area of the stack and between the stack headers and the active area. At the locations where the cathode flow channels extend through a seal area to the cathode input header and the cathode outlet header, and the anode flow channels extend through a seal area to the anode input header and the anode output header, the diffusion media layer on one side of the membrane is extended to provide the seal load. Alternately, shims can be used to carry the seal load.
摘要:
A fuel cell in a fuel cell stack that provides a transition from nested bipolar plates in the active region of the stack to non-nested bipolar plates in the inactive regions of the stack without giving up the reduced stack thickness provided by the nested plates or changing the size of the flow channels. Particularly, the diffusion media layers in the fuel cells are removed in the inactive regions where the bipolar plates are non-nested so that the volume necessary to maintain the size of the flow channels is provided without the need to increase the distance between adjacent MEAs. A thin shim can be provided between the membranes and the plates in the inactive regions to support the membrane where the diffusion media layer has been removed to prevent the membrane from intruding into the flow channels and blocking the reactive flow.
摘要:
A reactor system including a reactor housing having an inlet portion defined at one end of the housing and having a discharge opening formed in the housing at an opposite end. An air intake charge line is connected to the housing for charging air into the inlet portion. A steam charge line is connected to the housing for charging steam into the inlet portion. A fuel injector is positioned in the housing for injecting fuel into the stream of air and steam flowing through the housing. A fuel charge line is connected to the fuel injector for charging a carbon-based fuel into the injector. A catalyst bed is carried in the housing and positioned downstream of the fuel injector and at least a portion of the catalyst bed includes a catalyst for promoting the reformation of the carbon-based fuel to produce hydrogen. An auto-ignition suppression and carbon-suppression foam is carried in the housing and positioned between the catalyst bed and the fuel injector.
摘要:
Method of operating an autothermal reformer (ATR) to produce a high temperature reformate including preheating steam and air inputs to the ATR with heat from the reformate. The steam is heated by the reformate, and the air is then heated by the steam. There is no direct heat exchange between the reformate and the air. In the heat exchangers effecting the heat transfer, the steam is kept at a higher pressure that both the reformate and the air.
摘要:
A detection method for enabling gas composition observation during fuel cell system start-up is described. In one embodiment, the method includes initiating a flow of hydrogen to the anode to pressurize the anode; opening an anode flow valve; determining if an anode pressure exceeds an anode pressure threshold; enabling anode flow set point detection after a first predetermined time if the anode pressure exceeds the anode pressure threshold; monitoring an anode flow set point using the anode flow set point detection; determining if the anode flow set point exceeds an anode flow set point threshold; and closing the anode flow valve after a second predetermined time if the anode flow set point exceeds the anode flow set point threshold.
摘要:
A fuel cell component includes a first fluid distribution layer, a second fluid distribution layer, a cap layer, a third fluid distribution layer, and a pair of fluid diffusion medium layers. The individual layers are polymeric, mechanically integrated, and formed from a radiation-sensitive material. The first fluid distribution layer, the second fluid distribution layer, the cap layer, the third fluid distribution layer, and the pair of fluid diffusion medium layers are coated with an electrically conductive material. A pair of the fuel cell components may be arranged in a stack with a membrane electrode assembly therebetween to form a fuel cell.