公开(公告)号：US06803416B2

公开(公告)日：2004-10-12

申请号：US10029265

申请日：2001-12-28

申请人： Klaus Schultes ,  Thomas Suefke ,  Markus Parusel ,  Werner Hoess

发明人： Klaus Schultes ,  Thomas Suefke ,  Markus Parusel ,  Werner Hoess

IPC分类号： C08L1900

CPC分类号： C08F2/24 ,  C08F2/18

摘要： The present invention provides a moulding composition, which includes: a plurality of bead polymers dispersed in at least one matrix polymer; wherein the bead polymers: have an average particle size of 5 to 40 &mgr;m, and have a refractive index nD at 20° C. which is different from a refractive index nD at 20° C. of said matrix polymer; and wherein the bead polymers are prepared by a process, which includes: contacting: at least one polymerizable mix which includes at least 50% by weight of at least one (meth)acrylate monomer, at least one aluminum compound, and an aqueous phase, to prepare a mixture; dispersing the mixture at a shear rate ≧103 s−1 to form a dispersion, wherein the dispersion is stabilized by the aluminum compound; and polymerizing to produce the bead polymers having an average particle size of 5 to 40 &mgr;m.

摘要翻译： 本发明提供了一种模塑组合物，其包括：分散在至少一种基质聚合物中的多个珠粒聚合物;其中所述珠粒聚合物的平均粒度为5至40μm，并且在20℃具有折射率nD。 其与所述基质聚合物在20℃的折射率nD不同;并且其中所述珠粒聚合物通过一种方法制备，所述方法包括：使至少一种可聚合的混合物至少包含至少50重量％ 一种（甲基）丙烯酸酯单体，至少一种铝化合物和水相，以制备混合物;将混合物在剪切速率> 10 3 s -1下分散以形成分散体，其中分散体稳定 由铝化合物; 并且聚合以产生平均粒径为5至40μm的珠粒聚合物。

公开(公告)号：US4911875A

公开(公告)日：1990-03-27

申请号：US323046

申请日：1989-03-10

申请人： Heinz Vetter ,  Werner Hoess ,  Werner Siol

发明人： Heinz Vetter ,  Werner Hoess ,  Werner Siol

IPC分类号： B29C45/16 ,  B29C37/00 ,  B29C45/14 ,  C08J7/04

CPC分类号： B29C45/14778 ,  B29C37/0032 ,  B29K2995/0087

摘要： Injection molded parts having a scratch resistant surface are produced by applying a liquid mixture of at least one monomer susceptible of free radical polymerization and having more than one polymerizable double bond and of at least one free radical forming initiator to the forming surface of an injection mold, polymerizing the mixture at least partially, and then injecting a thermoplastic or duroplastic molding composition into the closed mold.

摘要翻译： 具有耐擦伤表面的注射成型品通过施加至少部分聚合至少一种可通过自由基聚合并含有多于一个可聚合双键的单体的液体混合物和至少一种形成 自由基进入注塑模具的模制表面，以便形成耐刮擦涂层，随后将热塑性或热固性模塑组合物注入封闭的注模中。

公开(公告)号：US09988548B2

公开(公告)日：2018-06-05

申请号：US14772618

申请日：2014-03-19

申请人： Werner Hoess ,  Victor Khrenov ,  Reiner Mueller ,  Lukas Friedrich Doessel ,  Dominic Stoerkle

发明人： Werner Hoess ,  Victor Khrenov ,  Reiner Mueller ,  Lukas Friedrich Doessel ,  Dominic Stoerkle

IPC分类号： C08L83/00 ,  C09D133/08 ,  C08F220/14 ,  C08F220/18 ,  C08F285/00 ,  C08L51/00 ,  C09D125/12 ,  C09D125/14

CPC分类号： C09D133/08 ,  C08F220/14 ,  C08F220/18 ,  C08F285/00 ,  C08L51/003 ,  C08L2207/53 ,  C09D125/12 ,  C09D125/14 ,  C08F2220/1808 ,  C08F220/40 ,  C08F2220/1825 ,  C08F212/08 ,  C08L33/12

摘要： The invention relates to a molding composition modified for impact resistance, in particular to impact-resistant PMMA with improved optical properties at elevated temperatures, to molded items obtainable therefrom, and also to the use of the molding composition and of the molded items.

公开(公告)号：US08975337B2

公开(公告)日：2015-03-10

申请号：US13241776

申请日：2011-09-23

申请人： Werner Hoess ,  Michael Wicker ,  Klaus Schultes ,  Klaus Albrecht ,  Martin Mohrmann

发明人： Werner Hoess ,  Michael Wicker ,  Klaus Schultes ,  Klaus Albrecht ,  Martin Mohrmann

IPC分类号： C08L33/04 ,  C08L33/12 ,  C08L35/06

CPC分类号： C08L33/04 ,  C08L33/12 ,  C08L2205/02 ,  Y10T428/24273 ,  Y10T428/24322 ,  Y10T428/24694 ,  Y10T428/31909 ,  C08L2666/04

摘要： A molding compound comprises a copolymer (I)a), produced by polymerization of 90-100% by weight methylmethacrylate, styrene and malic acid anhydride, and optionally 0-10% by weight additional monomers which can be copolymerized with methylmethacrylate, a (co)polymer (II)b), produced by polymerization of 80-100% by weight methylmethacrylate and optionally 0-20% by weight additional monomers which can be copolymerized with methylmethacrylate, and has a solution viscosity in chloroform at 25° C. (ISO 1628 Part 6) of 50 to 55 ml/g, as well as c) optional conventional additives, auxiliary agents and/or fillers. The molding compound is characterized in that the copolymer (I) has a solution viscosity in chloroform at 25° C. (ISO 1628 Part) of 55 ml/g or less. Also disclosed are moldings produced by thermoplastic processing of the molding compound and their uses.

摘要翻译： 模制化合物包括由90-100重量％甲基丙烯酸甲酯，苯乙烯和苹果酸酐的聚合产生的共聚物（I）a），和可与甲基丙烯酸甲酯共​​聚的任选的0-10重量％的另外的单体 ）聚合物（II）b），其通过聚合80-100重量％的甲基丙烯酸甲酯和任选的0-20重量％的可与甲基丙烯酸甲酯共​​聚的另外的单体聚合制得，并且在25℃下在氯仿中具有溶液粘度（ISO 1628 Part 6）为50至55ml / g，以及c）任选的常规添加剂，助剂和/或填料。 成型化合物的特征在于共聚物（I）在25℃下的氯仿溶液粘度（ISO 1628份）为55ml / g以下。 还公开了通过模塑料的热塑性加工及其用途制备的模制品。

公开(公告)号：US20140349093A1

公开(公告)日：2014-11-27

申请号：US14377061

申请日：2013-02-14

申请人： Thomas Hasskerl ,  Klaus Koralewski ,  Sabine Schwarz-Barac ,  Roger Recktenwald ,  Werner Hoess ,  Florian Band

发明人： Thomas Hasskerl ,  Klaus Koralewski ,  Sabine Schwarz-Barac ,  Roger Recktenwald ,  Werner Hoess ,  Florian Band

IPC分类号： B32B7/12 ,  C09J4/06 ,  B32B37/00 ,  B32B17/10

CPC分类号： B32B7/12 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10743 ,  B32B17/10899 ,  B32B37/00 ,  B32B2250/05 ,  B32B2250/40 ,  B32B2315/08 ,  C08F2220/1825 ,  C08F2220/325 ,  C09J4/06 ,  C09J133/08 ,  C09J133/10 ,  Y02E10/52 ,  Y10T428/2495 ,  Y10T428/266 ,  Y10T428/31645

摘要： The invention relates to a new adhesive composition and to sheets produced from it, for producing laminates, more particularly for bonding plastic with glass components, to a method for producing such laminates, and to the laminates produced accordingly.

摘要翻译： 本发明涉及一种新的粘合剂组合物和由其制备的片材，用于生产层压材料，更具体地说，用于将具有玻璃组分的塑料粘合到制造这种层压材料的方法中，以及相应地生产的层压材料。

公开(公告)号：US20120322932A1

公开(公告)日：2012-12-20

申请号：US13506268

申请日：2012-06-26

申请人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

发明人： Klaus Schultes ,  Werner Hoess ,  Nils Mehler

IPC分类号： C08L33/12 ,  B29C45/00 ,  C08K5/05

CPC分类号： C08L33/08 ,  C08L25/12 ,  C08L33/10 ,  C08L2666/04

摘要： Provided is a molding composition comprising, based on the total weight of the composition, (A) 50.0% by weight to 99.5% by weight of at least one (co)polymer which is a homopolymer or copolymer of at least 80% by weight of methyl methacrylate, (B) 0.5% by weight to 50.0% by weight of at least one copolymer obtained by polymerization of a monomer, and (C) at least one low molecular weight (meth)acrylate (co)polymer having a solution viscosity in chloroform at 25° C. (ISO 1628—part 6) of less than or equal to 55 ml/g.

摘要翻译： 本发明提供一种成型组合物，其包含基于组合物的总重量的（A）50.0重量％至99.5重量％的至少一种（共）聚合物，其为均聚物或共聚物，其为至少80重量％ 甲基丙烯酸甲酯，（B）0.5重量％〜50.0重量％的至少一种通过单体聚合获得的共聚物，和（C）至少一种具有溶液粘度的低分子量（甲基）丙烯酸酯 25℃下的氯仿（ISO 1628-第6部分）小于或等于55ml / g。

公开(公告)号：US20120015141A1

公开(公告)日：2012-01-19

申请号：US13241776

申请日：2011-09-23

申请人： Werner Hoess ,  Michael Wicker ,  Klaus Schultes ,  Klaus Albrecht ,  Martin Mohrmann

发明人： Werner Hoess ,  Michael Wicker ,  Klaus Schultes ,  Klaus Albrecht ,  Martin Mohrmann

IPC分类号： B32B27/28 ,  C08L33/12 ,  B32B3/12 ,  B32B3/28 ,  B32B3/24 ,  C08L35/06 ,  C08K5/05

CPC分类号： C08L33/04 ,  C08L33/12 ,  C08L2205/02 ,  Y10T428/24273 ,  Y10T428/24322 ,  Y10T428/24694 ,  Y10T428/31909 ,  C08L2666/04

摘要： A moulding compound comprises a copolymer (I)a), produced by polymerisation of 90-100% by weight methylmethacrylate, styrene and malic acid anhydride, and optionally 0-10% by weight additional monomers which can be copolymerised with methylmethacrylate, a (co)polymer (II)b), produced by polymerisation of 80-100% by weight methylmethacrylate and optionally 0-20% by weight additional monomers which can be copolymerised with methylmethacrylate, and has a solution viscosity in chloroform at 25° C. (ISO 1628 Part 6) of 50 to 55 ml/g, as well as c) optional conventional additives, auxiliary agents and/or fillers. The moulding compound is characterised in that the copolymer (I) has a solution viscosity in chloroform at 25° C. (ISO 1628 Part) of 55 ml/g or less. Also disclosed are mouldings produced by thermoplastic processing of the moulding compound and their uses.

摘要翻译： 模制化合物包括通过聚合90-100重量％甲基丙烯酸甲酯，苯乙烯和苹果酸酐和任选0-10重量％的另外的单体，其可以与甲基丙烯酸甲酯共​​聚而成的共聚物（I）a） ）聚合物（II）b），其通过聚合80-100重量％的甲基丙烯酸甲酯和任选的0-20重量％的可与甲基丙烯酸甲酯共​​聚的另外的单体聚合制备，并且在25℃下在氯仿中具有溶液粘度（ISO 1628 Part 6）为50至55ml / g，以及c）任选的常规添加剂，助剂和/或填料。 成型化合物的特征在于共聚物（I）在25℃下的氯仿溶液粘度（ISO 1628份）为55ml / g以下。 还公开了通过模塑料的热塑性加工及其用途制备的模制品。

公开(公告)号：US07790079B2

公开(公告)日：2010-09-07

申请号：US11817407

申请日：2006-04-11

申请人： Werner Hoess ,  Klaus Albrecht ,  Krzysztof Sado ,  Harald Haeger

发明人： Werner Hoess ,  Klaus Albrecht ,  Krzysztof Sado ,  Harald Haeger

IPC分类号： B29C47/00

CPC分类号： C08J3/20 ,  C08J3/205 ,  C08K3/013 ,  Y02P20/544

摘要： (EN) The invention concerns a method for producing a thermoplastic molding material or element, said material or element containing nanometric inorganic particles. In molten state, the thermoplastic is mixed with the nanometric inorganic particles and with a solubilizing agent in a conveyor screw extruder, the pressures and temperatures being adjusted so that the plastic is in melt form and the solubilizing agent in supercritical state. The invention is characterized in that at the output of the extruder, the mixture passes through a slot with a passage less than 20 $g(m)m to penetrate into an expansion zone and the molten material, wherein are incorporated the nanometric inorganic particles, is evacuated, reduced into molding material after cooling or transferred into a molding tool to be molded. The invention also concerns the molding material and the molding elements obtained by this method, as well as the uses thereof.

摘要翻译： （EN）本发明涉及一种生产热塑性成型材料或元素的方法，所述材料或元素含有纳米无机颗粒。 在熔融状态下，将热塑性塑料与纳米无机颗粒和增溶剂在输送机螺杆挤出机中混合，调节压力和温度，使塑料呈熔体状态，增溶剂处于超临界状态。 本发明的特征在于，在挤出机的输出处，混合物通过具有小于20千克（m）m的通道的槽，以渗入膨胀区，并且其中掺入纳米无机颗粒的熔融材料， 被抽真空，冷却后还原成模制材料或转移到待模制的模具中。 本发明还涉及通过该方法获得的成型材料和成型元件及其用途。

公开(公告)号：US20060175735A1

公开(公告)日：2006-08-10

申请号：US10546241

申请日：2004-03-02

申请人： Werner Hoess ,  Arne Schmidt ,  Klaus Albrecht ,  Klaus Schultes

发明人： Werner Hoess ,  Arne Schmidt ,  Klaus Albrecht ,  Klaus Schultes

IPC分类号： C08K7/16 ,  B29C45/00

CPC分类号： B29C70/585 ,  B29C45/0013 ,  B29K2033/12 ,  C08K7/16 ,  C08L25/04 ,  C08L33/10 ,  C08L83/00 ,  C08L2205/22 ,  C08L2666/02

摘要： The invention relates to an injection moulding method for the production of a complex, high optical quality light-diffusing moulded item. The moulding material used comprises a matrix made of polymethyl(meth)acrylate and spherical plastic particles whose particle size ranges from 1-24 μm and the concentration thereof ranges from 0.05-30 wt.-% in relation to the weight of the polymethyl(meth)acrylate. The spherical particles exhibit a refractive index differential in relation to the polymethyl(meth)acrylate matrix of 0.01 0.2.

摘要翻译： 本发明涉及一种用于生产复杂的高光学质量的光漫射模制品的注塑方法。 使用的成型材料包括由聚甲基（甲基）丙烯酸甲酯和粒径为1-24μm的球形塑料颗粒制成的基质，其浓度相对于聚甲基（甲基）丙烯酸酯的重量为0.05-30重量％ ）丙烯酸酯。 球形颗粒表现出相对于0.01±0.2的聚甲基（甲基）丙烯酸酯基质的折射率差。

公开(公告)号：US20060147714A1

公开(公告)日：2006-07-06

申请号：US10539509

申请日：2003-10-18

申请人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

发明人： Klaus Schultes ,  Reiner Mueller ,  Andreas Spiess ,  Klaus Albrecht ,  Werner Hoess

IPC分类号： B32B1/00

CPC分类号： C08L51/003 ,  C08F265/04 ,  C08F285/00 ,  C08L33/12 ,  C08L33/20 ,  C08L35/06 ,  C08L51/04 ,  C08L55/005 ,  C08L55/02 ,  Y10T428/2998 ,  C08L2666/02 ,  C08L2666/24

摘要： The present invention relates to a core-shell particle which has a core, a first shell and, where appropriate, a second shell, where: i) the core encompasses, based on its total weight, at least 75.0% by weight of (meth)acrylate repeat units; ii) the first shell has a glass transition temperature below 30° C.; iii) the second shell present where appropriate encompassed, based on its total weight, at lest 75.0% by weight of (meth)acrylate repeat units; iv) the first shell encompasses, based on its total weight, the following constituents; E) from 92.0 to 98.0% by weight of (meth)acrylate repeat units and F) from 2.0 to 8.0% by weight of styrenic repeat units of the general formula (I) where the radicals R1 to R6 are defined according to the Description and the percentages by weight of E) and F) give a total of 100.0% by weight, v) the radius of the core-shell particle inclusive of any second shell present, measured by the Coulter method, is in the range from above 160.0 to 240.0 nm. The present invention further relates to a process for preparing core-shell particles, to a moulding composition comprising core-shell particles, and to the use thereof.

摘要翻译： 本发明涉及一种具有芯，第一壳和适当的第二壳的核 - 壳颗粒，其中：i）芯基于其总重量包含至少75.0重量％的（甲基） ）丙烯酸酯重复单元; ii）第一壳的玻璃化转变温度低于30℃; iii）适当地包含的第二壳基于其总重量至少为75.0重量％的（甲基）丙烯酸酯重复单元; iv）第一壳基于其总重量包含以下组分; E）为92.0〜98.0重量％的（甲基）丙烯酸酯重复单元，F）2.0〜8.0重量％的通式（I）的苯乙烯重复单元，其中R 1〜 根据描述定义R 6，并且E）和F）的重量百分比总计为100.0重量％，v）包含任何第二壳的核 - 壳颗粒的半径 存在，通过库尔特法测量，在160.0至240.0nm之间的范围内。 本发明还涉及一种制备核 - 壳颗粒的方法，涉及包含核 - 壳颗粒的模塑组合物及其用途。