摘要:
The invention relates to thermoplastic molding compositions, comprising A) from 35 to 95% by weight of at least one graft copolymer A), which is obtainable via reaction of A1) from 5 to 95% by weight of a polymer A1), which is obtained from at least one dicarboxylic anhydride a11) and from at least one vinylaromatic comonomer a12), and A2) from 5 to 95% by weight of a polyamide A2), B) from 5 to 40% by weight of at least one ungrafted or grafted, non-particulate rubber without core-shell structure B), which has functional groups which can react with the end groups of component A), C) from 0 to 50% by weight of at least one particulate or fibrous filler or particulate or fibrous reinforcing material C), D) from 0 to 60% by weight of at least one copolymer D) composed of vinyl aromatic monomers d1) and of comonomers d2), and E) from 0 to 40% by weight of at least one other additive E), where the entirety of components A) to E) gives 100% by weight, and also to processes for preparation of the thermoplastic molding compositions, to the use of the thermoplastic molding compositions for production of moldings, of foils, of fibers, or of foams, and finally to the moldings, foils, fibers, and foams obtainable from the thermoplastic molding compositions.
摘要:
The invention relates to thermoplastic molding materials containing the following main components: A) 2 to 97.9 wt. % of at least one polyester; B) 0 to 95.9 wt. % of at least one polycarbonate; C) 1 to 80 wt. % of at least one graft polymer which is made up of c1) 40 to 80 wt. % of a graft base consisting of a rubber elastic polymer based on alkyl acrylates with 1 to 8 C-atoms in the alkyl radical and with a glass transition temperature of less than 10° C., c2) 20 to 60 wt. % of a graft support consisting of c21) 60 to 95 wt. % styrene or substituted styrenes of general formula (I), wherein R represents an alkyl radical with 1 to 8 C-atoms or a hydrogen atoms and R1 represents an alcohol radical with 1 to 8 C-atoms and the value of n is 1, 2 or 3 and c22) 5 to 40 wt. % of at least one unsaturated nitrile; D) 1 to 80 wt. % of a copolymer consisting of d1) 60 to 95 % styrene or substituted styrenes of general formula (I) or mixtures thereof and d2) 5 to 40 wt. % of at least one unsaturated nitrile; E) 0.1 to 10 wt. % of an epoxyde resin; and F) 0 to 80 wt. % other additives, the sum of the weight percentages of components A) to F) being 100%.
摘要:
Flame-retardant, thermoplastic molding materials containing A) at least one polyphenylene ether, B) at least one vinylaromatic polymer and C) at least one flameproofing agent, comprise D) an amount of expandable graphite which increases the resistance of the molding material to dripping and are used for the production of flame-retardant moldings, fibers and films.
摘要:
In the preparation of a rubber-modified molding material, in a first stage, a first mixture (A) contains at least one alkyl acrylate or methacrylate (a) of the formula (I) ##STR1## where R.sup.1 is hydrogen or methyl and R.sup.2 is alkyl of 1 to 32 carbon atoms, if required a first monomer (b) having two or more double bonds and, if required, also a second monomer (c) or a plurality thereof is polymerized, preferably with free radicals, to give a rubber (B), in a second stage, a third monomer (d) or a plurality thereof is added to the resulting rubber (B) to form a second mixture (C), whereby the rubber (B) is dissolved or swollen in the third monomer (d), with or with the addition of a solvent, and in a third stage, the second mixture (C) formed is polymerized with free radicals to give the rubber-modified molding material (D), and the mixture is reacted at >120.degree. C., during or after this polymerization, with a compound (e) which contains at least two peroxy groups.
摘要:
Finely divided electrically conductive pyrrole polymers are prepared by a process in which the pyrroles, in solution and in the presence of a conductive salt, are treated with an oxygen-containing oxidizing agent. The finely divided conductive pyrrole polymers can be used for the production of moldings.
摘要:
The subject invention relates to storage stable dispersions comprising certain aromatic polyesters dispersed in certain polyhydroxyl compounds and their process of preparation. The dispersions are useful for the preparation of polymers containing urethane and/or isocyanurate linkages.
摘要:
A blow molding having capacity of at least 250 ml, having a shell which is composed of impact-resistant polystyrene and which is produced via injection stretch blow molding where an average aspect ratio of rubber particles derived from longitudinal section and an average aspect ratio of rubber particles derived from cross section measured in transmission electron micrographs is greater than 4 respectively, and a biaxial orientation of the rubber particles, given by the ratio of the aspect ratio derived from cross section to the aspect ratio derived from longitudinal section is smaller than 3.
摘要:
Thermoplastic molding compositions comprising A) from 40 to 96.2% by weight of a semiaromatic polyamide, B) from 2 to 30% by weight of an impact-modifying polymer which comprises functional groups, C) from 1 to 50% by weight of fibrous or particulate fillers or a mixture of these, D) from 0.2 to 5% by weight of a lubricant, E) from 0.5 to 15% by weight of an electrically conductive additive, F) from 0 to 30% by weight of other added materials, where the total of the percentages by weight of components A) to F) is 100%.
摘要:
The present invention relates to a process for producing polymer fibers, especially nano- and mesofibers, by the electrospinning process, in which a colloidal dispersion of at least one essentially water-insoluble polymer and of at least one nonionic surfactant, if appropriate further comprising at least one water-soluble polymer, is electrospun in an aqueous medium. The present invention further relates to fibers obtainable by this process.
摘要:
A total prosthesis for the middle ear, with a prosthesis body, with a first coupling element for connection of the prosthesis to the tympanic membrane or for coupling to the manubrium, and with a second coupling element for connection to the footplate of the stirrup, which second coupling element has a receiving part, connected rigidly to the prosthesis body, and has an insert part with a plug element that can be inserted coaxially, and with a shoe that is connected rigidly to the plug element and that bears on the footplate of the stirrup, is characterized in that the receiving part has an elongate cavity as a receiving opening with a cylindrical bore which extends axially and encloses the full circumference of the plug element and whose inside diameter is greater than the maximum transverse extent of the plug element, which elongate cavity is closed at the end away from the insert part and acts as an end abutment for the plug element, and in that the second coupling element extends axially by at most a third of the axial length of the prosthesis body. In this way, it is easy to produce a desired defined length of the prosthesis, which also remains fixed after surgery, and it is also possible, during surgery, to react to the specific individual situation of the stirrup bone.