摘要:
The present invention relates to a process for the modification of thermoplastic aromatic polycarbonates containing aromatically bonded halogen, primary alkyl, secondary alkyl and/or alkenyl substituents, characterized in that these polycarbonates are irradiated with UV light, after adding between about 1 and 5% by weight, preferably between about 1 and 3% by weight, relative to the weight of polycarbonate, of photoinitiators and optionally between about 0.05 and 5% by weight, preferably between about 0.1 and 2% by weight, relative to the weight of polycarbonate, of flame-proofing agents. The present invention also relates to the modified polycarbonates obtainable by the process according to the invention.
摘要:
The present invention provides thermoplastic aromatic polycarbonates and a process for their production according to the phase boundary polycondensation process, characterized in that tertiary amines are employed as catalysts and are distilled beforehand over about 0.3-10% by weight, relative to the weight of the tertiary amine, of reducing agents and/or acid anhydrides with the exclusion of atmospheric oxygen.
摘要:
The present invention relates to glass fiber reinforced thermoplastic polycarbonate molding compositions whose toughness and elastic properties have been improved by the incorporation of 1 to 5 wt.% of poly-(2,6-dialkyl-1,4-phenyleneoxide). These compositions contain between 10 and 30 wt.% glass fibers and display improved properties even after extended times at high humidity. The polyphenylene oxides preferably have M.sub.w between 2,000 and 100,000, most preferably 20,000 and 60,000. A particularly suitable additive is poly-(2,6-dimethyl-1,4-phenylene oxide).
摘要:
Molding compositions having an oxygen index of greater than 0.30 based on high molecular weight aromatic polycarbonates containing 0.5-20% of organic fibers.
摘要:
Homopolymers and copolymers based on alkenoyloxybenzylidene-malonic esters of the formula ##SPC1##WhereR.sup.1 is hydrogen or C.sub.1 to C.sub.4 -alkyl;R.sup.2 is C.sub.1 to C.sub.12 -alkyl or cycloalkyl andR.sup.3 is hydrogen, C.sub.1 to C.sub.8 -alkyl, C.sub.1 to C.sub.8 -alkoxy or halogen, and plastics, i.e., polycarbonates, stabilized therewith.
摘要:
A novel process for the production of oligomeric and polymeric telechelic compositions, to the telechelic compositions produced in this manner and to use thereof in the plastics, fibres or lacquer sectors.
摘要:
A process is disclosed for the production of metal sheets enamelled with two layers, wherein the sheet is coated, before shaping, with a polymer suspension. The sheet is then dried and shaped, and optionally is coated with an enamel frit. The sheet is then fired at a temperature of 560 to 850 degrees C. The binder in the polymer suspension is preferably a material which burns completely at melting and stoving temperature.
摘要:
Anilines substituted in the m- and p-position by an alkyl radical and a halogen atom are eminently suitable for use as accelerators for cold-hardening unsaturated polyester resins.
摘要:
Stabilized thermoplastic moulding compositions comprising (1) from 10 to 90 parts by weight of a polycarbonate, based on aromatic dihydroxy compounds; and (2) from 90 to 10 parts by weight of a mixture of (2.1) from 25 to 100 parts by weight of a graft copolymer of a monomer mixture of styrene, methyl methacrylate or acrylonitrile polymerized on a rubber; of (2.2) from 0 to 20 parts by weight of a butadiene polymer having a butadiene content of at least 5 parts by weight; and (2.3) from 0 to 75 parts by weight of a copolymer of styrene, .alpha.-methyl styrene, methyl methacrylate, acrylonitrile or methacrylonitrile; containing 0.01 to 3.0% by weight, based on the whole stabilized mixture, of at least one ester of phosphorous acid and an ortho- or para-substituted phenol or bisphenol, and a process for their production.
摘要:
This disclosure is concerned with an improved process for preparing polymer blends by synthesizing a polyester by the phase boundary condensation synthesis wherein a preformed polymer is dissolved in the organic solvent phase of the synthesis system. This polymer is inert to the diphenol acid chloride and alkali used to form the polyester and differs from this polyester by at least molecular weight and may differ from it in chemical identity. This disclosure is also concerned with the polymer blends so obtained which display superior properties to those obtained by physically blending two already formed polymers.